Citation: Yu-Mei BAO, Yan-He CHEN, Yuan-Yuan XING, Jian-Yong ZHANG, Wei DENG. Syntheses, structures, and catalytic properties of three Ni(Ⅱ)-based coordination polymers from 2, 4, 6-tris(3-pyridyl)-1, 3, 5-benzene ligand[J]. Chinese Journal of Inorganic Chemistry, ;2023, 39(6): 993-1004. doi: 10.11862/CJIC.2023.074 shu

Syntheses, structures, and catalytic properties of three Ni(Ⅱ)-based coordination polymers from 2, 4, 6-tris(3-pyridyl)-1, 3, 5-benzene ligand

School of Chemical and Environmental Engineering, Shanghai Institute of Technology, Shanghai 201418, China

Corresponding author: Jian-Yong ZHANG, jianyong1106@163.com Wei DENG, wdeng@sit.edu.cn
Received Date: 29 November 2022
Revised Date: 23 April 2023

Figures(8)

By tuning the solvothermal reaction conditions, we prepared three Ni(Ⅱ)-based coordination polymers (CPs), namely[Ni(CH₃-BDC)(3-TBT)(H₂O)₂]·EtOH·2H₂O (CP1), [Ni₃(CH3-BDC)₃(3-TBT)₂(H₂O)₅]·2DMF·2H₂O (CP2), and[Ni₃(CH₃-BDC)₃(3-TBT)₂(H₂O)₆]·2DMF·4H₂O (CP3), where CH₃-H₂BDC=5-methyl isophthalic acid, 3-TBT=2, 4, 6-tris(3-pyridyl)-1, 3, 5-benzene. X-ray single crystal diffraction analyses reveal that three CPs are constructed from similar Ni₂(CH₃-BDC)₂ binuclear units and exhibited different zero-dimensional (0D), 2D, and 3D networks, respectively. Meanwhile, the catalytic experiments show that CP3 exhibits the best catalytic activities and cycle stability for the oxidative coupling reaction of benzyl alcohol and its derivatives with aniline under solvent-free conditions.
- coordination polymers,
- solvothermal reaction,
- C₃-symmetric ligands,
- catalytic activity
1. [1]
  Zhou H C, Long J R, Yaghi O M. Introduction to metal-organic frameworks[J]. Chem. Rev., 2012,112:673-674. doi: 10.1021/cr300014x
2. [2]
  CHEN X M, ZHANG J P. Metal-organic frameworks. Beijing: Chemical Industry Press, 2016: 56-59
3. [3]
  Wang H, Liu X Y, Yang W J, Mao G Y, Meng Z, Wu Z K, Jiang H L. Surface-clean Au₂₅ nanoclusters in modulated microenvironment enabled by metal-organic frameworks for enhanced catalysis[J]. J. Am. Chem. Soc., 2022,144:22008-22017. doi: 10.1021/jacs.2c09136
4. [4]
  BAI Y F, YANG Z H, FENG Y, LIU F L, CHEN X T, CHANG J Y. Preparation and electrocatalytic performance of Zn/N co-doped carbon catalyst derived from MOF[J]. Chinese J. Inorg. Chem., 2021,37(6):1055-1061.
5. [5]
  Kang Y S, Lu Y, Chen K, Zhao Y, Wang P, Sun W Y. Metal-organic frameworks with catalytic centers: From synthesis to catalytic application[J]. Coord. Chem. Rev., 2019,378:262-280. doi: 10.1016/j.ccr.2018.02.009
6. [6]
  YANG H, WU Y Z, CUI H L, LIU L, WANG J J, CHEN X L. Three-dimensional Cd-MOF based on benzenetetracarboxilic acid and bis (imidazolylmethyl)benzene ligands: Synthesis, structure and fluorescence property[J]. Chinese J. Inorg. Chem., 2021,37(3):465-472.
7. [7]
  Yue Q, Gao E Q. Azide and carboxylate as simultaneous coupler for magnetic coordination polymers[J]. Coord. Chem. Rev., 2019,382:1-31. doi: 10.1016/j.ccr.2018.12.002
8. [8]
  LI J H, LAN T H, CHEN Y, YANG J F, LI L B, LI J P. Research progress of MOF-based composites for gas adsorption and separation[J]. CIESC Journal, 2021,72(1):167-179.
