Citation: Ming GAO, Tong-Qing ZHANG, Jian-Jun LI, Jia-Qi HU, Ming-Yan JIN, Yan ZHAO, Hong-Yang WANG, Chang-Guo XUE. Preparition and multiple-dye adsorption of magnetic chitosan/Fe₃O₄/graphene oxide adsorbent[J]. Chinese Journal of Inorganic Chemistry, ;2023, 39(4): 723-734. doi: 10.11862/CJIC.2023.042 shu

Preparition and multiple-dye adsorption of magnetic chitosan/Fe₃O₄/graphene oxide adsorbent

Ming GAO ¹ ,
Tong-Qing ZHANG ² ,
Jian-Jun LI ^{1, 2, 3,,} ,
Jia-Qi HU ¹ ,
Ming-Yan JIN ¹ ,
Yan ZHAO ^{1, 3,,} ,
Hong-Yang WANG ¹ ,
Chang-Guo XUE ^{1, 3}

1.
Department of Materials Science and Engineering, Anhui University of Science and Technology, Huainan, Anhui 232001, China
2.
Shenzhen Green Ring Renewable Resources Development Co. LTD., Shenzhen, Guangdong 518125, China
3.
Anhui International Joint Research Center for Nano Carbon-Based Materials and Environmental Health, Huainan, Anhui 232001, China

Corresponding author: Jian-Jun LI, ljjhero4@gmail.com Yan ZHAO, 363990474@qq.com
Received Date: 24 August 2022
Revised Date: 9 March 2023

Figures(8)

