Citation: Xiao-Liang WANG, Duo ZHANG, Xue-Mei SHI, Xin-Ye QIAO, Yan CHENG, Hao-Nan ZHAO, Lei-Ming CHANG, Zhen-Qiu YU, Chuan-Hui HUANG, Shao-Bin YANG. Preparation by Co metal-organic framework template and capacitive properties of NiCo-layered double hydroxide/nickel foam composites[J]. Chinese Journal of Inorganic Chemistry, ;2023, 39(4): 607-616. doi: 10.11862/CJIC.2023.036 shu

Preparation by Co metal-organic framework template and capacitive properties of NiCo-layered double hydroxide/nickel foam composites

1.
Geology and Mineral Engineering Special Materials Professional Technology Innovation Center of Liaoning Province, Key Laboratory of Mineral High Value Conversion and Energy Storage Materials of Liaoning Province, College of Materials Science & Engineering, Liaoning Technical University, Fuxin, Liaoning 123000, China
2.
School of Mechanical & Electrical Engineering, Xuzhou University of Technology, Xuzhou, Jiangsu 221000, China
3.
Liaohe Oilfield Training Center, Panjin, Liaoning 124000, China

Corresponding author: Xiao-Liang WANG, ningke@163.com Shao-Bin YANG, lgdysb@163.com
Received Date: 12 June 2022
Revised Date: 2 March 2023

Figures(9)

Using a two-step method, a Co metal-organic framework (Co-MOF) nanosheet array was grown in situ on nickel foam (NF), and then Co-MOF nanosheets were etched with different concentrations of Ni²⁺ ion solution to obtain NiCo layered double hydroxide (NiCo-LDH). NiCo-LDH/NF inherits the Co-MOF nano-sheet structure to form a primary nano-sheet array and a secondary nano-sheet fold on the surface of the primary nano-sheet. NiCo-LDH/NF obtained by etching in 2 mmol Ni (NO₃)₂·6H₂O solution showed a small number of thin and folded secondary nano-sheets grown on the primary nano-sheet array, exhibited a high capacitance and high rate performance, had a specific capacitance of 7764.5 and 6098.2 mF·cm^-2 at a current density of 5 and 20 mA·cm^-2, and capacitance retention rate of 78.5%. After 5000 cycles at a current density of 20 A·g^-1, the capacitance retention rate was 85.9%. The hybrid capacitor assembled by NiCo-LDH/NF and active carbon achieved an maximum energy density of 38.9 Wh·kg^-1 and a maximum power density of 8000.0 W·kg^-1.
- metal-organic framework,
- layered double hydroxide,
- supercapacitors,
- composite material,
- in situ growth
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