Citation: Yu-Mei BAO, Yan-He CHEN, Yuan-Yuan XING, Jian-Yong ZHANG, Wei DENG. Syntheses, structures, and catalytic properties of three Ni(Ⅱ)-based coordination polymers from 2, 4, 6-tris(3-pyridyl)-1, 3, 5-benzene ligand[J]. Chinese Journal of Inorganic Chemistry, ;2023, 39(6): 993-1004. doi: 10.11862/CJIC.2023.074 shu

Syntheses, structures, and catalytic properties of three Ni(Ⅱ)-based coordination polymers from 2, 4, 6-tris(3-pyridyl)-1, 3, 5-benzene ligand

School of Chemical and Environmental Engineering, Shanghai Institute of Technology, Shanghai 201418, China

Corresponding author: Jian-Yong ZHANG, jianyong1106@163.com Wei DENG, wdeng@sit.edu.cn
Received Date: 29 November 2022
Revised Date: 23 April 2023

Figures(8)

By tuning the solvothermal reaction conditions, we prepared three Ni(Ⅱ)-based coordination polymers (CPs), namely[Ni(CH₃-BDC)(3-TBT)(H₂O)₂]·EtOH·2H₂O (CP1), [Ni₃(CH3-BDC)₃(3-TBT)₂(H₂O)₅]·2DMF·2H₂O (CP2), and[Ni₃(CH₃-BDC)₃(3-TBT)₂(H₂O)₆]·2DMF·4H₂O (CP3), where CH₃-H₂BDC=5-methyl isophthalic acid, 3-TBT=2, 4, 6-tris(3-pyridyl)-1, 3, 5-benzene. X-ray single crystal diffraction analyses reveal that three CPs are constructed from similar Ni₂(CH₃-BDC)₂ binuclear units and exhibited different zero-dimensional (0D), 2D, and 3D networks, respectively. Meanwhile, the catalytic experiments show that CP3 exhibits the best catalytic activities and cycle stability for the oxidative coupling reaction of benzyl alcohol and its derivatives with aniline under solvent-free conditions.
- coordination polymers,
- solvothermal reaction,
- C₃-symmetric ligands,
- catalytic activity
1. [1]
  Zhou H C, Long J R, Yaghi O M. Introduction to metal-organic frameworks[J]. Chem. Rev., 2012,112:673-674. doi: 10.1021/cr300014x
2. [2]
  CHEN X M, ZHANG J P. Metal-organic frameworks. Beijing: Chemical Industry Press, 2016: 56-59
3. [3]
  Wang H, Liu X Y, Yang W J, Mao G Y, Meng Z, Wu Z K, Jiang H L. Surface-clean Au₂₅ nanoclusters in modulated microenvironment enabled by metal-organic frameworks for enhanced catalysis[J]. J. Am. Chem. Soc., 2022,144:22008-22017. doi: 10.1021/jacs.2c09136
4. [4]
  BAI Y F, YANG Z H, FENG Y, LIU F L, CHEN X T, CHANG J Y. Preparation and electrocatalytic performance of Zn/N co-doped carbon catalyst derived from MOF[J]. Chinese J. Inorg. Chem., 2021,37(6):1055-1061.
5. [5]
  Kang Y S, Lu Y, Chen K, Zhao Y, Wang P, Sun W Y. Metal-organic frameworks with catalytic centers: From synthesis to catalytic application[J]. Coord. Chem. Rev., 2019,378:262-280. doi: 10.1016/j.ccr.2018.02.009
6. [6]
  YANG H, WU Y Z, CUI H L, LIU L, WANG J J, CHEN X L. Three-dimensional Cd-MOF based on benzenetetracarboxilic acid and bis (imidazolylmethyl)benzene ligands: Synthesis, structure and fluorescence property[J]. Chinese J. Inorg. Chem., 2021,37(3):465-472.
7. [7]
  Yue Q, Gao E Q. Azide and carboxylate as simultaneous coupler for magnetic coordination polymers[J]. Coord. Chem. Rev., 2019,382:1-31. doi: 10.1016/j.ccr.2018.12.002
8. [8]
  LI J H, LAN T H, CHEN Y, YANG J F, LI L B, LI J P. Research progress of MOF-based composites for gas adsorption and separation[J]. CIESC Journal, 2021,72(1):167-179.