To improve the multiple-dye adsorption performance of the adsorbent and endow it with magnetism, a magnetic composite adsorbent composed of chitosan, magnetite nanoparticles, and graphene oxide (CS/Fe₃O₄/GO) was prepared by a simple co-precipitation method.Careful structural investigations indicated that magnetite nanoparticles covered by CS were evenly distributed on the surface of graphene oxide.CS, Fe₃O₄, and GO were chemically bonded together to form a stable composite material.The magnetism of CS/Fe₃O₄/GO was tested as 42.5 emu·g^-1, which is strong enough for efficient solid-liquid separation under an applied magnetic field.CS/Fe₃O₄/GO was used to adsorb multiple synthetic dyes, including methylene blue (MB), Congo red (CR), and methyl orange (MO), and showed high multi-dye adsorption performance.It is found that the adsorption of MB, MO, and CR under optimal conditions reached 210.6, 258.6, and 308.9 mg·g^-1, respectively.The effect of pH, initial concentration, and contact time on the adsorption was investigated.Recycling experiments showed that CS/Fe₃O₄/GO had excellent
- magnetic adsorbent,
- multi-dye adsorption,
- chitosan,
- graphene oxide,
- magnetic separation
1. [1]
  Solano M A, Galan J, Vallejo W, Arana V A, Grande -Tovar C D. Chitosan beads incorporated with graphene oxide/titanium dioxide nanoparticles for removing an anionic dye[J]. Appl. Sci., 2021,11(20)9439. doi: 10.3390/app11209439
2. [2]
  Sheshmani S, Ashori A, Hasanzadeh S. Removal of acid orange 7 from aqueous solution using magnetic graphene/chitosan: A promising nano-adsorbent[J]. Int. J. Biol. Macromol., 2014,68:218-244. doi: 10.1016/j.ijbiomac.2014.04.057
3. [3]
  Le T T N, Le V T, Dao M U, Nguyen Q V, Vu T T, Nguyen M H, Tran D L, Le H S. Preparation of magnetic graphene oxide/chitosan composite beads for effective removal of heavy metals and dyes from aque-ous solutions[J]. Chem. Eng. Commun., 2019,206(10):1337-1352. doi: 10.1080/00986445.2018.1558215
4. [4]
  Nekouei M N, Shahbazi A. A novel environmental -friendly nanobio-composite synthesis by EDTA and chitosan functionalized magnetic graphene oxide for high removal of rhodamine B: Adsorption mechanism and separation property[J]. Chemosphere, 2019,218:715-725. doi: 10.1016/j.chemosphere.2018.11.109
5. [5]
  de la Luz-Asunción M, Pérez-Ramírez E E, Martínez-Hernández A L, García-Casillas P E, Luna-Bárcenas J G, Velasco-Santos C. Adsorption and kinetic study of reactive red 2 dye onto graphene oxides and graphene quantum dots[J]. Diam. Relat. Mater., 2020,109108002. doi: 10.1016/j.diamond.2020.108002
6. [6]
  Alves D, Healy B, Yu T, Breslin C B. Graphene -based materials immobilized within chitosan: Applications as adsorbents for the removal of aquatic pollutants[J]. Materials, 2021,14(13)3655. doi: 10.3390/ma14133655
7. [7]
  Sheshmani S, Mashhadi S. Potential of magnetite reduced graphene oxide/chitosan nanocomposite as biosorbent for the removal of dyes from aqueous solutions[J]. Polym. Compos., 2018,39:E457-E462. doi: 10.1002/pc.24608
8. [8]
  Van H N, Khong T T, Quyen T T H, Trung T S. One-step facile synthesis of mesoporous graphene/Fe₃O₄/chitosan nanocomposite and its adsorption capacity for a textile dye[J]. J. Water Process. Eng., 2016,9:170-178. doi: 10.1016/j.jwpe.2015.12.005
9. [9]
  Song X S, Zhou J, Fan J S, Zhang Q Q, Wang S F. Preparation and adsorption properties of magnetic graphene oxide composites for the removal of methylene blue from water[J]. Mater. Res. Express, 2022,9(2)020002. doi: 10.1088/2053-1591/ac52c6
10. [10]
  Sadiq A C, Olasupo A, Ngah W S W, Rahim N Y, Suah F B M. A decade development in the application of chitosan -based materials for dye adsorption: A short review[J]. Int. J. Biol. Macromol., 2021,191:1151-1163. doi: 10.1016/j.ijbiomac.2021.09.179
11. [11]
