Citation: Yu-Mei BAO, Yan-He CHEN, Yuan-Yuan XING, Jian-Yong ZHANG, Wei DENG. Syntheses, structures, and catalytic properties of three Ni(Ⅱ)-based coordination polymers from 2, 4, 6-tris(3-pyridyl)-1, 3, 5-benzene ligand[J]. Chinese Journal of Inorganic Chemistry, ;2023, 39(6): 993-1004. doi: 10.11862/CJIC.2023.074 shu

Syntheses, structures, and catalytic properties of three Ni(Ⅱ)-based coordination polymers from 2, 4, 6-tris(3-pyridyl)-1, 3, 5-benzene ligand

School of Chemical and Environmental Engineering, Shanghai Institute of Technology, Shanghai 201418, China

Corresponding author: Jian-Yong ZHANG, jianyong1106@163.com Wei DENG, wdeng@sit.edu.cn
Received Date: 29 November 2022
Revised Date: 23 April 2023

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By tuning the solvothermal reaction conditions, we prepared three Ni(Ⅱ)-based coordination polymers (CPs), namely[Ni(CH₃-BDC)(3-TBT)(H₂O)₂]·EtOH·2H₂O (CP1), [Ni₃(CH3-BDC)₃(3-TBT)₂(H₂O)₅]·2DMF·2H₂O (CP2), and[Ni₃(CH₃-BDC)₃(3-TBT)₂(H₂O)₆]·2DMF·4H₂O (CP3), where CH₃-H₂BDC=5-methyl isophthalic acid, 3-TBT=2, 4, 6-tris(3-pyridyl)-1, 3, 5-benzene. X-ray single crystal diffraction analyses reveal that three CPs are constructed from similar Ni₂(CH₃-BDC)₂ binuclear units and exhibited different zero-dimensional (0D), 2D, and 3D networks, respectively. Meanwhile, the catalytic experiments show that CP3 exhibits the best catalytic activities and cycle stability for the oxidative coupling reaction of benzyl alcohol and its derivatives with aniline under solvent-free conditions.
- coordination polymers,
- solvothermal reaction,
- C₃-symmetric ligands,
- catalytic activity
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