Two anthracene-based Au(Ⅰ) complexes [Au(anbdtim)2]PF6 and [Au(anbdtim)2][Au(CN)2]: Structural modulation and luminescence switching
- Corresponding author: Deng-Ke CAO, dkcao@nju.edu.cn
Citation:
Jian-Gong HUANG, Fu-Shun WAN, Cheng-Hui YE, Wen-Wen CHEN, Xin-Tong Lü, Deng-Ke CAO. Two anthracene-based Au(Ⅰ) complexes [Au(anbdtim)2]PF6 and [Au(anbdtim)2][Au(CN)2]: Structural modulation and luminescence switching[J]. Chinese Journal of Inorganic Chemistry,
;2023, 39(5): 959-966.
doi:
10.11862/CJIC.2023.064
Babu S S, Praveen V K, Ajayaghosh A. Functional π-gelators and their applications[J]. Chem. Rev., 2014,114:1973-2129. doi: 10.1021/cr400195e
Pacheco-Linan P J, Martin C, Alonso-Moreno C, Juan A, Hermida-Merino D, Garzon-Ruiz A, Albaladejo J, Auweraer M V, Cohen B, Bravo I. The role of water and influence of hydrogen bonding on the self-assembly aggregation induced emission of an anthracene-guanidine-derivative[J]. Chem. Commun., 2020,56:4102-4105. doi: 10.1039/D0CC00990C
Liu H C, Gu Y R, Dai Y X, Wang K, Zhang S T, Chen G, Zou B, Yang B. Pressure-induced blue-shifted and enhanced emission: A cooperative effect between aggregation-induced emission and energy-transfer suppression[J]. J. Am. Chem. Soc., 2020,142:1153-1158. doi: 10.1021/jacs.9b11080
Chen J F, Gong D P, Wen J, Ma H, Cao D K. 2-(Anthracenyl)-4, 5-bis(2, 5-dimethyl(3-thienyl))-1H-imidazole: Regulatable stacking structures, reversible grinding- and heating-induced emission switching, and solid-state photodimerization behavior[J]. Chem. Sci., 2016,7:451-456. doi: 10.1039/C5SC03201F
Fudickar W, Linker T. Release of singlet oxygen from aromatic endoperoxides by chemical triggers[J]. Angew. Chem. Int. Ed., 2018,57:12971-12975. doi: 10.1002/anie.201806881
Wang M, Liu Z P, Zhou X H, Xiao H P, You Y J, Huang W. Anthracene-based lanthanide coordination polymer: Structure, luminescence, and detections of UO22+, PO43-, and 2-thiazolidinethione-4-carboxylic acid in water[J]. Inorg. Chem., 2020,59:18027-18034. doi: 10.1021/acs.inorgchem.0c02446
Zhou W L, Chen Y, Yu Q L, Li P Y, Chen X M, Liu Y. Photo-responsive cyclodextrin/anthracene/Eu3+ supramolecular assembly for a tunable photochromic multicolor cell label and fluorescent ink[J]. Chem. Sci., 2019,10:3346-3352. doi: 10.1039/C9SC00026G
(a) Yuan Q Z, Fan Q, Lv H, Chen W W, Yang X X, Cao D K, Wen J. Two anthracene-based Ir(Ⅲ) complexes[Ir(pbt)2(aip)]Cl and[Ir(pbt)2(aipm)]Cl: Relationship between substituent group and photo-oxidation activity as well as photo-oxidation-induced luminescence. Inorg. Chem., 2020, 59: 17071-17076
(b)Gao T B, Qu Z Z, Tang Z, Cao D K. Cyclometalated Ir(Ⅲ) complexes incorporating a photoactive anthracene-based ligand: Syntheses, crystal structures and luminescence switching by light irradiation. Dalton Trans., 2017, 46: 15443-15450
Li Q S, Wan C Q, Zou R Y, Xu F B, Song H B, Wan X J, Zhang Z Z. Gold(Ⅰ) η2-arene complexes[J]. Inorg. Chem., 2006,45:1888-1890. doi: 10.1021/ic051869r
