Citation: Zhen WANG, Li LI, Jun-Ting ZHANG, Xiao-Long DENG, Yong-Feng LIU. High temperature performances of lithium-rich manganese ternary cathode material modified by aluminum based compounds[J]. Chinese Journal of Inorganic Chemistry, ;2023, 39(6): 1053-1060. doi: 10.11862/CJIC.2023.066 shu

High temperature performances of lithium-rich manganese ternary cathode material modified by aluminum based compounds

Zhen WANG ^{1, 2, 3,,} ,
Li LI ³ ,
Jun-Ting ZHANG ³ ,
Xiao-Long DENG ¹ ,
Yong-Feng LIU ²

1.
Postdoctoral Research Workstation of Zhejiang Geely Holding Group Co., Ltd., Hangzhou 310000, China
2.
School of Materials Science and Engineering, Zhejiang University, Hangzhou 310000, China
3.
Shandong Si-Nano Materials Technology Co. Ltd., Zibo, Shandong 255000, China

Corresponding author: Zhen WANG, hagongdawangzhen@163.com
Received Date: 24 December 2022
Revised Date: 17 April 2023

Figures(5)

To solve the problem of the electrochemical performance of lithium-rich manganese ternary cathode material (Li_1.2Ni_0.133Co_0.133Mn_0.533O₂, LR) with poor cyclic stability at high temperatures, the materials modified with Al₂O₃, AlF₃, and AlPO₄ were prepared by simple multi-phase recombination. X-ray photoelectron spectroscopy (XPS), transmission electron microscopy (TEM), and electrochemical impedance spectroscopy (EIS) were used to study the composition structure, electrochemical properties, and mechanism of the composite materials at high temperatures. The results showed that the Li_1.2Ni_0.133Co_0.133Mn_0.533O₂ modified with Al₂O₃ (LRO) had the best properties and the coating layer was thin and uniform. At 50℃, the average discharge capacity of LRO was 189.5 mAh·g^-1 for 200 cycles, and the capacity retention rate was 81.5%, which was 61.5 mAh·g^-1 and 49.8% higher than that of raw materials, respectively. The charge transfer resistance of LRO after 100 cycles was 443.1 Ω, only half of the raw materials, showing excellent electrochemical performance.
- lithium-rich manganese ternary cathode material,
- alumina,
- high temperature performance,
- lithium-ion battery
1. [1]
  Winter M, Barnett B, Xu K. Before Li ion batteries[J]. Chem. Rev., 2018,118(23):11433-11456. doi: 10.1021/acs.chemrev.8b00422
2. [2]
  WANG Z X, MA J, GAO Y R, LIU S, FENG X, CHEN L Q. Stabilizing structure and performances of lithium rich layer-structured oxide cathode materials[J]. Prog. Chem., 2019,31(11):1591-1614.
3. [3]
  Wu F, Yushin G. Conversion cathodes for rechargeable lithium and lithium-ion batteries[J]. Energy Environ. Sci., 2017,10(2):435-459. doi: 10.1039/C6EE02326F
4. [4]
  Schmuch R, Wagner R, Hörpel G, Placke T, Winter M. Performance and cost of materials for lithium-based rechargeable automotive batteries[J]. Nat. Energy, 2018,3(4):267-278. doi: 10.1038/s41560-018-0107-2
5. [5]
  Xia Y, Zheng J M, Wang C M, Gu M. Designing principle for Ni-rich cathode materials with high energy density for practical applications[J]. Nano Energy, 2018,49:434-452. doi: 10.1016/j.nanoen.2018.04.062
6. [6]
  Zhang X, Ju Z Y, Zhu Y, Takeuchi K J, Takeuchi E S, Marschilok A C, Yu G H. Multiscale understanding and architecture design of high energy/power lithium-ion battery electrodes[J]. Adv. Energy Mater., 2021,11(2)2000808. doi: 10.1002/aenm.202000808
7. [7]
  Nitta N, Wu F X, Lee J T, Yushin G. Li-ion battery materials: Present and future[J]. Mater. Today, 2015,18(5):252-264. doi: 10.1016/j.mattod.2014.10.040
8. [8]
  MA C, LV Y C, LI H. Fundamental scientific aspects of lithium batteries(Ⅶ)—Positive electrode materials[J]. Energy Storage Science and Technology, 2014,3(1):53-65. doi: 10.3969/j.issn.2095-4239.2014.01.008
