Citation: Xuan WANG, Ji-Jiang WANG, Long TANG, Yi-Dan ZHENG, Xin ZHANG, Er-Lin YUE, Chao BAI, Yu-Qi ZHANG. Synthesis, structures, magnetic and fluorescent sensing properties of 1D Co(Ⅱ)/Ni(Ⅱ) coordination polymers[J]. Chinese Journal of Inorganic Chemistry, ;2023, 39(3): 545-553. doi: 10.11862/CJIC.2023.020 shu

Synthesis, structures, magnetic and fluorescent sensing properties of 1D Co(Ⅱ)/Ni(Ⅱ) coordination polymers

Yan'an City Key Laboratory of New Energy & New Functional Materials, Shaanxi Key Laboratory of Chemical Reaction Engineering, College of Chemistry and Chemical Engineering, Yan'an University, Yan'an, Shaanxi 716000, China

Corresponding author: Ji-Jiang WANG, yadxwjj@126.com Long TANG, E-mailydtanglong@163.com
Received Date: 26 August 2022
Revised Date: 15 February 2023

Figures(11)

Two new coordination polymers [Co(L)_0.5(1, 4-bib)(H₂O)₃]_n (1) and [Ni(L)_0.5(1, 4-bib)(H₂O)₃]_n (2) (H4L=1, 4-bis (2, 6-dimethyl-3, 5-dicarboxypyridyl) benzene, 1, 4-bib=1, 4-bis(1-imidazolyl) benzene) were synthesized by hydrothermal method. Their structures were characterized by single crystal and powder X-ray diffraction, elemental analysis, infrared spectroscopic analysis, and thermogravimetric analysis. Structural analysis shows that complexes 1 and 2 are heterogeneous isomorphisms and 1D structures. The antiferromagnetic interaction between Co(Ⅱ)/Ni(Ⅱ) ions in complexes 1 and 2 was found by variable temperature magnetic susceptibility measurement. In addition, complex 1 can be used to detect cefixime (CEF) by fluorescence quenching method, and complex 2 can be used to detect tetra-cycline (TET). This method had high sensitivity and good selectivity, and their detection limits were 0.86 μmol·L^-1 (CEF) and 0.49 μmol·L^-1 (TET), respectively.
- coordination polymers,
- Co(Ⅱ),
- Ni(Ⅱ),
- magnetism,
- fluorescent sensing
1. [1]
  Batten S R, Champness N R, Chen X M, Garcia-Martinez J, Kitagawa S, Öhrström L, O'Keeffe M, Suh M P, Reedijk J. Coordination polymers, metal-organic frameworks and the need for terminology guidelines[J]. CrystEngComm, 2012,14:3001-3004. doi: 10.1039/c2ce06488j
2. [2]
  Batten S R, Champness N R, Chen X M, Garcia-Martinez J, Kitagawa S, Öhrström L, O'Keeffe M, Suh M P, Reedijk J. Terminology of metal-organic frameworks and coordination polymers (IUPAC Recommendations 2013)[J]. Pure Appl. Chem., 2013,85:1715-1724. doi: 10.1351/PAC-REC-12-11-20
3. [3]
  Liang Q N, Chen J M, Wang F L, Li Y W. Transition metal-based metal-organic frameworks for oxygen evolution reaction[J]. Coord. Chem. Rev., 2020,424213488. doi: 10.1016/j.ccr.2020.213488
4. [4]
  Sakamoto N, Nishimura Y F, Nonaka T, Ohashi M, Ishida N, Kitazumi K, Kato Y, Sekizawa K, Morikawa T, Arai T. Self-assembled cuprous coordination polymer as a catalyst for CO₂ electrochemical reduction into C₂ products[J]. ACS Catal., 2020,10(18):10412-10419. doi: 10.1021/acscatal.0c01593
5. [5]
  Woldu A R, Huang Z L, Zhao P X, Hu L S, Astruc D. Electrochemical CO₂ reduction (CO₂RR) to multi-carbon products over copper-based catalysts[J]. Coord. Chem. Rev., 2022,454214340. doi: 10.1016/j.ccr.2021.214340