  HUANG K L, CHEN J, LIU S Q, LI G Y. Chemical modification and coating mechanism of magnetic Fe₃O₄/chitosan[J]. Chinese J. Inorg. Chem, 2007,23(8):1491-1495. doi: 10.3321/j.issn:1001-4861.2007.08.033
12. [12]
  Zhang C L, Chen Z Z, Guo W, Zhu C W, Zou Y J. Simple fabrication of chitosan/graphene nanoplates composite spheres for efficient adsorption of acid dyes from aqueous solution[J]. Int. J. Biol. Macromol., 2018,112:1048-1054. doi: 10.1016/j.ijbiomac.2018.02.074
13. [13]
  Kosowska K, Domalik-Pyzik P, Krok-Borkowicz M, Chlopek J. Synthesis and characterization of chitosan/reduced graphene oxide hybrid composites[J]. Materials, 2019,12(13)2077. doi: 10.3390/ma12132077
14. [14]
  LI J J, BAO X, WU X F, ISLAM N, LIU Y, QIAO S Y, YU Z W, ZHU J B. Magnetic chitosan micron spheres: Synthesis and adsorption property for Cu²⁺[J]. Chinese J. Inorg. Chem., 2017,33(3):383-388.
15. [15]
  Wang Y, Xia G M, Wu C, Sun J, Song R, Huang W. Porous chitosan doped with graphene oxide as highly effective adsorbent for methyl orange and amido black 10B[J]. Carbohydr. Polym., 2015,115:686-693. doi: 10.1016/j.carbpol.2014.09.041
16. [16]
  WANG J H, CHEN Y, LIU N, SUN T T, ATIF S. Chitosan modified magnetic carbon-based adsorbent: Preparation and adsorption mechanism for Cr(Ⅲ)-EDTA in water[J]. Chinese J. Inorg. Chem., 2020,36(7):1249-1258.
17. [17]
  Zhang Y, Li H J, Li M C, Xin M H. Adsorption of aniline on aminated chitosan/graphene oxide composite material[J]. J. Mol. Struct., 2020,1209127973. doi: 10.1016/j.molstruc.2020.127973
18. [18]
  Tahira I, Aslam Z, Abbas A, Monim-Ul-Mehboob M, Ali S, Asghar A. Adsorptive removal of acidic dye onto grafted chitosan: A plausible grafting and adsorption mechanism[J]. Int. J. Biol. Macromol., 2019,136:1209-1218. doi: 10.1016/j.ijbiomac.2019.06.173
19. [19]
  Croitoru A M, Ficai A, Ficai D, Trusca R, Dolete G, Andronescu E, Turculet S C. Chitosan/graphene oxide nanocomposite membranes as adsorbents with applications in water purification[J]. Materials, 2020,13(7)1687. doi: 10.3390/ma13071687
20. [20]
  El Rouby W M A, Farghali A A, Sadek M A, Khalil W F. Fast Removal of Sr(Ⅱ) from water by graphene oxide and chitosan modified graphene oxide[J]. J. Inorg. Organomet. Polym. Mater., 2018,28(6):2336-2349. doi: 10.1007/s10904-018-0885-9
21. [21]
  Wang Z Q, Zhang G H, Li Y H. Preparation of chitosan/polyacrylamide/graphene oxide composite membranes and study of their methylene blue adsorption properties[J]. Materials, 2020,13(19)4407. doi: 10.3390/ma13194407
22. [22]
  Du W J, Ma R, Liu Z Y, Yang G, Chen T. Study on the adsorption properties of graphene oxide/Laponite RD/chitosan composites[J]. Materials, 2021,14(12)3224. doi: 10.3390/ma14123224
23. [23]
  Wang Y, Liu X, Wang H F, Xia G M, Huang W, Song R. Microporous spongy chitosan monoliths doped with graphene oxide as highly effective adsorbent for methyl orange and copper nitrate (Cu(NO₃)₂) ions[J]. J. Colloid Interface Sci., 2014,416:243-251. doi: 10.1016/j.jcis.2013.11.012
24. [24]
  Wu Y, Bian Y Q, Yang F, Ding Y, Chen K X. Preparation and properties of chitosan/graphene modified bamboo fiber fabrics[J]. Polymers., 2019,11(10)1540. doi: 10.3390/polym11101540
25. [25]
  Du Q J, Sun J K, Li Y H, Yang X X, Wang X H, Wang Z H, Xia L H. Highly enhanced adsorption of Congo red onto graphene oxide/chitosan fibers by wet-chemical etching off silica nanoparticles[J]. Chem. Eng. J., 2014,245:99-106. doi: 10.1016/j.cej.2014.02.006
26. [26]
  Huang C Q, Liao H Y, Ma X H, Xiao M, Liu X H, Gong S, Shu X G, Zhou X H. Adsorption performance of chitosan Schiff base towards anionic dyes: Electrostatic interaction effects[J]. Chem. Phys. Lett., 2021,780138958. doi: 10.1016/j.cplett.2021.138958
27. [27]
  Chen X Y, He L D. Microwave irradiation assisted preparation of chitosan composite microsphere for dye adsorption[J]. Int. J. Polym. Sci., 2017,2017:1-8.
28. [28]