9. [9]
  Rossouw M H, Thackeray M M. Lithium manganese oxides from Li₂MnO₃ for rechargeable lithium battery applications[J]. Mater. Res. Bull., 1991,26(6):463-473. doi: 10.1016/0025-5408(91)90186-P
10. [10]
  Johnson C S, Korte S D, Vaughey J T, Thackeray M M, Bofinger T E, Shao-Horn Y, Hackney S A. Structural and electrochemical analysis of layered compounds from Li₂MnO₃[J]. J. Power Sources, 1999,81:491-495.
11. [11]
  Thackeray M M, Kang S H, Johnson C S, Vaughey J T, Benedek R, Hackney S A. Li₂MnO₃-stabilized LiMO₂ (M=Mn, Ni, Co) electrodes for lithium-ion batteries[J]. J. Mater. Chem., 2007,17(30):3112-3125. doi: 10.1039/b702425h
12. [12]
  YIN Z W, SUN S G. Origin of structure and voltage fade of high-capacity Li-rich Mn-rich cathode for Li-ion batteries and its solution[J]. Prog. Chem., 2022,34(6):1249-1251.
13. [13]
  YANG J G, LI Y J, LU D, CHEN Y F, SUN W W, ZHENG C M. Morphology control and lithium storage performance of micro/nano Li-rich cathode material[J]. Chem. J. Chinese University, 2019,40(7):1495-1500.
14. [14]
  WANG J Y. Multi-scale structure of high-capacity electrode materials for lithium-ion batteries. Beijing: University of Chinese Academy of Sciences (Institute of Physics, Chinese Academy of Sciences), 2022: 23-40
15. [15]
  McCalla E, Abakumov A M, Saubanère M, Foix D, Berg E J, Rousse G, Doublet M L, Gonbeau D, Novák P, Tendeloo G V, Dominko R, Tarascon J M. Visualization of O-O peroxo-like dimers in high-capacity layered oxides for Li-ion batteries[J]. Science, 2015,350(6267):1516-1521. doi: 10.1126/science.aac8260
16. [16]
  LI Z, WANG Z, BAN L Q, WANG J T, LU S G. Recent advances on surface modification of Li- and Mn-rich cathode materials[J]. Acta Chim. Sin., 2019,77(11):1115-1128.
17. [17]
  Li J, Camardese J, Shunmugasundaram R, Glazier S, Lu Z H, Dahn J R. Synthesis and characterization of the lithium-rich core-shell cathodes with low irreversible capacity and mitigated voltage fade[J]. Chem. Mater., 2015,27(9):3366-3377. doi: 10.1021/acs.chemmater.5b00617
18. [18]
  Qing R P, Shi J L, Xiao D D, Zhang X D, Yin Y X, Zhai Y B, Gu L, Guo Y G. Enhancing the kinetics of Li-rich cathode materials through the pinning effects of gradient surface Na⁺ doping[J]. Adv. Energy Mater., 2016,6(6)1501914. doi: 10.1002/aenm.201501914
19. [19]
  Hu X, Guo H J, Peng W J, Wang Z X, Li X H, Hu Q Y. Effects of Nb doping on the performance of 0.5Li₂MnO₃·0.5LiNi_1/3Co_1/3Mn_1/3O₂ cathode material for lithium-ion batteries[J]. J. Electroanal. Chem., 2018,822:57-65. doi: 10.1016/j.jelechem.2018.05.015
20. [20]
  Gao M X, Yan C H, Shao Q N, Chen J, Zhang C Y, Chen G R, Jiang Y Z, Zhu T J, Sun W P, Liu Y F, Gao M X, Pan H G. A novel perovskite electron-ion conductive coating to simultaneously enhance cycling stability and rate capability of Li_1.2Ni_0.13Co_0.13Mn_0.54O₂ cathode material for lithium-ion batteries[J]. Small, 2021,17(19)2008132.
21. [21]
  Shu W, Jian Z L, Zhou J, Zheng Y, Chen W. Boosting the electrochemical performance of Li_1.2Ni_0.13Co_0.13Mn_0.54O₂ by rough coating with the superionic conductor Li₇La₃Zr₂O₁₂[J]. ACS Appl. Mater., 2021,13(46):54916-54923.
22. [22]
  Dong S D, Zhou Y, Hai C X, Zeng J B, Sun Y X, Ma Y F, Shen Y, Li X, Ren X F, Sun C, Zhang G T, Wu Z W. Enhanced cathode performance: Mixed Al₂O₃ and LiAlO₂ coating of Li_1.2Ni_0.13Co_0.13Mn_0.54O₂[J]. ACS Appl. Mater., 2020,12(34):38153-38162.
23. [23]
