Citation: Xue-Qin GUO, Xiao-Chuan DENG, Chao-Liang ZHU, Xin FU, Rui-Rui WANG, Wan-Xia MA, Jie FAN, Fang-Tao ZUO, Bin-Ju QING. Preparation and adsorption properties for Cs⁺ of modified diatomite-supported copper hexacyanoferrate composite[J]. Chinese Journal of Inorganic Chemistry, ;2023, 39(5): 815-829. doi: 10.11862/CJIC.2023.043 shu

Preparation and adsorption properties for Cs⁺ of modified diatomite-supported copper hexacyanoferrate composite

Xue-Qin GUO ^{1, 2, 3} ,
Xiao-Chuan DENG ^{1, 2} ,
Chao-Liang ZHU ^{1, 2} ,
Xin FU ⁴ ,
Rui-Rui WANG ^{1, 2, 3} ,
Wan-Xia MA ^{1, 2} ,
Jie FAN ^{1, 2} ,
Fang-Tao ZUO ^{1, 2} ,
Bin-Ju QING ^{1, 2,,}

1.
Key Laboratory of Comprehensive and Highly Efficient Utilization of Salt Lake Resources, Qinghai Institute of Salt Lakes, Chinese Academy of Sciences, Xining 810008, China
2.
Qinghai Engineering and Technology Research Center of Comprehensive Utilization of Salt Lake Resources, Xining 810008, China
3.
University of Chinese Academy of Sciences, Beijing 100049, China
4.
Hangzhou Water Treatment Technology Development Center, Hangzhou 310012, China

Corresponding author: Bin-Ju QING, qbj@isl.ac.cn
Received Date: 18 October 2022
Revised Date: 13 March 2023

Figures(18)

