Citation: Jia-Xue MU, Xiong LI, Xun-Zhong ZOU, An-Sheng FENG, Yu LI. Synthesis, structures, and catalytic activity in the Knoevenagel condensation reaction of three Co(Ⅱ), Cu(Ⅱ), and Cd(Ⅱ) coordination polymers based on an ether-bridged tetracarboxylic acid[J]. Chinese Journal of Inorganic Chemistry, ;2023, 39(3): 554-562. doi: 10.11862/CJIC.2023.024 shu

Synthesis, structures, and catalytic activity in the Knoevenagel condensation reaction of three Co(Ⅱ), Cu(Ⅱ), and Cd(Ⅱ) coordination polymers based on an ether-bridged tetracarboxylic acid

Guangdong Engineering Technology Research Center of Special Building Materials and Its Green Preparation, Guangdong Industry Polytechnic, Guangzhou 510300, China

Corresponding author: Yu LI, liyuletter@163.com
Received Date: 30 September 2022
Revised Date: 14 December 2022

Figures(11)

Three cobalt(Ⅱ)), copper(Ⅱ), and cadmium(Ⅱ) coordination polymers, namely [Co₂(μ₄-dia)(phen)₂(H₂O)₂]_n (1), [Cu₂(μ₆-dia)(bipy)₂]_n (2), and {[Cd₂(μ₅-dia)(μ-bpa)₂(H₂O)]·H₂O}_n (3) have been constructed hydrothermally using H₄dia (5-(2, 5-dicarboxyphenoxy)isophthalic acid), phen (phen=1, 10-phenanthroline), bipy (2, 2'-bipyridine), bpa (bis(4-pyridyl)amine), and cobalt, copper and cadmium chlorides at 160 ℃. The products were isolated as stable crystalline solids and were characterized by IR spectra, elemental analyses, thermogravimetric analyses, and singlecrystal X-ray diffraction analyses. Single-crystal X-ray diffraction analyses reveal that three compounds crystallize in the monoclinic or triclinic systems, space groups P2₁/n, P2₁/c, or P1. Compound 1 discloses a 1D double-chain structure. Compounds 2 and 3 show 3D frameworks. The catalytic activity in the Knoevenagel condensation reaction of these compounds was investigated. Compound 2 exhibited excellent catalytic activity in the Knoevenagel conden-sation reaction at 50 ℃.
- coordination polymer,
- tetracarboxylic acid,
- catalytic properties,
- Knoevenagel condensation reaction
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