9. [9]
  ZHAO D, LIAO Z T, ZHANG W, CHEN Z Z, SUN W Y. Progress in functional metal-organic frameworks for catalytic conversion of carbon dioxide[J]. Chinese J. Inorg. Chem., 2021,37(7):1153-1176.
10. [10]
  Zhang J P, Zhou H L, Zhou D D, Liao P Q, Chen X M. Controlling flexibility of metal-organic frameworks[J]. Natl. Sci. Rev., 2018,5:907-919. doi: 10.1093/nsr/nwx127
11. [11]
  Sun Y X, Sun W Y. Influence of temperature on metal-organic frameworks[J]. Chin. Chem. Lett., 2014,25:823-828. doi: 10.1016/j.cclet.2014.04.032
12. [12]
  Liu Q, Zhang L Y, Bao Y M, Zhang N, Zhang J Y, Xing Y Y, Deng W, Liu Z J. Structures and catalytic oxidative coupling reaction of four Co-MOFs modified with R-isophthalic acid (R=H, OH and COOH) H, OH and COOH) and trigonal ligands[J]. CrystEngComm, 2021,23(43):7590-7601. doi: 10.1039/D1CE01221E
13. [13]
  Zhang Y Y, Liu Q, Zhang L Y, Bao Y M, Tan J Y, Zhang N, Zhang J Y, Liu Z J. MOFs assembled from C₃ symmetric ligands: Structure, iodine capture and role as bifunctional catalysts towards the oxidation-Knoevenagel cascade reaction[J]. Dalton Trans., 2021,50(2):647-659.
14. [14]
  Liu Q, Tan J Y, Zhang J Y, Zhang N, Deng W. R-Substituent induced structural diversity, synergistic effect and highly selective luminescence sensing for Fe³⁺ detection by post-synthetically modified Cd-MOFs[J]. CrystEngComm, 2020,22(22):3871-3883.
15. [15]
  Schmittel M, He B, Mal P. Supramolecular multicomponent self-assembly of shape-adaptive nanoprisms: Wrapping up C₆₀ with three porphyrin units[J]. Org. Lett., 2008,10(12):2513-2516.
16. [16]
  Spek A L. PLATON, A multipurpose crystallographic tool. Utrecht University, The Netherlands, 2006.
17. [17]
  Sheldrick G M. SADABS, Program for empirical absorption correction of area detector data. University of Göttingen, Germany, 1996.
18. [18]
  Sheldrick G M. SHELXTL Version 5.1. Bruker Analytical X-ray Instruments Inc., Madison, Wisconsin, USA, 1998.
19. [19]
  Pal A, Debreczeni J É, Sevvana M, Gruene T, Kahle B, Zeeck A, Sheldrick G M. Structures of viscotoxins A1 and B2 from European mistletoe solved using native data alone[J]. Acta Crystallogr. Sect. A, 2008,A64(9):985-992.
20. [20]
  Zhang N, Sun Y J, Yang H, Zhang Y J, Gao E Q. Solvothermal synthesis, structures, and magnetic properties of Ni^Ⅱ compounds directed by N, N'-bridging auxiliary ligands[J]. Inorg. Chem. Acta, 2015,428:37-43.
21. [21]
  Tan J Y, Shi J X, Cui P H, Zhang Y Y, Zhang N, Zhang J Y, Deng W. A Ni₃(OH)(COO)₆-based MOF from C₃ symmetric ligands: Structure and heterogeneous catalytic activities in one-pot synthesis of imine[J]. Microporous Mesoporous Mat., 2019,287:152-158.
22. [22]
  Chen B, Wang L Y, Gao S. Recent advances in aerobic oxidation of alcohols and amines to imines[J]. ACS Catal., 2015,5:5851-5876.
23. [23]
  Yan H J, Bai J W, Wang J, Zhang X Y, Wang B, Liu Q, Liu L H. Graphene homogeneously anchored with Ni(OH)₂ nanoparticles as advanced supercapacitor electrodes[J]. CrystEngComm, 2013,15(46):10007-10015.
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