Citation: Xiang YANG, Ming-Hui ZHANG, Kai CHEN, Ran LI, Xiu-Du ZHANG. Co(Ⅱ)-based metal-organic frameworks containing bipyridyl ligands and terephthalic acid as fluorescent probes for Fe(Ⅲ)[J]. Chinese Journal of Inorganic Chemistry, ;2023, 39(7): 1244-1252. doi: 10.11862/CJIC.2023.095 shu

Co(Ⅱ)-based metal-organic frameworks containing bipyridyl ligands and terephthalic acid as fluorescent probes for Fe(Ⅲ)

Xiang YANG ¹ ,
Ming-Hui ZHANG ¹ ,
Kai CHEN ^1,, ,
Ran LI ¹ ,
Xiu-Du ZHANG ^2,,

1.
Jiangsu Collaborative Innovation Centre of Atmospheric Environment and Equipment Technology, Jiangsu Key Laboratory of Atmospheric Environment Monitoring and Pollution Control, School of Environmental Science and Engineering, Nanjing University of Information Science & Technology, Nanjing 210044, China
2.
Key Laboratory of Functional Molecular Solids, Ministry of Education, Anhui Laboratory of Molecule-Based Materials, Anhui Key Laboratory of Functional Molecular Solids, College of Chemistry and Materials Science, Anhui Normal University, Wuhu, Anhui 241002, China

Corresponding author: Kai CHEN, kaichen85@nuist.edu.cn Xiu-Du ZHANG, xiuduzhang@nju.edu.cn
Received Date: 6 January 2023
Revised Date: 27 March 2023

Figures(4)

The ligands 1, 4-bis(2-(2-pyridyl)ethenyl)benzene (2-bpeb) and 1, 2-di(pyridin-4-yl)ethene (dpe) have been employed to react with terephthalic acid (H₂PTA) and Co(NO₃)₂ under solvothermal conditions to fabricate two novel Co(Ⅱ)-MOFs (1 and 2). The structure of 1 manifests a 3D framework constituted by the Co-2-bpeb and Co-PTA chains, while complex 2 is a 3D framework constructed from the Co-PTA layers connected by the dpe ligand. Due to the existence of a large π-conjugated system in the pyridyl ligands and in consideration of the practical application, the fluorescence properties of 1 and 2 were investigated and the sensing experiments revealed that both of them could be used as a fluorescent sensor for detecting Fe³⁺ with good sensitivity and recyclability.
- metal-organic frameworks,
- mixed-ligand strategy,
- conjugated system,
- fluorescent probes,
- Fe³⁺
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