Citation: Xuan WANG, Ji-Jiang WANG, Long TANG, Yi-Dan ZHENG, Xin ZHANG, Er-Lin YUE, Chao BAI, Yu-Qi ZHANG. Synthesis, structures, magnetic and fluorescent sensing properties of 1D Co(Ⅱ)/Ni(Ⅱ) coordination polymers[J]. Chinese Journal of Inorganic Chemistry, ;2023, 39(3): 545-553. doi: 10.11862/CJIC.2023.020 shu

Synthesis, structures, magnetic and fluorescent sensing properties of 1D Co(Ⅱ)/Ni(Ⅱ) coordination polymers

Yan'an City Key Laboratory of New Energy & New Functional Materials, Shaanxi Key Laboratory of Chemical Reaction Engineering, College of Chemistry and Chemical Engineering, Yan'an University, Yan'an, Shaanxi 716000, China

Corresponding author: Ji-Jiang WANG, yadxwjj@126.com Long TANG, E-mailydtanglong@163.com
Received Date: 26 August 2022
Revised Date: 15 February 2023

Figures(11)

Two new coordination polymers [Co(L)_0.5(1, 4-bib)(H₂O)₃]_n (1) and [Ni(L)_0.5(1, 4-bib)(H₂O)₃]_n (2) (H4L=1, 4-bis (2, 6-dimethyl-3, 5-dicarboxypyridyl) benzene, 1, 4-bib=1, 4-bis(1-imidazolyl) benzene) were synthesized by hydrothermal method. Their structures were characterized by single crystal and powder X-ray diffraction, elemental analysis, infrared spectroscopic analysis, and thermogravimetric analysis. Structural analysis shows that complexes 1 and 2 are heterogeneous isomorphisms and 1D structures. The antiferromagnetic interaction between Co(Ⅱ)/Ni(Ⅱ) ions in complexes 1 and 2 was found by variable temperature magnetic susceptibility measurement. In addition, complex 1 can be used to detect cefixime (CEF) by fluorescence quenching method, and complex 2 can be used to detect tetra-cycline (TET). This method had high sensitivity and good selectivity, and their detection limits were 0.86 μmol·L^-1 (CEF) and 0.49 μmol·L^-1 (TET), respectively.
- coordination polymers,
- Co(Ⅱ),
- Ni(Ⅱ),
- magnetism,
- fluorescent sensing
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