9. [9]
  ZHAO D, LIAO Z T, ZHANG W, CHEN Z Z, SUN W Y. Progress in functional metal-organic frameworks for catalytic conversion of carbon dioxide[J]. Chinese J. Inorg. Chem., 2021,37(7):1153-1176.
10. [10]
  Zhang J P, Zhou H L, Zhou D D, Liao P Q, Chen X M. Controlling flexibility of metal-organic frameworks[J]. Natl. Sci. Rev., 2018,5:907-919. doi: 10.1093/nsr/nwx127
11. [11]
  Sun Y X, Sun W Y. Influence of temperature on metal-organic frameworks[J]. Chin. Chem. Lett., 2014,25:823-828. doi: 10.1016/j.cclet.2014.04.032
12. [12]
  Liu Q, Zhang L Y, Bao Y M, Zhang N, Zhang J Y, Xing Y Y, Deng W, Liu Z J. Structures and catalytic oxidative coupling reaction of four Co-MOFs modified with R-isophthalic acid (R=H, OH and COOH) H, OH and COOH) and trigonal ligands[J]. CrystEngComm, 2021,23(43):7590-7601. doi: 10.1039/D1CE01221E
13. [13]
  Zhang Y Y, Liu Q, Zhang L Y, Bao Y M, Tan J Y, Zhang N, Zhang J Y, Liu Z J. MOFs assembled from C₃ symmetric ligands: Structure, iodine capture and role as bifunctional catalysts towards the oxidation-Knoevenagel cascade reaction[J]. Dalton Trans., 2021,50(2):647-659.
14. [14]
  Liu Q, Tan J Y, Zhang J Y, Zhang N, Deng W. R-Substituent induced structural diversity, synergistic effect and highly selective luminescence sensing for Fe³⁺ detection by post-synthetically modified Cd-MOFs[J]. CrystEngComm, 2020,22(22):3871-3883.
15. [15]
  Schmittel M, He B, Mal P. Supramolecular multicomponent self-assembly of shape-adaptive nanoprisms: Wrapping up C₆₀ with three porphyrin units[J]. Org. Lett., 2008,10(12):2513-2516.
16. [16]
  Spek A L. PLATON, A multipurpose crystallographic tool. Utrecht University, The Netherlands, 2006.
17. [17]
  Sheldrick G M. SADABS, Program for empirical absorption correction of area detector data. University of Göttingen, Germany, 1996.
18. [18]
  Sheldrick G M. SHELXTL Version 5.1. Bruker Analytical X-ray Instruments Inc., Madison, Wisconsin, USA, 1998.
19. [19]
  Pal A, Debreczeni J É, Sevvana M, Gruene T, Kahle B, Zeeck A, Sheldrick G M. Structures of viscotoxins A1 and B2 from European mistletoe solved using native data alone[J]. Acta Crystallogr. Sect. A, 2008,A64(9):985-992.
20. [20]
  Zhang N, Sun Y J, Yang H, Zhang Y J, Gao E Q. Solvothermal synthesis, structures, and magnetic properties of Ni^Ⅱ compounds directed by N, N'-bridging auxiliary ligands[J]. Inorg. Chem. Acta, 2015,428:37-43.
21. [21]
  Tan J Y, Shi J X, Cui P H, Zhang Y Y, Zhang N, Zhang J Y, Deng W. A Ni₃(OH)(COO)₆-based MOF from C₃ symmetric ligands: Structure and heterogeneous catalytic activities in one-pot synthesis of imine[J]. Microporous Mesoporous Mat., 2019,287:152-158.
22. [22]
  Chen B, Wang L Y, Gao S. Recent advances in aerobic oxidation of alcohols and amines to imines[J]. ACS Catal., 2015,5:5851-5876.
23. [23]
  Yan H J, Bai J W, Wang J, Zhang X Y, Wang B, Liu Q, Liu L H. Graphene homogeneously anchored with Ni(OH)₂ nanoparticles as advanced supercapacitor electrodes[J]. CrystEngComm, 2013,15(46):10007-10015.
1. [1]
