Citation: Jing ZHU, Shun ZHONG, Lin SUN, Yong DAI. Photo-responsive UiO-66 with spiropyran functionalization adsorbent: Preparation and adsorption performance[J]. Chinese Journal of Inorganic Chemistry, ;2023, 39(8): 1510-1518. doi: 10.11862/CJIC.2023.079 shu

Photo-responsive UiO-66 with spiropyran functionalization adsorbent: Preparation and adsorption performance

School of Chemistry and Chemical Engineering, Yancheng Institute of Technology, Yancheng, Jiangsu 224051, China

Corresponding author: Jing ZHU, jingzhu@ycit.cn Yong DAI, dy@ycit.cn
Received Date: 20 February 2023
Revised Date: 2 May 2023

Figures(11)

Herein, a representative metal-organic framework (MOF), UiO-66, with a microporous structure and hydrothermal stability, has been chosen as porous support. Photo-responsive adsorbents were prepared by introducing the spiropyran derivative SP-CH₃ into the non-polar pore cage of UiO-66 as photo-regulated active sites. The framework structure of the support material was maintained after SP-CH₃ functionalization. An anionic dye, methyl orange, was adopted as a probe to explore the adsorption and desorption performance of the adsorbent in different light conditions. The experimental results showed that the adsorption amount of methyl orange by the sample after UV irradiation was 41.99 mg·g^-1, which increased by 57.56% in comparison to that after visible light irradiation. In addition, the desorption of methyl orange of the adsorbent after visible light irradiation was up to 81.6%. Changes in the electric surface charge and polarity of the adsorbents, owing to efficient photo-isomerization of spiropyran in the non-polar environment of UiO-66 cage, have great effects on the adsorption/desorption behaviors of methyl orange on the adsorbents. The resultant adsorbents with photo-regulated active sites exhibit enhanced adsorptive performance and effective desorption.
- metal-organic frameworks,
- spiropyran,
- photo-response,
- adsorption separation
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