Herein, aluminum chloride was used as the aluminum source to modify diatomite (De) by hydrothermal method. Copper hexacyanoferrate (KCuHCF) nanoparticles were loaded onto the surface of modified De by the impregnation method, and two composite adsorbents, γ-AlOOH/De-KCuHCF and γ-Al₂O₃/De-KCuHCF, were prepared. The prepared materials were characterized and used for Cs⁺ adsorption. The results showed that the prepared adsorbents had better adsorption performance for Cs⁺. The maximum adsorption capacity can reach 75.44 and 84.02 mg·g^-1, respectively. The desorption rate of γ-Al₂O₃/De-KCuHCF can reach 81.88% after three consecutive desorption with 3 mol·L^-1 NH₄NO₃ as the desorption solution and the Cs⁺ adsorption rate of γ-Al₂O₃/De-KCuHCF in simulated brines was as high as 97.55%. After five adsorption-desorption cycles the adsorption capacity remained high. The adsorption kinetic process and adsorption isotherm model of the prepared adsorbent were also analyzed. The results showed that the adsorption process was in line with the quasi-second-order kinetic model, which was controlled by the intra-particle diffusion and liquid film diffusion, and was in line with the Langmuir adsorption isotherm model.
- aluminium chloride,
- diatomite,
- copper hexacyanoferrate,
- Cs⁺ adsorption
1. [1]
  HUANG W F, LI X D. Applications and up-to-date development of extraction separation technology of Cs[J]. Rare Metals and Cemented Carbides, 2003,31(3):18-20. doi: 10.3969/j.issn.1004-0536.2003.03.006
2. [2]
  LIANG C J. Experimental investigation on extraction of rubidium and cesium from dolomite containing rubidium and cesium. Guizhou: Guizhou University, 2016: 1-3
3. [3]
  LIU L. Development and thinking of rubidium cesium[J]. Xinjiang Youse Jinshu, 2013,36(6):46-50. doi: 10.16206/j.cnki.65-1136/tg.2013.06.043
4. [4]
  ZHENG X Y, ZHANG M G, XU X. Annals of salt lakes in China. Beijing: Science Press, 2002: 105-130
5. [5]
  Ye X S, Wu Z J, Li W. Rubidium and cesium ion adsorption by an ammonium molybdophosphate-calcium alginate composite adsorbent[J]. Colloid Surf. A-Physicochem. Eng. Asp., 2009,342(1/2/3):76-83.
6. [6]
  Yang J Y, Luo X G, Yan T S. Recovery of cesium from saline lake brine with potassium cobalt hexacyanoferrate‑modified chrome‑tanned leather scrap adsorbent[J]. Colloid Surf. A‐Physicochem. Eng. Asp., 2017,537:268-280.
7. [7]
  Xing P, Wang C, Chen Y, Ma B. Rubidium extraction from mineral and brine resources: A review[J]. Hydrometallurgy, 2021,203105644. doi: 10.1016/j.hydromet.2021.105644
8. [8]
  Chen S Q, Hu J Y, Senjian H. A review on emerging composite materials for cesium adsorption and environmental remediation on the latest decade[J]. Sep. Purif. Technol., 2020,15(251)117340.
9. [9]
  Loos N C, Ayrault S, Badillo V. Structure of copper-potassium hexacyanoferrate(Ⅱ) and sorption mechanisms of cesium[J]. J. Solid State Chem., 2004,177(6):1817-1828. doi: 10.1016/j.jssc.2004.01.018
10. [10]
  Wang J L, Zhuang S T, Liu Y. Metal hexacyanoferrates-based adsorbents for cesium removal[J]. Coord. Chem. Rev., 2018,374:430-438. doi: 10.1016/j.ccr.2018.07.014
11. [11]
  Dong C C, Deng X C, Guo X Q, Wang B, Ye X S, Fan J, Qing B J. Synthesis of potassium metal ferrocyanide/Al-MCM-41 with fast and selective adsorption of cesium[J]. Colloid Surf. A-Physicochem. Eng. Asp., 2021,613126107. doi: 10.1016/j.colsurfa.2020.126107
12. [12]
  Jung Y K, Choi U S, Ko Y G. Securely anchored prussian blue nanocrystals on the surface of porous PAAm sphere for high and selective cesium removal[J]. J. Hazard. Mater., 2021,420126654. doi: 10.1016/j.jhazmat.2021.126654
13. [13]