6. [6]
  Zhou Y T, Abazari R, Chen J, Tahir M, Kumar A, Ikreedeegh R R, Rani E, Singh H, Kirillov A M. Bimetallic metal-organic frameworks and MOF-derived composites: Recent progress on electro and photoelectrocatalytic applications[J]. Coord. Chem. Rev., 2022,451214264. doi: 10.1016/j.ccr.2021.214264
7. [7]
  Lin J B, Zhang J P, Chen X M. Nonclassical active site for enhanced gas sorption in porous coordination polymer[J]. J. Am. Chem. Soc., 2010,132:6654-6656. doi: 10.1021/ja1009635
8. [8]
  Duan J G, Jin W Q, Kitagawa S. Water-resistant porous coordination polymers for gas separation[J]. Coord. Chem. Rev., 2017,332:48-74. doi: 10.1016/j.ccr.2016.11.004
9. [9]
  Duan J G, Higuchi M, Krishna R, Kiyonaga T, Tsutsumi Y, Sato Y, Kubota Y, Takata M, Kitagawa S. High CO₂/N₂/O₂/CO separation in a chemically robust porous coordination polymer with low binding energy[J]. Chem. Sci., 2014,5:660-666. doi: 10.1039/C3SC52177J
10. [10]
  Imaz I, Rubio-Martinez M, Garcia-Fernandez L, Garcia F, Ruiz-Molina D, Hernando J, Puntes V, Maspoch D. Coordination polymer particles as potential drug delivery systems[J]. Chem. Commun., 2010,46:4737-4739. doi: 10.1039/c003084h
11. [11]
  Dutta B, Hazra A, Dey A, Sinha C, Ray P P, Banerjee P, Mir M H. Construction of a succinate-bridged Cd(Ⅱ)-based two-dimensional coordination polymer for efficient optoelectronic device fabrication and explosive sensing application[J]. Cryst. Growth Des., 2020,20(2):765-776. doi: 10.1021/acs.cgd.9b01181
12. [12]
  Wen T, Zhang D X, Liu J, Lin R, Zhang J. A multifunctional helical Cu coordination polymer with mechanochromic, sensing and photocatalytic properties[J]. Chem. Commun., 2013,49:5660-5662. doi: 10.1039/c3cc42241k
13. [13]
  Luo X Z, Abazari R, Tahir M, Fan W K, Kumar A, Kalhorizadeh T, Kirillov A M, Amani-Ghadim A R, Chen J, Zhou Y T. Trimetallic metal-organic frameworks and derived materials for environmental remediation and electrochemical energy storage and conversion[J]. Coord. Chem. Rev., 2022,461214505. doi: 10.1016/j.ccr.2022.214505
14. [14]
  Horike S, Umeyama D, Kitagawa S. Ion conductivity and transport by porous coordination polymers and metal-organic frameworks[J]. Acc. Chem. Res., 2013,46(11):2376-2384. doi: 10.1021/ar300291s
15. [15]
  Bain G A, Berry J F. Diamagnetic corrections and Pascal's constant[J]. J. Chem. Educ., 2008,85(4)532. doi: 10.1021/ed085p532
16. [16]
  Wu B L, Yuan D Q, Jiang F L, Han L, Lou B Y, Liu C P, Hong M C. Effect of conformation and combination of 1, 3-bis(4-pyridylthio) propan-2-one upon coordination architectures: Syntheses, characterizations and properties[J]. Eur. J. Inorg. Chem., 2005(7):1303-1311.
17. [17]
  Wang L B, Wang J J, Yue E L, Li J F, Tang L, Bai C, Wang X, Hou X Y, Zhang Y Q. Information encryption, highly sensitive detection of nitrobenzene, tetracycline based on a stable luminescent Cd-MOF[J]. Spectroc. Acta Pt. A—Molec. Biomolec. Spectr., 2022,269120752. doi: 10.1016/j.saa.2021.120752
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