  Xiaxia LIU , Xiaofang MA , Luxia GUO , Xianda HAN , Sisi FENG . Structure and magnetic properties of Mn(Ⅱ) coordination polymers regulated by N-auxiliary ligands. Chinese Journal of Inorganic Chemistry, 2025, 41(3): 587-596. doi: 10.11862/CJIC.20240269
2. [2]
  Long TANG , Yaxin BIAN , Luyuan CHEN , Xiangyang HOU , Xiao WANG , Jijiang WANG . Syntheses, structures, and properties of three coordination polymers based on 5-ethylpyridine-2,3-dicarboxylic acid and N-containing ligands. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1975-1985. doi: 10.11862/CJIC.20240180
3. [3]
  Peipei CUI , Xin LI , Yilin CHEN , Zhilin CHENG , Feiyan GAO , Xu GUO , Wenning YAN , Yuchen DENG . Transition metal coordination polymers with flexible dicarboxylate ligand: Synthesis, characterization, and photoluminescence property. Chinese Journal of Inorganic Chemistry, 2024, 40(11): 2221-2231. doi: 10.11862/CJIC.20240234
4. [4]
  Gaofeng WANG , Shuwen SUN , Yanfei ZHAO , Lixin MENG , Bohui WEI . Structural diversity and luminescence properties of three zinc coordination polymers based on bis(4-(1H-imidazol-1-yl)phenyl)methanone. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 849-856. doi: 10.11862/CJIC.20230479
5. [5]
  Shuwen SUN , Gaofeng WANG . Design and synthesis of a Zn(Ⅱ)-based coordination polymer as a fluorescent probe for trace monitoring 2, 4, 6-trinitrophenol. Chinese Journal of Inorganic Chemistry, 2025, 41(4): 753-760. doi: 10.11862/CJIC.20240399
6. [6]
  Zhenzhong MEI , Hongyu WANG , Xiuqi KANG , Yongliang SHAO , Jinzhong GU . Syntheses and catalytic performances of three coordination polymers with tetracarboxylate ligands. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1795-1802. doi: 10.11862/CJIC.20240081
7. [7]
  Shuwen SUN , Gaofeng WANG . Two cadmium coordination polymers constructed by varying Ⅴ-shaped co-ligands: Syntheses, structures, and fluorescence properties. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 613-620. doi: 10.11862/CJIC.20230368
8. [8]
  Yue Mao , Zhonghang Chen , Tiankai Sun , Wenyue Cui , Peng Cheng , Wei Shi . Luminescent coordination polymers with mixed carboxylate and triazole ligands for rapid detection of chloroprene metabolite. Chinese Journal of Structural Chemistry, 2024, 43(9): 100353-100353. doi: 10.1016/j.cjsc.2024.100353
9. [9]
  Dongdong YANG , Jianhua XUE , Yuanyu YANG , Meixia WU , Yujia BAI , Zongxuan WANG , Qi MA . Design and synthesis of two coordination polymers for the rapid detection of ciprofloxacin based on triphenylpolycarboxylic acid ligands. Chinese Journal of Inorganic Chemistry, 2024, 40(12): 2466-2474. doi: 10.11862/CJIC.20240266
10. [10]
  Zhenghua ZHAO , Qin ZHANG , Yufeng LIU , Zifa SHI , Jinzhong GU . Syntheses, crystal structures, catalytic and anti-wear properties of nickel(Ⅱ) and zinc(Ⅱ) coordination polymers based on 5-(2-carboxyphenyl)nicotinic acid. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 621-628. doi: 10.11862/CJIC.20230342
11. [11]
  Weizhong LING , Xiangyun CHEN , Wenjing LIU , Yingkai HUANG , Yu LI . Syntheses, crystal structures, and catalytic properties of three zinc(Ⅱ), cobalt(Ⅱ) and nickel(Ⅱ) coordination polymers constructed from 5-(4-carboxyphenoxy)nicotinic acid. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1803-1810. doi: 10.11862/CJIC.20240068