  Yuan P, Liu D, Tan D Y, Liu K K, Yu H G, Zhong Y H, Yuan A H, Yu W B, He H P. Surface silylation of mesoporous/macroporous diatomite (diatomaceous earth) and its function in Cu(Ⅱ) adsorption: The effects of heating pretreatment[J]. Microporous Mesoporous Mat., 2013,170:9-19. doi: 10.1016/j.micromeso.2012.11.030
14. [14]
  Wang X K, Wang J S, Teng W L, Du Y C, Wu J S, Guo F, Chen B B. Fabrication of highly efficient magnesium silicate and its adsorption behavior towards Cr(Ⅵ)[J]. Microporous Mesoporous Mat., 2021,323:1387-1811.
15. [15]
  DU Y C, LI S H, GU H X, LI Y, WU J S, JIN C X. Mercapto/carboxyl modified diatomite: Adsorption properties to Pb(Ⅱ) and Cd(Ⅱ)[J]. Chinese J. Inorg. Chem., 2021,37(1):65-73.
16. [16]
  JIN C X, DU Y C, WU J S, NIU Y, WANG X K, LI Y. In-situ growing nanostructured magnesium silicate on diatomite: Adsorption properties of Cr(Ⅵ)[J]. Chinese J. Inorg. Chem., 2019,35(4):621-628.
17. [17]
  Du Y C, Zhen S, Wang J S, Ma Y L, Wu J S, Dai H X. FeOOH-MnO₂/Sepiolite and Fe₂O₃-MnO₂/Diatomite: Highly efficient adsorbents for the removal of As(Ⅴ)[J]. Appl. Clay Sci., 2022,222106491. doi: 10.1016/j.clay.2022.106491
18. [18]
  ZHENG G W, DU Y C, HOU R Q, SUN G B, WANG J S, WU J S. Fabrication and highly efficient adsorption for Cs⁺ and Pb²⁺ of γ-AlOOH/Al₂O₃ modified diatomite[J]. Chinese J. Inorg. Chem., 2015,31(5):930-938.
19. [19]
  Mathieu Y, Vidal L, Valtchev V, Lebeau B. Preparation of γ-Al₂O₃ film by high temperature transformation of nanosized γ-AlOOH precursors[J]. New J. Chem., 2009,33(11):2255-2260. doi: 10.1039/b9nj00351g
20. [20]
  Miao Y E, Wang R Y, Chen D, Liu Z Y, Liu T X. Electrospun self-standing membrane of hierarchical SiO@γ-AlOOH (Boehmite) core/sheath fibers for water remediation[J]. ACS Appl. Mater. Interfaces, 2012,4(10):5353-5359. doi: 10.1021/am3012998
21. [21]
  Jbara A S, Othaman Z, Ati A A, Saeed M A. Characterization of γ-Al₂O₃ nanopowders synthesized by co-precipitation method[J]. Mater. Chem. Phys., 2017,188:24-29. doi: 10.1016/j.matchemphys.2016.12.015
22. [22]
  Wang Z J, Du H, Gong J H, Yang S G, Ma J H, Xu J. Facile synthesis of hierarchical flower-like γ-AlOOH films via hydrothermal route on quartz surface[J]. Colloid Surf. A-Physicochem. Eng. Asp., 2014,450:76-82. doi: 10.1016/j.colsurfa.2014.03.014
23. [23]
  Zong Y L, Zhang Y D, Lin X Y, Ye D, Qiao D, Zeng S N. Facile synthesis of potassium copper ferrocyanide composite particles for selective cesium removal from wastewater in the batch and continuous processes[J]. RSC Adv., 2017,7(54):31352-31364.
24. [24]
  Hu J Y, Chen S Q, Zhang N L, Wang Z, Guo Y F, Deng T L. Porous composite sphere CMC-KCuFC-PEG for efficient cesium removal from wastewater[J]. New J. Chem., 2019,43(24):9658-9665. doi: 10.1039/C9NJ01697J
25. [25]
  Xiang S L, Zhang X, Tao Q Q, Dai Y. Adsorption of cesium on mesoporous SBA-15 material containing embedded copper hexacyanoferrate[J]. J. Radioanal. Nucl. Chem., 2019,320(3):609-619. doi: 10.1007/s10967-019-06523-8
26. [26]
  Mohammadi S, Faghihian H. Elimination of Cs⁺ from aquatic systems by an adsorbent prepared by immobilization of potassium copper hexacyanoferrate on the SBA-15 surface: Kinetic, thermodynamic, and isotherm studies[J]. Environ. Sci. Pollut. Res., 2019,26(12):12055-12070. doi: 10.1007/s11356-019-04623-2
27. [27]
  Kim Y, Eom H H, Kim D H, Harbottle D, Lee J W. Adsorptive removal of cesium by electrospun nanofibers embedded with potassium copper hexacyanoferrate[J]. Sep. Purif. Technol., 2021,255117745. doi: 10.1016/j.seppur.2020.117745
28. [28]
