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Citation: Jian-Gong HUANG, Fu-Shun WAN, Cheng-Hui YE, Wen-Wen CHEN, Xin-Tong Lü, Deng-Ke CAO. Two anthracene-based Au(Ⅰ) complexes [Au(anbdtim)2]PF6 and [Au(anbdtim)2][Au(CN)2]: Structural modulation and luminescence switching[J]. Chinese Journal of Inorganic Chemistry, ;2023, 39(5): 959-966. doi: 10.11862/CJIC.2023.064 shu

Two anthracene-based Au(Ⅰ) complexes [Au(anbdtim)2]PF6 and [Au(anbdtim)2][Au(CN)2]: Structural modulation and luminescence switching

  • School of Chemistry and Chemical Engineering, Nanjing University, Nanjing 210093, China

  • Corresponding author: Deng-Ke CAO, dkcao@nju.edu.cn
  • Received Date: 30 November 2022
    Revised Date: 17 March 2023

Figures(7)

  • Two anthracene-based complexes [Au(anbdtim)2]PF6 (1) and [Au(anbdtim)2][Au(CN)2] (2) have been synthesized, where anbdtim=2-(anthracenyl)-4, 5-bis(2, 5-dimethyl(3-thienyl))-1-methyl-imidazole. The different counter anions, PF6- in 1 and [Au(CN)2]- in 2, led to significantly different fluorescence between 1 and 2 both in solution and in the solid state. Complexes 1 and 2 in CH2Cl2 revealed an emission at 465 and 445 nm, respectively, and their solidstate luminescence exhibited an emission at 450 nm for 1 and 478 nm for 2. Interestingly, the luminescence of 2 was sensitive to benzene molecules, with an emission at 475 nm (quantum yield Φ=66.5%) in benzene while 448 nm (Φ=22.9%) in CH2Cl2. Moreover, the blue-green-emitting solid 2-benzene was prepared by the evaporation of a benzene solution of complex 2. This solid exhibited reversible luminescence switching between blue-green emission at 491 nm and steel-blue emission at 460 nm upon alternately removing and incorporating benzene molecules. On the basis of these experimental results, we discussed the influence of counter anions and benzene molecules on the luminescence behaviours of 1 and 2.
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