Citation: Yan-Yan AN, Li-Ping LU, Miao-Li ZHU. One Cd^Ⅱ-MOF as a multi-responsive fluorescent probe for sensing Fe(Ⅲ) and Cr(Ⅵ)[J]. Chinese Journal of Inorganic Chemistry, ;2023, 39(5): 939-946. doi: 10.11862/CJIC.2023.056 shu

One Cd^Ⅱ-MOF as a multi-responsive fluorescent probe for sensing Fe(Ⅲ) and Cr(Ⅵ)

Yan-Yan AN ^1,, ,
Li-Ping LU ² ,
Miao-Li ZHU ^2,,

1.
Department of Materials and Chemical Engineering, Taiyuan University, Taiyuan 030032, China
2.
Key Laboratory of Chemical Biology and Molecular Engineering of the Education Ministry, Institute of Molecular Science, Shanxi University, Taiyuan 030006, China

Corresponding author: Yan-Yan AN, anyanyan@tyu.edu.cn Miao-Li ZHU, miaoli@sxu.edu.cn
Received Date: 2 November 2022
Revised Date: 15 March 2023

Figures(7)

One metal-organic framework [Cd₃(L)₂(H₂O)₉]·9H₂O (MOF 1), where H₃L=5-(((4-carboxyphenyl)oxy)methyl) benzene-1,3-dicarboxylic acid, has been hydrothermally synthesized and characterized by single-crystal X-ray diffraction, powder X-ray diffraction, and elemental analysis. MOF 1 exhibits a 2D microporous structure with an accessible volume of 22.4%. Luminescent property studies reveal that MOF 1 can act as a promising luminescent sensor for detecting Fe(Ⅲ) and Cr(Ⅵ) with high selectivities and low detection limits, which are additionally free from the interference of other ions. Moreover, the mechanism of selective quenching was studied by measuring the UV-Vis absorption of the host metal-organic framework and the target analyte ions. The fluorescence resonance energy transfer is the possible mechanism involved in the quenching of the fluorescence intensity.
- 5-(((4-carboxyphenyl)oxy)methyl)benzene-1,3-dicarboxylic acid,
- Cd^Ⅱ complex,
- crystal structure,
- fluorescence probe
1. [1]
  Li L, Lin R B, Krishna R, Li H, Xiang S, Wu H, Li J, Zhou W, Chen B. Ethane/ethylene separation in a metal-organic framework with ironperoxo sites[J]. Science, 2018,362:443-446. doi: 10.1126/science.aat0586
2. [2]
  Liu X P, Fan W D, Zhang M H, Li G X, Liu H J, Sun D F, Zhao L M, Zhu H Y, Guo W Y. Enhancing light hydrocarbon storage and separation through introducing Lewis basic nitrogen sites within a carboxylate-decorated copper-organic framework[J]. Mater. Chem. Front., 2018,2:1146-1154. doi: 10.1039/C8QM00105G
3. [3]
  Oar-Arteta L, Wezendonk T, Sun X H, Kapteijn F, Gascon J. Metal organic frameworks as precursors for the manufacture of advanced catalytic materials[J]. Mater. Chem. Front., 2017,1:1709-1745. doi: 10.1039/C7QM00007C
4. [4]
  Sun Y, Zhang N, Guan Q L, Liu C H, Li B, Zhang K Y, Li G H, Xing Y H, Bai F Y, Sun L X. Sensing of Fe³⁺ and Cr₂O₇^2- in water and white light: Synthesis characterization and fluorescence properties of a crystalline bismuth-1,3,5-benzenetricarboxylic acid framework[J]. Cryst. Growth Des., 2019,19:7217-7229. doi: 10.1021/acs.cgd.9b01098
5. [5]
  ZHANG Q, ZHANG G W, CHENG J Y, LU W X, WANG P. Synthesis, crystal structure and fluorescence emission properties of Cd(Ⅱ) and Pb(Ⅱ) MOFs based on hydroxyethoxy isophthalate acid[J]. Chinese J. Inorg. Chem., 2020,36(11):2063-2070.
6. [6]
  Goswami S, Leitus G, Tripuramallu B K, Goldberg I. Mn^Ⅱ and Co^Ⅱ coordination polymers showing field-dependent magnetism and slow magnetic relaxation behavior[J]. Cryst. Growth Des., 2017,17:4393-4404. doi: 10.1021/acs.cgd.7b00696
7. [7]
  Feng C, Lv C P, Zhao H, Li Z Q, Xie W N, Sun L N, Wang Y C. Structural elucidation and supercapacitive performance on a Mn(Ⅱ)-based MOF[J]. Cryst. Growth Des., 2020,20:5682-5687. doi: 10.1021/acs.cgd.9b01013
8. [8]
  Lin X M, Niu J L, Chen D N, Lu Y N, Zhang G, Cai Y P. Four metalorganic frameworks based on a semirigid tripodal ligand and different secondary building units: Structures and electrochemical performance[J]. CrystEngComm, 2016,18:6841-6848. doi: 10.1039/C6CE01068G
