Citation: Dominic Kurbah Sunshine. Dioxidomolybdenum(Ⅵ) complex derived from malonoyldihydrazones: Synthesis, characterization, and crystal structure[J]. Chinese Journal of Inorganic Chemistry, ;2023, 39(4): 709-715. doi: 10.11862/CJIC.2023.028 shu

Dioxidomolybdenum(Ⅵ) complex derived from malonoyldihydrazones: Synthesis, characterization, and crystal structure

Dominic Kurbah Sunshine ^,

Department of Chemistry, Pandit Deendayal Upadhyaya Adarsha Mahavidyalaya, Eraligool-788723, Karimganj, Assam, India

Corresponding author: Dominic Kurbah Sunshine, sunshinekurbah@yahoo.com
Received Date: 28 April 2022
Revised Date: 16 December 2022

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In this paper, we report the synthesis, characterization, and molecular structure of the dioxidomolybdenum (Ⅵ) complex[MoO₂(H₂L)(H₂O)].The complex was obtained by reaction of malanoyldihydrazones ligand bis (2 hydroxy-1-naphthaldehyde) malonoyldihydrazone (H₄L) with molybdenum bis (acetylacetonato) dioxomolybdenum (Ⅵ) in a 1∶1 molar ratio in methanol.The complex was characterized by using various spectroscopic studies, such as IR, MS, and NMR.The structure of the complex was established by single-crystal X-ray crystallography.The complex crystallizes in the monoclinic space group P2₁/c.The metal center has distorted octahedral coordination environments, connected to one azomethine nitrogen atom of H₄L, two terminal oxido groups, two oxygen atoms of H₄L, and one oxygen atom of a coordinated water molecule.
- crystal structure,
- metal complex,
- dioxidomolybdenum(Ⅵ),
- octahedral coordination
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