Zhuo H, Chi X, Jiang M T, Xu H B, Zeng M H. Luminescence switching of organogold(Ⅰ) complexes between aggregation-induced phosphorescence enhancement and aggregation-caused quenching by balancing auxiliary ligands around the Au(Ⅰ) center[J]. Chem. Asian J., 2021,16:1165-1170. doi: 10.1002/asia.202100186
Ang P L, Nguyen V H, Yip J H K. A dynamic tetranuclear gold(Ⅰ)-cyclophane-gold(Ⅰ)-centred chirality and fluxionality arising from an intramolecular shift of Au-S bonds[J]. Dalton Trans., 2021,50:11422-11428. doi: 10.1039/D1DT01984H
Zhang D, Suzuki S, Naota T. Rapid luminescent enhancement triggered by one-shot needlestick-stimulus using a liquescent gold(Ⅰ) salt[J]. Angew. Chem. Int. Ed., 2021,60:19701-19704. doi: 10.1002/anie.202107097
Luong L M C, Lowe C D, Adams A V, Moshayedi V, Olmstead M M, Balch A L. Seeing luminescence appear as crystals crumble. Isolation and subsequent self-association of individual[(C6H11NC)2Au]+ ions in crystals[J]. Chem. Sci., 2020,11:11705-11713. doi: 10.1039/D0SC03299A
Yang J G, Li K, Wang J, Sun S S, Chi W J, Wang C, Chang X Y, Zou C, To W P, Li M D, Liu X G, Lu W, Zhang H X, Che C M, Chen Y. Controlling metallophilic interactions in chiral Au(Ⅰ) double salts towards excitation wavelength-tunable circularly polarized luminescence[J]. Angew. Chem. Int. Ed., 2020,59:6915-6922. doi: 10.1002/anie.202000792
Wu N M W, Ng M, Yam V W W. Photocontrolled multiple-state photochromic benzo[b]phosphole thieno[3, 2-b]phosphole-containing alkynyl gold(Ⅰ) complex via selective light irradiation[J]. Nat. Commun., 2022,13:33-42. doi: 10.1038/s41467-021-27711-9
Tian Z Z, Yang X L, Liu B A, Zhong D K, Zhou G J, Wang W Y. New heterobimetallic Au(Ⅰ)—Pt(Ⅱ) polyynes achieving a good trade-off between transparency and optical power limiting performance[J]. J. Mater. Chem. C, 2018,6:6023-6032. doi: 10.1039/C8TC01539B
Gong D P, Gao T B, Cao D K, Ward M D. Cyclometalated Ir(Ⅲ) complexes containing quinoline-benzimidazole-based N^N ancillary ligands: Structural and luminescence modulation by varying the substituent groups or the protonation/deprotonation state of imidazole units[J]. Dalton Trans., 2017,46:275-286. doi: 10.1039/C6DT04091H
Hattori Y, Kitajima R, Matsuoka R, Kusamoto T, Nishihara H, Uchida K. Amplification of luminescence of stable radicals by coordination to NHC-gold(Ⅰ) complex[J]. Chem. Commun., 2022,58:2560-2563. doi: 10.1039/D1CC06555F
Sathyanarayana A, Siddhant K, Yamane M, Hisano K, Prabusankar G, Tsutsumi O. Tuning the Au—Au interactions by varying the degree of polymerisation in linear polymeric Au(Ⅰ) N-heterocyclic carbene complexes[J]. J. Mater. Chem. C, 2022,10:6050-6060. doi: 10.1039/D2TC00534D
(a) Xing G H, Du T C, Liu S J, Ma Y, Zhao Q. Controlling the photophysical properties of ionic transition-metal complexes through various counterions. Chem. Commun., 2022, 58: 12286-12296
(b)Cao D K, Wei R H, Li X X, Chen J F, Ward M D. Heteroleptic Ir(Ⅲ) complexes based on 2-(2, 4-difluorophenyl)-pyridine and bisthienylethene: Structures, luminescence and photochromic properties. Dalton Trans., 2015, 44: 4289-4296
(c)Sykes D, Parker S C, Sazanovich I V, Stephenson A, Weinstein J A, Ward M D. d→f energy transfer in Ir(Ⅲ)/Eu(Ⅲ) dyads: Use of a naphthyl spacer as a spatial and energetic "stepping stone". Inorg. Chem., 2013, 52: 10500-10511