  CHEN L D, ZOU W, WU L, XIA F J, HU Z Y, LI Y, SU B L. Nano-Al₂O₃ coated Li-rich cathode material Li_1.2Ni_0.13Co_0.13Mn_0.54O₂ for highly improved lithium-ion batteries[J]. Chem. J. Chinese University, 2020,41(6):1329-1336.
24. [24]
  Su Y F, Yuan F Y, Chen L, Lu Y, Dong J Y, Fang Y Y, Chen S, Wu F. Enhanced high-temperature performance of Li-rich layered oxide via surface heterophase coating[J]. J. Energy Chem., 2020,51:39-47.
25. [25]
  Li Q, Li G S, Fu C C, Luo D, Fan J M, Zheng J, Xie D J, Li L P. A study on storage characteristics of pristine Li-rich layered oxide Li_1.20Mn_0.54Co_0.13Ni_0.13O₂: Effect of storage temperature and duration[J]. Electrochim. Acta, 2015,154:249-258.
26. [26]
  Panda A, Patra J, Hsieh C T, Huange Y C, Gandomi Y A, Fu C C, Lin M H, Juang R S, Chang J K. Improving high-temperature performance of lithium-rich cathode by roll-to-roll atomic layer deposition of titania nanocoating for lithium-ion batteries[J]. J. Energy Storage, 2021,44103348.
27. [27]
  Shimoda K, Minato T, Nakanishi K, Komatsu H, Matsunaga T, Tanida H, Arai H, Ukyo Y, Uchimoto Y, Ogumi Z. Oxidation behaviour of lattice oxygen in Li-rich manganese-based layered oxide studied by hard X-ray photoelectron spectroscopy[J]. J. Mater. Chem. A, 2016,4(16):5909-5916.
1. [1]
  Liangliang Song , Haoyan Liang , Shunqing Li , Bao Qiu , Zhaoping Liu . Challenges and strategies on high-manganese Li-rich layered oxide cathodes for ultrahigh-energy-density batteries. Acta Physico-Chimica Sinica, 2025, 41(8): 100085-0. doi: 10.1016/j.actphy.2025.100085
2. [2]
  Siyu Zhang , Kunhong Gu , Bing'an Lu , Junwei Han , Jiang Zhou . Hydrometallurgical Processes on Recycling of Spent Lithium-lon Battery Cathode: Advances and Applications in Sustainable Technologies. Acta Physico-Chimica Sinica, 2024, 40(10): 2309028-0. doi: 10.3866/PKU.WHXB202309028
3. [3]
  Qi Li , Pingan Li , Zetong Liu , Jiahui Zhang , Hao Zhang , Weilai Yu , Xianluo Hu . Fabricating Micro/Nanostructured Separators and Electrode Materials by Coaxial Electrospinning for Lithium-Ion Batteries: From Fundamentals to Applications. Acta Physico-Chimica Sinica, 2024, 40(10): 2311030-0. doi: 10.3866/PKU.WHXB202311030
4. [4]
  Ying Li , Yushen Zhao , Kai Chen , Xu Liu , Tingfeng Yi , Li-Feng Chen . Rational Design of Cross-Linked N-Doped C-Sn Nanofibers as Free-Standing Electrodes towards High-Performance Li-Ion Battery Anodes. Acta Physico-Chimica Sinica, 2024, 40(3): 2305007-0. doi: 10.3866/PKU.WHXB202305007
5. [5]
  Qingtang ZHANG , Xiaoyu WU , Zheng WANG , Xiaomei WANG . Performance of nano Li₂FeSiO₄/C cathode material co-doped by potassium and chlorine ions. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1689-1696. doi: 10.11862/CJIC.20240115
6. [6]
  Xueyu Lin , Ruiqi Wang , Wujie Dong , Fuqiang Huang . Rational Design of Bimetallic Oxide Anodes for Superior Li⁺ Storage. Acta Physico-Chimica Sinica, 2025, 41(3): 2311005-0. doi: 10.3866/PKU.WHXB202311005
7. [7]
  Chenyue Huang , Hongfei Zheng , Ning Qin , Canpei Wang , Liguang Wang , Jun Lu . Single-Crystal Nickel-Rich Cathode Materials: Challenges and Strategies. Acta Physico-Chimica Sinica, 2024, 40(9): 2308051-0. doi: 10.3866/PKU.WHXB202308051
8. [8]
  Xinpeng LIU , Liuyang ZHAO , Hongyi LI , Yatu CHEN , Aimin WU , Aikui LI , Hao HUANG . Ga₂O₃ coated modification and electrochemical performance of Li_1.2Mn_0.54Ni_0.13Co_0.13O₂ cathode material. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1105-1113. doi: 10.11862/CJIC.20230488
9. [9]
  Zhihuan XU , Qing KANG , Yuzhen LONG , Qian YUAN , Cidong LIU , Xin LI , Genghuai TANG , Yuqing LIAO . Effect of graphene oxide concentration on the electrochemical properties of reduced graphene oxide/ZnS. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1329-1336. doi: 10.11862/CJIC.20230447