  Lv S H, Zhu L L, Li Y, Jia C M, Sun S Y. The adsorption capacity of GONs/CMC/Fe₃O₄ magnetic composite microspheres and applications for purifying dye wastewater[J]. Materials, 2017,10(1)58. doi: 10.3390/ma10010058
29. [29]
  Zang J, Wu T T, Song H H, Zhou N, Fan S S, Xie Z X, Tang J. Removal of tetracycline by hydrous Ferric oxide: Adsorption kinetics, isotherms, and mechanism[J]. Int. J. Environ. Res. Public. Health, 2019,16(22)4580. doi: 10.3390/ijerph16224580
30. [30]
  Paliwal M K, Sonia Y K, Meher S K. Hierarchically structured β -Ni(OH)₂ clusters: A uniquely efficient aqueous phase pollutant adsorbent for multiple anionic dyes and heavy metal ions[J]. Mater. Today Chem., 2021,22100551. doi: 10.1016/j.mtchem.2021.100551
31. [31]
  Cho S Y, Kim T. Adsorption equilibria of reactive dye onto highly polyaminated porous chitosan beads[J]. Korean J. Chem. Eng., 2005,22(5):691-696. doi: 10.1007/BF02705784
32. [32]
  Abu-Nada A, Abdala A, Mckay G. Removal of phenols and dyes from aqueous solutions using graphene and graphene composite adsorption: A review[J]. J. Environ. Chem. Eng., 2021,9(5)150858.
33. [33]
  Aramesh N, Bagheri A R, Bilal M. Chitosan-based hybrid materials for adsorptive removal of dyes and underlying interaction mechanisms[J]. Int. J. Biol. Macromol., 2021,183:399-422. doi: 10.1016/j.ijbiomac.2021.04.158
34. [34]
  Liu Y Z, Zheng H L, Han Y W, Wu Y W, Wang Y, Liu Y D, Feng L. Amphiphilic magnetic copolymer for enhanced removal of anionic dyes: Fabrication, application and adsorption mechanism[J]. Colloid Surf. A-Physicochem. Eng. Asp., 2021,623126674. doi: 10.1016/j.colsurfa.2021.126674
1. [1]
  Zeyu XU , Anlei DANG , Bihua DENG , Xiaoxin ZUO , Yu LU , Ping YANG , Wenzhu YIN . Evaluation of the efficacy of graphene oxide quantum dots as an ovalbumin delivery platform and adjuvant for immune enhancement. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1065-1078. doi: 10.11862/CJIC.20240099
2. [2]
  Zhuo WANG , Junshan ZHANG , Shaoyan YANG , Lingyan ZHOU , Yedi LI , Yuanpei LAN . Preparation and photocatalytic performance of CeO₂-reduced graphene oxide by thermal decomposition. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1708-1718. doi: 10.11862/CJIC.20240067
3. [3]
  Cheng Guo , Xiaoxiao Zhang , Xiujuan Hong , Yiqiu Hu , Lingna Mao , Kezhi Jiang . Graphene as adsorbent for highly efficient extraction of modified nucleosides in urine prior to liquid chromatography-tandem mass spectrometry analysis. Chinese Chemical Letters, 2024, 35(4): 108867-. doi: 10.1016/j.cclet.2023.108867
4. [4]
  Hongdao LI , Shengjian ZHANG , Hongmei DONG . Magnetic relaxation and luminescent behavior in nitronyl nitroxide-based annuluses of rare-earth ions. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 972-978. doi: 10.11862/CJIC.20230411
5. [5]
  Rui Wang , He Qi , Haijiao Zheng , Qiong Jia . Light/pH dual-responsive magnetic metal-organic frameworks composites for phosphorylated peptide enrichment. Chinese Chemical Letters, 2024, 35(7): 109215-. doi: 10.1016/j.cclet.2023.109215
6. [6]
  Shuangying Li , Qingxiang Zhou , Zhi Li , Menghua Liu , Yanhui Li . Sensitive measurement of silver ions in environmental water samples integrating magnetic ion-imprinted solid phase extraction and carbon dot fluorescent sensor. Chinese Chemical Letters, 2024, 35(5): 108693-. doi: 10.1016/j.cclet.2023.108693
7. [7]
  Xianzheng Zhang , Yana Chen , Zhiyong Ye , Huilin Hu , Ling Lei , Feng You , Junlong Yao , Huan Yang , Xueliang Jiang . Magnetic field-assisted microbial corrosion construction iron sulfides incorporated nickel-iron hydroxide towards efficient oxygen evolution. Chinese Journal of Structural Chemistry, 2024, 43(1): 100200-100200. doi: 10.1016/j.cjsc.2023.100200
8. [8]
  Yan Cheng , Hua-Peng Ruan , Yan Peng , Longhe Li , Zhenqiang Xie , Lang Liu , Shiyong Zhang , Hengyun Ye , Zhao-Bo Hu . Magnetic, dielectric and luminescence synergetic switchable effects in molecular material [Et₃NCH₂Cl]₂[MnBr₄]. Chinese Chemical Letters, 2024, 35(4): 108554-. doi: 10.1016/j.cclet.2023.108554