Xiaoxue Li , Hongwei Zhou , Rongrong Qian , Xu Zhang , Lei Yu . A concise synthesis of Se/Fe materials for catalytic oxidation reactions of anthracene and polyene. Chinese Chemical Letters, 2025, 36(3): 110036-. doi: 10.1016/j.cclet.2024.110036
Gaofeng WANG , Shuwen SUN , Yanfei ZHAO , Lixin MENG , Bohui WEI . Structural diversity and luminescence properties of three zinc coordination polymers based on bis(4-(1H-imidazol-1-yl)phenyl)methanone. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 849-856. doi: 10.11862/CJIC.20230479
Dan Luo , Jinya Tian , Jianqiao Zhou , Xiaodong Chi . Anthracene-bridged "Texas-sized" box for the simultaneous detection and uptake of tryptophan. Chinese Chemical Letters, 2024, 35(9): 109444-. doi: 10.1016/j.cclet.2023.109444
Yan-Kai Zhang , Yong-Zheng Zhang , Chun-Xiao Jia , Fang Wang , Xiuling Zhang , Yuhang Wu , Zhongmin Liu , Hui Hu , Da-Shuai Zhang , Longlong Geng , Jing Xu , Hongliang Huang . A stable Zn-MOF with anthracene-based linker for Cr(VI) photocatalytic reduction under sunlight irradiation. Chinese Chemical Letters, 2024, 35(12): 109756-. doi: 10.1016/j.cclet.2024.109756
Ying-Mei Zhong , Zi-Jun Xia , Yu-Hang Hu , Li-Peng Zhou , Li-Xuan Cai , Qing-Fu Sun . Effective separation of phenanthrene from isomeric anthracene using a water-soluble macrocycle-based cage. Chinese Chemical Letters, 2025, 36(4): 110164-. doi: 10.1016/j.cclet.2024.110164
Hang Meng , Bicheng Zhu , Ruolun Sun , Zixuan Liu , Shaowen Cao , Kan Zhang , Jiaguo Yu , Jingsan Xu . Dynamic photoluminescence switching of carbon nitride thin films for anticounterfeiting and encryption. Chinese Journal of Structural Chemistry, 2024, 43(10): 100410-100410. doi: 10.1016/j.cjsc.2024.100410
Guoliang Liu , Zhiqiang Liu , Anmin Zheng . Modulation of zeolite surface realizes dynamic copper species redispersion. Chinese Journal of Structural Chemistry, 2024, 43(6): 100308-100308. doi: 10.1016/j.cjsc.2024.100308
Jian Ji , Jie Yan , Honggen Peng . Modulation of dinuclear site by orbital coupling to boost catalytic performance. Chinese Journal of Structural Chemistry, 2024, 43(8): 100360-100360. doi: 10.1016/j.cjsc.2024.100360
Juhong Zhou , Hui Zhao , Ping Han , Ziyue Wang , Yan Zhang , Xiaoxia Mao , Konglin Wu , Shengjue Deng , Wenxiang He , Binbin Jiang . Strategic modulation of CoFe sites for advanced bifunctional oxygen electrocatalyst. Chinese Journal of Structural Chemistry, 2025, 44(1): 100470-100470. doi: 10.1016/j.cjsc.2024.100470
Zhaohong Chen , Mengzhen Li , Jinfei Lan , Shengqian Hu , Xiaogang Chen . Organic ferroelastic enantiomers with high Tc and large dielectric switching ratio triggered by order-disorder and displacive phase transition. Chinese Chemical Letters, 2024, 35(10): 109548-. doi: 10.1016/j.cclet.2024.109548
Yan Wang , Si-Meng Zhai , Peng Luo , Xi-Yan Dong , Jia-Yin Wang , Zhen Han , Shuang-Quan Zang . Vapor- and temperature-triggered reversible optical switching for multi-response Cu8 cluster supercrystals. Chinese Chemical Letters, 2024, 35(11): 109493-. doi: 10.1016/j.cclet.2024.109493
