Citation: Zhen WANG, Li LI, Jun-Ting ZHANG, Xiao-Long DENG, Yong-Feng LIU. High temperature performances of lithium-rich manganese ternary cathode material modified by aluminum based compounds[J]. Chinese Journal of Inorganic Chemistry, ;2023, 39(6): 1053-1060. doi: 10.11862/CJIC.2023.066 shu

High temperature performances of lithium-rich manganese ternary cathode material modified by aluminum based compounds

Zhen WANG ^{1, 2, 3,,} ,
Li LI ³ ,
Jun-Ting ZHANG ³ ,
Xiao-Long DENG ¹ ,
Yong-Feng LIU ²

1.
Postdoctoral Research Workstation of Zhejiang Geely Holding Group Co., Ltd., Hangzhou 310000, China
2.
School of Materials Science and Engineering, Zhejiang University, Hangzhou 310000, China
3.
Shandong Si-Nano Materials Technology Co. Ltd., Zibo, Shandong 255000, China

Corresponding author: Zhen WANG, hagongdawangzhen@163.com
Received Date: 24 December 2022
Revised Date: 17 April 2023

Figures(5)

To solve the problem of the electrochemical performance of lithium-rich manganese ternary cathode material (Li_1.2Ni_0.133Co_0.133Mn_0.533O₂, LR) with poor cyclic stability at high temperatures, the materials modified with Al₂O₃, AlF₃, and AlPO₄ were prepared by simple multi-phase recombination. X-ray photoelectron spectroscopy (XPS), transmission electron microscopy (TEM), and electrochemical impedance spectroscopy (EIS) were used to study the composition structure, electrochemical properties, and mechanism of the composite materials at high temperatures. The results showed that the Li_1.2Ni_0.133Co_0.133Mn_0.533O₂ modified with Al₂O₃ (LRO) had the best properties and the coating layer was thin and uniform. At 50℃, the average discharge capacity of LRO was 189.5 mAh·g^-1 for 200 cycles, and the capacity retention rate was 81.5%, which was 61.5 mAh·g^-1 and 49.8% higher than that of raw materials, respectively. The charge transfer resistance of LRO after 100 cycles was 443.1 Ω, only half of the raw materials, showing excellent electrochemical performance.
- lithium-rich manganese ternary cathode material,
- alumina,
- high temperature performance,
- lithium-ion battery
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