12. [12]
  Peng Meng , Qian-Cheng Luo , Aidan Brock , Xiaodong Wang , Mahboobeh Shahbazi , Aaron Micallef , John McMurtrie , Dongchen Qi , Yan-Zhen Zheng , Jingsan Xu . Molar ratio induced crystal transformation from coordination complex to coordination polymers. Chinese Chemical Letters, 2024, 35(4): 108542-. doi: 10.1016/j.cclet.2023.108542
13. [13]
  Ruiying Liu , Li Zhao , Baishan Liu , Jiayuan Yu , Yujie Wang , Wanqiang Yu , Di Xin , Chaoqiong Fang , Xuchuan Jiang , Riming Hu , Hong Liu , Weijia Zhou . Modulating pollutant adsorption and peroxymonosulfate activation sites on Co3O4@N,O doped-carbon shell for boosting catalytic degradation activity. Chinese Journal of Structural Chemistry, 2024, 43(8): 100332-100332. doi: 10.1016/j.cjsc.2024.100332
14. [14]
  Weichen WANG , Chunhua GONG , Junyong ZHANG , Yanfeng BI , Hao XU , Jingli XIE . Construction of two metal-organic frameworks by rigid bis(triazole) and carboxylate mixed-ligands and their catalytic properties for CO₂ cycloaddition reaction. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1377-1386. doi: 10.11862/CJIC.20230415
15. [15]
  Xiumei LI , Yanju HUANG , Bo LIU , Yaru PAN . Syntheses, crystal structures, and quantum chemistry calculation of two Ni(Ⅱ) coordination polymers. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 2031-2039. doi: 10.11862/CJIC.20240109
16. [16]
  Xiumei LI , Linlin LI , Bo LIU , Yaru PAN . Syntheses, crystal structures, and characterizations of two cadmium(Ⅱ) coordination polymers. Chinese Journal of Inorganic Chemistry, 2025, 41(3): 613-623. doi: 10.11862/CJIC.20240273
17. [17]
  Jialin Cai , Yizhe Chen , Ruiwen Zhang , Cheng Yuan , Zeyu Jin , Yongting Chen , Shiming Zhang , Jiujun Zhang . Interfacial Pt-N coordination for promoting oxygen reduction reaction. Chinese Chemical Letters, 2025, 36(2): 110255-. doi: 10.1016/j.cclet.2024.110255
18. [18]
  Zhendong Liu , Sainan Liu , Bin Liu , Qi Meng , Meng Yuan , Chunzheng Yang , Yulong Bian , Ping'an Ma , Jun Lin . Fe(Ⅲ)-juglone nanoscale coordination polymers for cascade chemodynamic therapy through synergistic ferroptosis and apoptosis strategy. Chinese Chemical Letters, 2024, 35(11): 109626-. doi: 10.1016/j.cclet.2024.109626
19. [19]
  Anqiu LIU , Long LIN , Dezhi ZHANG , Junyu LEI , Kefeng WANG , Wei ZHANG , Junpeng ZHUANG , Haijun HAO . Synthesis, structures, and catalytic activity of aluminum and zinc complexes chelated by 2-((2,6-dimethylphenyl)amino)ethanolate. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 791-798. doi: 10.11862/CJIC.20230424
20. [20]
  Guoping Yang , Zhoufu Lin , Xize Zhang , Jiawei Cao , Xuejiao Chen , Yufeng Liu , Xiaoling Lin , Ke Li . Assembly of Y(Ⅲ)-containing antimonotungstates induced by malic acid with catalytic activity for the synthesis of imidazoles. Chinese Chemical Letters, 2024, 35(12): 110274-. doi: 10.1016/j.cclet.2024.110274

Get Citation

PDF

XML

Metrics

PDF Downloads(8)
Abstract views(1837)
HTML views(117)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142