  Nayl A A, Ahmed I M, Abd-Elhamid A I, Aly H F, Attallah M F. Selective sorption of ¹³⁴Cs and ⁶⁰Co radioisotopes using synthetic nanocopper ferrocyanide-SiO₂ materials[J]. Sep. Purif. Technol., 2020,234116060. doi: 10.1016/j.seppur.2019.116060
29. [29]
  Zhang H G, Hodges C S, Mishra P K, Yoon J Y, Hunter T N, Lee J W, Harbottle D. Bio-inspired preparation of clay-hexacyanoferrate composite hydrogels as super adsorbents for Cs⁺[J]. ACS Appl. Mater. Interfaces, 2020,12(29):33173-33185. doi: 10.1021/acsami.0c06598
30. [30]
  Seo Y, Hwang Y. Prussian blue immobilized on covalent organic polymer-grafted granular activated carbon for cesium adsorption from water[J]. J. Environ. Chem. Eng., 2021,9(5)105950. doi: 10.1016/j.jece.2021.105950
31. [31]
  Kim Y, Eom H H, Kim Y K, Harbottle D, Lee J W. Effective removal of cesium from wastewater via adsorptive filtration with potassium copper hexacyanoferrate-immobilized and polyethyleneimine-grafted graphene oxide[J]. Chemosphere, 2020,250126262. doi: 10.1016/j.chemosphere.2020.126262
32. [32]
  Chen S Q, Dong Y N, Wang H H, Sun J J, Wang J F, Zhang S J, Dong H F. Highly efficient and selective cesium recovery from natural brine resources using mesoporous Prussian blue analogs synthesized by ionic liquid-assisted strategy[J]. Resour. Conserv. Recycl., 2022,186106542. doi: 10.1016/j.resconrec.2022.106542
1. [1]
  Limei CHEN , Mengfei ZHAO , Lin CHEN , Ding LI , Wei LI , Weiye HAN , Hongbin WANG . Preparation and performance of paraffin/alkali modified diatomite/expanded graphite composite phase change thermal storage material. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 533-543. doi: 10.11862/CJIC.20230312
2. [2]
  Peng GENG , Guangcan XIANG , Wen ZHANG , Haichuang LAN , Shuzhang XIAO . Hollow copper sulfide loaded protoporphyrin for photothermal-sonodynamic therapy of cancer cells. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1903-1910. doi: 10.11862/CJIC.20240155
3. [3]
  Qiuping Liu , Yongxian Fan , Wenxian Chen , Mengdi Wang , Mei Mei , Genrong Qiang . Design of Ideological and Political Education for the Preparation Experiment of Ferrous Sulfate. University Chemistry, 2024, 39(2): 116-120. doi: 10.3866/PKU.DXHX202309083
4. [4]
  Juan Guo , Mingyuan Fang , Qingsong Liu , Xiao Ren , Yongqiang Qiao , Mingju Chao , Erjun Liang , Qilong Gao . Zero thermal expansion in Cs₂W₃O₁₀. Chinese Chemical Letters, 2024, 35(7): 108957-. doi: 10.1016/j.cclet.2023.108957
5. [5]
  Jihua Deng , Xinshi Wu , Dichang Zhong . Exploration of Green Teaching and Ideological and Political Education in Chemical Experiment of “Preparation of Ammonium Ferrous Sulfate”. University Chemistry, 2024, 39(10): 325-329. doi: 10.12461/PKU.DXHX202405046
6. [6]
  Zhuoya WANG , Le HE , Zhiquan LIN , Yingxi WANG , Ling LI . Multifunctional nanozyme Prussian blue modified copper peroxide: Synthesis and photothermal enhanced catalytic therapy of self-provided hydrogen peroxide. Chinese Journal of Inorganic Chemistry, 2024, 40(12): 2445-2454. doi: 10.11862/CJIC.20240194
7. [7]
  Pan Liu , Yanming Sun , Alberto J. Fernández-Carrión , Bowen Zhang , Hui Fu , Lunhua He , Xing Ming , Congling Yin , Xiaojun Kuang . Bismuth-based halide double perovskite Cs₂KBiCl₆: Disorder and luminescence. Chinese Chemical Letters, 2024, 35(5): 108641-. doi: 10.1016/j.cclet.2023.108641
8. [8]
  Kai Han , Guohui Dong , Ishaaq Saeed , Tingting Dong , Chenyang Xiao . Boosting bulk charge transport of CuWO4 photoanodes via Cs doping for solar water oxidation. Chinese Journal of Structural Chemistry, 2024, 43(2): 100207-100207. doi: 10.1016/j.cjsc.2023.100207
9. [9]