10. [10]
  Yuanchao LI , Weifeng HUANG , Pengchao LIANG , Zifang ZHAO , Baoyan XING , Dongliang YAN , Li YANG , Songlin WANG . Effect of heterogeneous dual carbon sources on electrochemical properties of LiMn_0.8Fe_0.2PO₄/C composites. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 751-760. doi: 10.11862/CJIC.20230252
11. [11]
  Yuting ZHANG , Zunyi LIU , Ning LI , Dongqiang ZHANG , Shiling ZHAO , Yu ZHAO . Nickel vanadate anode material with high specific surface area through improved co-precipitation method: Preparation and electrochemical properties. Chinese Journal of Inorganic Chemistry, 2024, 40(11): 2163-2174. doi: 10.11862/CJIC.20240204
12. [12]
  Yifeng Xu , Jiquan Liu , Bin Cui , Yan Li , Gang Xie , Ying Yang . “Xiao Li’s School Adventures: The Working Principles and Safety Risks of Lithium-ion Batteries”. University Chemistry, 2024, 39(9): 259-265. doi: 10.12461/PKU.DXHX202404009
13. [13]
  Xintong Zhu , Bin Cao , Chong Yan , Cheng Tang , Aibing Chen , Qiang Zhang . Advances in coating strategies for graphite anodes in lithium-ion batteries. Acta Physico-Chimica Sinica, 2025, 41(9): 100096-0. doi: 10.1016/j.actphy.2025.100096
14. [14]
  Jingshuo Zhang , Yue Zhai , Ziyun Zhao , Jiaxing He , Wei Wei , Jing Xiao , Shichao Wu , Quan-Hong Yang . Research Progress of Functional Binders in Silicon-Based Anodes for Lithium-Ion Batteries. Acta Physico-Chimica Sinica, 2024, 40(6): 2306006-0. doi: 10.3866/PKU.WHXB202306006
15. [15]
  Aoyu Huang , Jun Xu , Yu Huang , Gui Chu , Mao Wang , Lili Wang , Yongqi Sun , Zhen Jiang , Xiaobo Zhu . Tailoring Electrode-Electrolyte Interfaces via a Simple Slurry Additive for Stable High-Voltage Lithium-Ion Batteries. Acta Physico-Chimica Sinica, 2025, 41(4): 2408007-0. doi: 10.3866/PKU.WHXB202408007
16. [16]
  Junke LIU , Kungui ZHENG , Wenjing SUN , Gaoyang BAI , Guodong BAI , Zuwei YIN , Yao ZHOU , Juntao LI . Preparation of modified high-nickel layered cathode with LiAlO₂/cyclopolyacrylonitrile dual-functional coating. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1461-1473. doi: 10.11862/CJIC.20240189
17. [17]
  Jianbao Mei , Bei Li , Shu Zhang , Dongdong Xiao , Pu Hu , Geng Zhang . Enhanced Performance of Ternary NASICON-Type Na_3.5−xMn_0.5V_1.5−xZr_x (PO₄)₃/C Cathodes for Sodium-Ion Batteries. Acta Physico-Chimica Sinica, 2024, 40(12): 2407023-0. doi: 10.3866/PKU.WHXB202407023
18. [18]
  Jiaxuan Zuo , Kun Zhang , Jing Wang , Xifei Li . Nucleation Regulation and Mechanism of Precursors for Nickel Cobalt Manganese-based Cathode Materials in Lithium-Ion Batteries. Acta Physico-Chimica Sinica, 2025, 41(1): 100009-0. doi: 10.3866/PKU.WHXB202404042
19. [19]
  Xuechen Hu , Qiuying Xia , Fan Yue , Xinyi He , Zhenghao Mei , Jinshi Wang , Hui Xia , Xiaodong Huang . Electrochemical Characteristics of LiNbO₃ Anode Film and Its Applications in All-Solid-State Thin-Film Lithium-Ion Battery. Acta Physico-Chimica Sinica, 2024, 40(2): 2309046-0. doi: 10.3866/PKU.WHXB202309046
20. [20]
  Zhenming Xu , Mingbo Zheng , Zhenhui Liu , Duo Chen , Qingsheng Liu . Experimental Design of Project-Driven Teaching in Computational Materials Science: First-Principles Calculations of the LiFePO₄ Cathode Material for Lithium-Ion Batteries. University Chemistry, 2024, 39(4): 140-148. doi: 10.3866/PKU.DXHX202307022

Get Citation

PDF

XML

Metrics

PDF Downloads(3)
Abstract views(2862)
HTML views(190)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142