Hui Zhang , Rong Feng , Wanyi Yu , Hongbei Wei , Tianhong Wu , Peng Zhang , Wenhai Bian , Xin Li , Di Gao , Guojun Weng , Zhe Yang , Tony D. James , Xiaolong Sun . Evaluating the global thiols redox state in living cells using a reducing sulfur species responsive fluorescence switching platform. Chinese Chemical Letters, 2025, 36(4): 110528-. doi: 10.1016/j.cclet.2024.110528
Shihong Wu , Ronghui Zhou , Hang Zhao , Peng Wu . Sonoafterglow luminescence for in vivo deep-tissue imaging. Chinese Chemical Letters, 2024, 35(10): 110026-. doi: 10.1016/j.cclet.2024.110026
Jun-Yi Wang , Jue-Yu Bao , Zheng-Guang Wu , Zheng-Yin Du , Xunwen Xiao , Xu-Feng Luo . Recent progress in steric modulation of MR-TADF materials and doping concentration independent OLEDs with narrowband emission. Chinese Journal of Structural Chemistry, 2025, 44(1): 100451-100451. doi: 10.1016/j.cjsc.2024.100451
Yue Sun , Yingnan Zhu , Jiahang Si , Ruikang Zhang , Yalan Ji , Jinjie Fan , Yuze Dong . Glucose-activated nanozyme hydrogels for microenvironment modulation via cascade reaction in diabetic wound. Chinese Chemical Letters, 2025, 36(4): 110012-. doi: 10.1016/j.cclet.2024.110012
Xuan Zhu , Lin Zhou , Xiao-Yun Huang , Yan-Ling Luo , Xin Deng , Xin Yan , Yan-Juan Wang , Yan Qin , Yuan-Yuan Tang . (Benzimidazolium)2GeI4: A layered two-dimensional perovskite with dielectric switching and broadband near-infrared photoluminescence. Chinese Journal of Structural Chemistry, 2024, 43(6): 100272-100272. doi: 10.1016/j.cjsc.2024.100272
Yin-Hang Chai , Li-Long Dang . New structural breakthrough and topological transformation of homogeneous metalla[4]catenane compounds. Chinese Journal of Structural Chemistry, 2024, 43(10): 100322-100322. doi: 10.1016/j.cjsc.2024.100322
Fuyun Chi , Man Zhang , Yiman Han , Fukui Shen , Shijie Peng , Bo Su , Yuanyuan Hou , Gang Bai . Covalent modulation of mPGES1 activity via α,β-unsaturated aldehyde group: Implications for downregulating PGE2 expression and antipyretic response. Chinese Chemical Letters, 2025, 36(4): 109913-. doi: 10.1016/j.cclet.2024.109913
Huijie An , Chen Yang , Zhihui Jiang , Junjie Yuan , Zhongming Qiu , Longhao Chen , Xin Chen , Mutu Huang , Linlang Huang , Hongju Lin , Biao Cheng , Hongjiang Liu , Zhiqiang Yu . Luminescence-activated Pt(Ⅳ) prodrug for in situ triggerable cancer therapy. Chinese Chemical Letters, 2024, 35(7): 109134-. doi: 10.1016/j.cclet.2023.109134
Chaohui Zheng , Jing Xi , Shiyi Long , Tianpei He , Rui Zhao , Xinyuan Luo , Na Chen , Quan Yuan . Persistent luminescence encoding for rapid and accurate oral-derived bacteria identification. Chinese Chemical Letters, 2025, 36(1): 110223-. doi: 10.1016/j.cclet.2024.110223
All H atoms attached to carbon atoms are omitted for clarity; Symmetr code: A: 1-x, y, 0.5-z
c=0.1 mmol·L-1, λex=380 nm for 1, 361 nm for 2, and 367 nm for anbdtim; Inset: photographs of solutions of the compounds
c=0.1 mmol·L-1, λex=361 nm
Inset: photographs of 1 and 2 under 365 nm light
Inset: photographs of 2-benzene under 365 nm light upon alternating heating treatment and crystallization from benzene