Citation: Dong LI, Jia-Xin SONG, Lian KONG, Zhen ZHAO. Effect of P promoter on the oxidative dehydrogenation of ethane over Ni-Al-O catalysts[J]. Chinese Journal of Inorganic Chemistry, ;2023, 39(4): 637-648. doi: 10.11862/CJIC.2023.023 shu

Effect of P promoter on the oxidative dehydrogenation of ethane over Ni-Al-O catalysts

Dong LI ^{1, 2} ,
Jia-Xin SONG ^{1, 2} ,
Lian KONG ^2,, ,
Zhen ZHAO ^{1, 2,,}

1.
State Key Laboratory of Heavy Oil, China University of Petroleum, Beijing 102249, China
2.
College of Chemistry and Chemical Engineering, Institute of Catalysis for Energy and Environment, Shenyang Normal University, Shenyang 110034, China

Corresponding author: Lian KONG, konglian0907@163.com Zhen ZHAO, zhenzhao@cup.edu.cn; zhaozhen@synu.edu.cn
Received Date: 22 September 2022
Revised Date: 10 January 2023

Figures(11)

A series of phosphorus-modified Ni-Al-O catalysts (P_x-Ni-Al-O) were prepared by the one-pot hydrothermal method.The performance of the oxidative dehydrogenation of ethane to ethylene over series catalysts was evaluated by using O₂ as an oxidant.The results showed that the P incorporation can not only reduce the crystallite sizes of NiO, but also affect the interaction between Ni and Al.In the temperature range of 350-475℃, the selectivities towards ethylene over P-modified Ni-Al-O catalysts were higher than those over the unmodified catalyst, and the addition of the appropriate amount of P could also improve the ethane conversion.The selectivity and yield of ethylene over the P_0.15-Ni-Al-O catalyst were 61.4% and 31.9% at 475℃, respectively.Moreover, the P-modified catalyst showed a strong resistance to carbon deposition and remained the catalytic performance for 22 h after a continuous reaction.
- hydrothermal method,
- promoter P,
- Ni-Al-O catalyst,
- oxidative dehydrogenation of ethane
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