  Meng Wang , Yan Zhang , Yunbo Yu , Wenpo Shan , Hong He . High-temperature calcination dramatically promotes the activity of Cs/Co/Ce-Sn catalyst for soot oxidation. Chinese Chemical Letters, 2025, 36(1): 109928-. doi: 10.1016/j.cclet.2024.109928
10. [10]
  Rong Tian , Yadi Yang , Naihao Lu . Comprehensive Experimental Design of Undergraduate Students Based on Interdisciplinarity: Study on the Effect of Quercetin on Chlorination Activity of Myeloperoxidase. University Chemistry, 2024, 39(8): 247-254. doi: 10.3866/PKU.DXHX202312064
11. [11]
  Xiaosong PU , Hangkai WU , Taohong LI , Huijuan LI , Shouqing LIU , Yuanbo HUANG , Xuemei LI . Adsorption performance and removal mechanism of Cd(Ⅱ) in water by magnesium modified carbon foam. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1537-1548. doi: 10.11862/CJIC.20240030
12. [12]
  Jingke LIU , Jia CHEN , Yingchao HAN . Nano hydroxyapatite stable suspension system: Preparation and cobalt adsorption performance. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1763-1774. doi: 10.11862/CJIC.20240060
13. [13]
  Ping ZHANG , Chenchen ZHAO , Xiaoyun CUI , Bing XIE , Yihan LIU , Haiyu LIN , Jiale ZHANG , Yu'nan CHEN . Preparation and adsorption-photocatalytic performance of ZnAl@layered double oxides. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1965-1974. doi: 10.11862/CJIC.20240014
14. [14]
  Fang Niu , Rong Li , Qiaolan Zhang . Analysis of Gas-Solid Adsorption Behavior in Resistive Gas Sensing Process. University Chemistry, 2024, 39(8): 142-148. doi: 10.3866/PKU.DXHX202311102
15. [15]
  Jiali CHEN , Guoxiang ZHAO , Yayu YAN , Wanting XIA , Qiaohong LI , Jian ZHANG . Machine learning exploring the adsorption of electronic gases on zeolite molecular sieves. Chinese Journal of Inorganic Chemistry, 2025, 41(1): 155-164. doi: 10.11862/CJIC.20240408
16. [16]
  Fei Xie , Chengcheng Yuan , Haiyan Tan , Alireza Z. Moshfegh , Bicheng Zhu , Jiaguo Yu . d带中心调控过渡金属单原子负载COF吸附O₂的理论计算研究. Acta Physico-Chimica Sinica, 2024, 40(11): 2407013-. doi: 10.3866/PKU.WHXB202407013
17. [17]
  Hong Chen , Mao-Yin Ran , Long-Hua Li , Xin-Tao Wu , Hua Lin . [Cs14Cl][Tm71Se110]: An unusual salt-inclusion chalcogenide containing different valent Tm centers and ultralow thermal conductivity. Chinese Journal of Structural Chemistry, 2024, 43(10): 100397-100397. doi: 10.1016/j.cjsc.2024.100397
18. [18]
  Zhijie Zhang , Xun Li , Huiling Tang , Junhao Wu , Chunxia Yao , Kui Li . Cs₂CuBr₄ perovskite quantum dots confined in mesoporous CuO framework as a p-n type S-scheme heterojunction for efficient CO₂ photoconversion. Chinese Chemical Letters, 2024, 35(11): 109700-. doi: 10.1016/j.cclet.2024.109700
19. [19]
  Yuan Teng , Zichun Zhou , Jinghua Chen , Siying Huang , Hongyan Chen , Daibin Kuang . Dual atom-bridge effect promoting interfacial charge transfer in 2D/2D Cs₃Bi₂Br₉/BiOBr epitaxial heterojunction for efficient photocatalysis. Chinese Chemical Letters, 2025, 36(2): 110430-. doi: 10.1016/j.cclet.2024.110430
20. [20]
  Jie ZHAO , Sen LIU , Qikang YIN , Xiaoqing LU , Zhaojie WANG . Theoretical calculation of selective adsorption and separation of CO₂ by alkali metal modified naphthalene/naphthalenediyne. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 515-522. doi: 10.11862/CJIC.20230385

Get Citation

PDF

XML

Metrics

PDF Downloads(2)
Abstract views(798)
HTML views(127)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Preparation and adsorption properties for Cs+ of modified diatomite-supported copper hexacyanoferrate composite

Metrics

通讯作者: 陈斌, bchen63@163.com

Preparation and adsorption properties for Cs⁺ of modified diatomite-supported copper hexacyanoferrate composite