Citation: Shi-Peng GAI, Jin-Dou TIAN, Fei-Long JIANG, Qi-Hui CHEN, Mao-Chun HONG. A microporous cobalt-based metal-organic framework for selective gas adsorption[J]. Chinese Journal of Inorganic Chemistry, ;2023, 39(6): 1014-1022. doi: 10.11862/CJIC.2023.076 shu

A microporous cobalt-based metal-organic framework for selective gas adsorption

Shi-Peng GAI ^{1, #} ,
Jin-Dou TIAN ^{2, #} ,
Fei-Long JIANG ² ,
Qi-Hui CHEN ^2,, ,
Mao-Chun HONG ^2,,

1.
College of Chemistry and Materials Science, Fujian Normal University, Fuzhou 350007, China
2.
Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou 350002, China

Corresponding author: Qi-Hui CHEN, chenqh@fjirsm.ac.cn Mao-Chun HONG, hmc@fjirsm.ac.cn
Received Date: 24 February 2023
Revised Date: 24 April 2023

Figures(6)

Herein, a novel metal-organic framework {[Co(DTBDA)]₂·DMF·MeOH}_n (FJI-H37) was prepared by solvothermal reaction of cobalt nitrate with ligand 5, 5'-di(1H-1, 2, 4-triazol-1-yl)-(1, 1'-biphenyl)-2, 2'-dicarboxylic acid (H₂DTBDA). FJI-H37 not only has 0.69 nm of micropores for gas adsorption but also possesses good thermal stability and organic solvent tolerance. The gas adsorption tests show that FJI-H37 can not only selectively adsorb C₂H₂ from a C₂H₂/CO₂ (50:50, V/V) mixture with a relatively high adsorption selectivity of 4.2, but also selectively capture CO₂ from a CO₂/N₂ (15:85, V/V) and CO₂/CH₄ (50:50, V/V) mixture; which can be further confirmed by the dynamic fixedbed breakthrough experiments.
- metal-organic framework,
- microporous material,
- acetylene adsorption,
- carbon dioxide capture,
- selective adsorption
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