9. [9]
  Wang Q S, Li J J, Zhang M N, Li X. A luminescent Eu(Ⅲ)-based metalorganic framework as a highly effective sensor for cation and anion detections[J]. Sens. Actuators B-Chem., 2018,258:358-364. doi: 10.1016/j.snb.2017.11.075
10. [10]
  Diamantis S A, Margariti A, Pournara A D, Papaefstathiou G S, Manos M J, Lazarides T. Luminescent metal-organic frameworks as chemical sensors: Common pitfalls and proposed best practices[J]. Inorg. Chem. Front., 2018,5:1493-1511.
11. [11]
  Fard Z H, Kalinovskyy Y, Spasyuk D M, Blight B A, Shimizu G K. Alkaline-earth phosphonate MOFs with reversible hydration-dependent fluorescence[J]. Chem. Commun., 2016,52:12865-12868. doi: 10.1039/C6CC06490F
12. [12]
  Cao Y Y, Guo X F, Wang H. High sensitive luminescence metalorganic framework sensor for hydrogen sulfide in aqueous solution: A trial of novel turn-on mechanism[J]. Sens. Actuators B-Chem., 2017,243:8-13. doi: 10.1016/j.snb.2016.11.085
13. [13]
  Wang X N, Li J L, Jiang C G, Hu P, Li B, Zhang T L, Zhou H C. An efficient strategy for improving the luminescent sensing performance of a terbium(Ⅲ) metal-organic framework towards multiple substances[J]. Chem. Commun., 2018,54:13271-13274. doi: 10.1039/C8CC07369D
14. [14]
  Wang G Y, Song C, Kong D M, Ruan W J, Chang Z, Li Y. Two luminescent metal-organic frameworks for the sensing of nitroaromatic explosives and DNA strands[J]. J. Mater. Chem. A, 2014,2:2213-2220. doi: 10.1039/C3TA14199C
15. [15]
  Chen L L, Xu H, Wang L, Li Y, Tian X K. Portable ratiometric probe based on the use of europium(Ⅲ) coordination polymers doped with carbon dots for visual fluorometric determination of oxytetracy[J]. Microchim. Acta, 2020,187125. doi: 10.1007/s00604-019-4104-3
16. [16]
  Cook T R, Zheng Y R, Stang P J. Metal-organic frameworks and selfassembled supramolecular coordination complexes: Comparing and contrasting the design synthesis and functionality of metal-organic materials[J]. Chem. Rev., 2013,113:734-777. doi: 10.1021/cr3002824
17. [17]
  LI Y L, ZHAO Y, SUN W Y. Two Zn and Cd metal-organic frameworks with mixed ligands: Synthesis, structure, sorption and luminescent properties[J]. Chinese J. Inorg. Chem., 2020,36(6):1176-1184.
18. [18]
  Acharyya K, Mukherjee P S. A fluorescent organic cage for picric acid detection[J]. Chem. Commun., 2014,50:15788-15791. doi: 10.1039/C4CC06225F
19. [19]
  Wu J X, Yan B. A dual-emission probe to detect moisture and water in organic solvents based on green-Tb³⁺ post-coordinated metalorganic frameworks with red carbon dots[J]. Dalton Trans., 2017,46:7098-7105. doi: 10.1039/C7DT01352C
20. [20]
  Zhou J M, Shi W, Li H M, Li H, Cheng P. Experimental studies and mechanism analysis of high-sensitivity luminescent sensing of pollutional small molecules and ions in Ln₄O₄ cluster based microporous metal-organic frameworks[J]. J. Phys. Chem. C, 2014,118:416-426. doi: 10.1021/jp4097502
21. [21]
  Cheung W, Patel M, Ma Y F, Chen Y, Xie Q Q, Lockard J V, Gao Y, He H X. π-Plasmon absorption of carbon nanotubes for the selective and sensitive detection of Fe³⁺ ions[J]. Chem. Sci., 2016,7:5192-5199. doi: 10.1039/C6SC00006A
22. [22]
  Li M F, Fang H B, Ji Y F, Chen Y C, He W J, Guo Z J. Rational design of ratiometric Fe³⁺ fluorescent probes based on FRET mechanism[J]. Chem. Res. Chin. Univ., 2022,38:67-74. doi: 10.1007/s40242-021-1398-6
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通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

One CdⅡ-MOF as a multi-responsive fluorescent probe for sensing Fe(Ⅲ) and Cr(Ⅵ)

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通讯作者: 陈斌, bchen63@163.com

One Cd^Ⅱ-MOF as a multi-responsive fluorescent probe for sensing Fe(Ⅲ) and Cr(Ⅵ)