9. [9]
  Ying Chen , Li Li , Junyao Zhang , Tongrui Sun , Xuan Zhang , Shiqi Zhang , Jia Huang , Yidong Zou . Tailored ionically conductive graphene oxide-encased metal ions for ultrasensitive cadaverine sensor. Chinese Chemical Letters, 2024, 35(8): 109102-. doi: 10.1016/j.cclet.2023.109102
10. [10]
  Jia-Li Xie , Tian-Jin Xie , Yu-Jie Luo , Kai Mao , Cheng-Zhi Huang , Yuan-Fang Li , Shu-Jun Zhen . Octopus-like DNA nanostructure coupled with graphene oxide enhanced fluorescence anisotropy for hepatitis B virus DNA detection. Chinese Chemical Letters, 2024, 35(6): 109137-. doi: 10.1016/j.cclet.2023.109137
11. [11]
  Jinjie Lu , Qikai Liu , Yuting Zhang , Yi Zhou , Yanbo Zhou . Antibacterial performance of cationic quaternary phosphonium-modified chitosan polymer in water. Chinese Chemical Letters, 2024, 35(9): 109406-. doi: 10.1016/j.cclet.2023.109406
12. [12]
  Linshan Peng , Qihang Peng , Tianxiang Jin , Zhirong Liu , Yong Qian . Highly efficient capture of thorium ion by citric acid-modified chitosan gels from aqueous solution. Chinese Chemical Letters, 2024, 35(5): 108891-. doi: 10.1016/j.cclet.2023.108891
13. [13]
  Ningning Gao , Yue Zhang , Zhenhao Yang , Lijing Xu , Kongyin Zhao , Qingping Xin , Junkui Gao , Junjun Shi , Jin Zhong , Huiguo Wang . Ba²⁺/Ca²⁺ co-crosslinked alginate hydrogel filtration membrane with high strength, high flux and stability for dye/salt separation. Chinese Chemical Letters, 2024, 35(5): 108820-. doi: 10.1016/j.cclet.2023.108820
14. [14]
  Tian Cao , Xuyin Ding , Qiwen Peng , Min Zhang , Guoyue Shi . Intelligent laser-induced graphene sensor for multiplex probing catechol isomers. Chinese Chemical Letters, 2024, 35(7): 109238-. doi: 10.1016/j.cclet.2023.109238
15. [15]
  Rui Liu , Jinbo Pang , Weijia Zhou . Monolayer water shepherding supertight MXene/graphene composite films. Chinese Journal of Structural Chemistry, 2024, 43(10): 100329-100329. doi: 10.1016/j.cjsc.2024.100329
16. [16]
  Lingling Su , Qunyan Wu , Congzhi Wang , Jianhui Lan , Weiqun Shi . Theoretical design of polyazole based ligands for the separation of Am(Ⅲ)/Eu(Ⅲ). Chinese Chemical Letters, 2024, 35(8): 109402-. doi: 10.1016/j.cclet.2023.109402
17. [17]
  Jingwen Zhao , Jianpu Tang , Zhen Cui , Limin Liu , Dayong Yang , Chi Yao . A DNA micro-complex containing polyaptamer for exosome separation and wound healing. Chinese Chemical Letters, 2024, 35(9): 109303-. doi: 10.1016/j.cclet.2023.109303
18. [18]
  Huangjie Lu , Yingzhe Du , Peng Lin , Jian Lin . Separation of americium from lanthanides based on oxidation state control. Chinese Journal of Structural Chemistry, 2024, 43(10): 100344-100344. doi: 10.1016/j.cjsc.2024.100344
19. [19]
  Hanqing Zhang , Xiaoxia Wang , Chen Chen , Xianfeng Yang , Chungli Dong , Yucheng Huang , Xiaoliang Zhao , Dongjiang Yang . Selective CO2-to-formic acid electrochemical conversion by modulating electronic environment of copper phthalocyanine with defective graphene. Chinese Journal of Structural Chemistry, 2023, 42(10): 100089-100089. doi: 10.1016/j.cjsc.2023.100089
20. [20]
  Qiang Cao , Xue-Feng Cheng , Jia Wang , Chang Zhou , Liu-Jun Yang , Guan Wang , Dong-Yun Chen , Jing-Hui He , Jian-Mei Lu . Graphene from microwave-initiated upcycling of waste polyethylene for electrocatalytic reduction of chloramphenicol. Chinese Chemical Letters, 2024, 35(4): 108759-. doi: 10.1016/j.cclet.2023.108759

Get Citation

PDF

XML

Metrics

PDF Downloads(6)
Abstract views(886)
HTML views(72)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Preparition and multiple-dye adsorption of magnetic chitosan/Fe3O4/graphene oxide adsorbent

Metrics

通讯作者: 陈斌, bchen63@163.com

Preparition and multiple-dye adsorption of magnetic chitosan/Fe₃O₄/graphene oxide adsorbent