Citation: Yu-Mei BAO, Yan-He CHEN, Yuan-Yuan XING, Jian-Yong ZHANG, Wei DENG. Syntheses, structures, and catalytic properties of three Ni(Ⅱ)-based coordination polymers from 2, 4, 6-tris(3-pyridyl)-1, 3, 5-benzene ligand[J]. Chinese Journal of Inorganic Chemistry, ;2023, 39(6): 993-1004. doi: 10.11862/CJIC.2023.074 shu

Syntheses, structures, and catalytic properties of three Ni(Ⅱ)-based coordination polymers from 2, 4, 6-tris(3-pyridyl)-1, 3, 5-benzene ligand

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  • By tuning the solvothermal reaction conditions, we prepared three Ni(Ⅱ)-based coordination polymers (CPs), namely[Ni(CH3-BDC)(3-TBT)(H2O)2]·EtOH·2H2O (CP1), [Ni3(CH3-BDC)3(3-TBT)2(H2O)5]·2DMF·2H2O (CP2), and[Ni3(CH3-BDC)3(3-TBT)2(H2O)6]·2DMF·4H2O (CP3), where CH3-H2BDC=5-methyl isophthalic acid, 3-TBT=2, 4, 6-tris(3-pyridyl)-1, 3, 5-benzene. X-ray single crystal diffraction analyses reveal that three CPs are constructed from similar Ni2(CH3-BDC)2 binuclear units and exhibited different zero-dimensional (0D), 2D, and 3D networks, respectively. Meanwhile, the catalytic experiments show that CP3 exhibits the best catalytic activities and cycle stability for the oxidative coupling reaction of benzyl alcohol and its derivatives with aniline under solvent-free conditions.
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