Citation: Xiao-Min HOU, Si-Fu TANG. Heterometallic uranyl sulfophosphonates: Synthesis, crystal structures, and fluorescence properties[J]. Chinese Journal of Inorganic Chemistry, ;2023, 39(4): 746-752. doi: 10.11862/CJIC.2023.034 shu

Heterometallic uranyl sulfophosphonates: Synthesis, crystal structures, and fluorescence properties

Xiao-Min HOU ¹ ,
Si-Fu TANG ^2,,

1.
College of Life Science, Qingdao Agricultural University, Qingdao, Shandong 266109, China
2.
College of Chemistry and Pharmaceutical Sciences, Qingdao Agricultural University, Qingdao, Shandong 266109, China

Corresponding author: Si-Fu TANG, tangsf@qau.edu.cn
Received Date: 2 October 2022
Revised Date: 17 January 2023

Figures(5)

It is still a great challenge to construct heterometallic uranyl phosphonates. In this work, a series of isostructural heterometallic uranyl sulfophosphonates, namely [UO₂M(L)₂(H₂O)₄], where M=Mn (1), Co (2), Ni (3), Zn (4), Cd (5) and Et₂L=diethyl ((phenylsulfonyl)methyl)phosphonate, have been successfully synthesized and systematically characterized. The sulfonyl group is not involved in coordination with the metal centers, whereas the phosphonate group is fully deprotonated and connects with two uranyl cations and one transition metal ion, affording a 2D layered crystal structure. It was found that the luminescent emission was almost totally quenched in the presence of Mn(Ⅱ), Co(Ⅱ), and Ni(Ⅱ), whereas showed strong emissions in the presence of Zn(Ⅱ) and Cd(Ⅱ).
- uranyl,
- phosphonates,
- crystal structures,
- fluorescence
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