Citation: Yan-Ying RAO, Bing-Gui WANG, Zhang-Liang LI, Xue-Wen CHEN, Li-Rong QIU, Hong XU, Jian-Hui HUANG. Facile fabrication and surface-enhanced Raman scattering properties of ordered Au/Ag nanobowl array[J]. Chinese Journal of Inorganic Chemistry, ;2023, 39(4): 753-764. doi: 10.11862/CJIC.2023.018 shu

Facile fabrication and surface-enhanced Raman scattering properties of ordered Au/Ag nanobowl array

Fujian Provincial Key Laboratory of Ecology-Toxicological Effects & Control for Emerging Contaminants, Key Laboratory of Ecological Environment and Information Atlas, Fujian Provincial University, College of Environmental and Biological Engineering, Putian University, Putian, Fujian 351100, China

Corresponding author: Yan-Ying RAO, yanyingrao@ptu.edu.cn
Received Date: 30 September 2022
Revised Date: 18 December 2022

Figures(8)

Herein, we present a novel and simple method to fabricate a large-area ordered Au/Ag nanobowl (Au/AgNB) array based on SiO₂ colloidal crystals by wet chemosynthesis. The arrays combine the advantages of gold and silver and have been well recognized as excellent surface-enhanced Raman scattering (SERS) substrates in practical application. First of all, a 3D SiO₂ colloidal crystal was arrayed on the glass substrate as a template. Then, a layer of Au nanoshell (AuNS) was deposited on the 3D SiO₂ template by in-situ growth method with the help of Au nanoparticle (AuNP) seeds. Afterward, silver nanoshells were further deposited on the surface of AuNS by HCHO-reduced Ag⁺, then Ag/Au double nanoshell (Ag/AuNS) array was formed. A monolayer-ordered reversed Ag/AuNB array was conveniently obtained by an acrylic ester-modified biaxial-oriented polypropylene (BOPP). The ordered Au/AgNB array with adjustable periodic holes, shapes, and sizes could be obtained when the SiO₂ core was etched by HF solution. With prominent stability and reproducibility, the SERS analytical enhancement factor (AEF) of this ordered Au/AgNB array could reach 2.23×10⁷, which shows high SERS-enhancing activity and can be used as a universal SERS substrate.
- Au nanoshell,
- Ag/Au nanoshell,
- Au/Ag nanobowl,
- order array,
- surface-enhanced Raman scattering
1. [1]
  Zhai Q G, Bu X H, Mao C Y, Zhao X, Daemen L, Cheng Y Q, Ramirez-Cuesta A J, Feng P Y. An ultra-tunable platform for molecular engineering of high-performance crystalline porous materials[J]. Nat. Commun., 2016,713645. doi: 10.1038/ncomms13645
2. [2]
  Feng J R, Lv F, Zhang W Y, Li P H, Wang K, Yang C, Wang B, Yang Y, Zhou J H, Lin F, Wang G C, Guo S J. Iridium-Based multimetallic porous hollow nanocrystals for efficient overall-water-splitting catalysis[J]. Adv. Mater., 2017,29(47)1703798. doi: 10.1002/adma.201703798
3. [3]
  Seo J, Lee J, Kim Y. Ultrasensitive plasmon-free surface-enhanced Raman spectroscopy with femtomolar detection limit from 2D van der Waals heterostructure[J]. Nano Lett., 2020,20(3):1620-1630. doi: 10.1021/acs.nanolett.9b04645
4. [4]
  Zheng Y H, Soeriyadi A H, Rosa L, Ng S H, Bach U, Gooding J J. Reversible gating of smart plasmonic molecular traps using thermoresponsive polymers for single-molecule detection[J]. Nat. Commun., 2015,6(1):8797-8803. doi: 10.1038/ncomms9797
5. [5]
  Kong X M, Xi Y T, Le Duff P, Chong X Y, Li E, Ren F H, Rorrer G L, Wang A X. Detecting explosive molecules from nanoliter solution: A new paradigm of SERS sensing on hydrophilic photonic crystal biosilica[J]. Biosens. Bioelectron., 2017,88:63-70. doi: 10.1016/j.bios.2016.07.062
6. [6]
  Zou X, Silva R, Huang X, Alsharab J F, Asefa T. A self-cleaning porous TiO₂-Ag core-shell nanocomposite material for surface-enhanced Raman scattering[J]. Chem. Commun., 2013,49(4):382-384. doi: 10.1039/C2CC35917K
7. [7]
  Zhong L B, Yin J, Zheng Y M, Liu Q, Cheng X X, Luo F H. Self-assembly of Au nanoparticles on PMMA template as flexible, transparent, and highly active SERS substrates[J]. Anal. Chem., 2014,86(13):6262-6267. doi: 10.1021/ac404224f
8. [8]
  Gahlaut S K, Savargaonkar D, Sharan C, Yadav S, Singh J P. SERS platform for dengue diagnosis from clinical samples employing a hand held Raman spectrometer[J]. Anal. Chem., 2020,92(3):2527-2534. doi: 10.1021/acs.analchem.9b04129
9. [9]
  Imai R, Tanaka M, Hashimoto H, Asoh H. Facile synthesis of size-and shape-controlled freestanding Au nanohole arrays by sputter deposition using anodic porous alumina templates[J]. Nanotechnology, 2020,31(41)415303. doi: 10.1088/1361-6528/ab9f76
10. [10]
  Hong G S, Li C, Qi L M. Facile fabrication of two-dimensionally ordered macroporous silver thin films and their application in molecular sensing[J]. Adv. Funct. Mater., 2010,20(21):3774-3783. doi: 10.1002/adfm.201001177
11. [11]
  Dong Y H, Laaksonen A, Huo F, Gao Q W, Ji X Y. Hydrated ionic liquids boost the trace detection capacity of proteins on TiO₂ support[J]. Langmuir, 2021,37(16):5012-5021. doi: 10.1021/acs.langmuir.1c00525
12. [12]
  Reza K K, Wang J, Vaidyanathan R, Dey S, Wang Y L, Trau M. Electrohydrodynamic-induced SERS immunoassay for extensive multiplexed biomarker sensing[J]. Small, 2017,13(9)1602902. doi: 10.1002/smll.201602902
13. [13]
  Wang Z Y, Zong S F, Li W, Wang C L, Xu S H, Chen H, Cui Y P. SERS-fluorescence joint spectral encoding using organic-metal-QD hybrid nanoparticles with a huge encoding capacity for high-throughput biodetection: Putting theory into practice[J]. J. Am. Chem. Soc., 2012,134(6):2993-3000. doi: 10.1021/ja208154m
14. [14]
  Fang S, Hung H C, Sinclair A, Peng Z, Tao B, Galvan D D, Jain P, Li B W, Jiang S Y, Yu Q M. Hierarchical zwitterionic modification of a SERS substrate enables real-time drug monitoring in blood plasma[J]. Nat. Commun., 2016,7(7)13437.
15. [15]
  Sandeep S P, Gonzalo R G, Siraj S, Tazara L L, Claramaria R G, Inocencio H C, Pedro C S, Tanya C V, Elder D R. Ultra-sensitive SERS substrate for label-free therapeutic drug monitoring of paclitaxel and cyclophosphamide in blood serum[J]. Anal. Chem., 2019,91(3):2100-2111. doi: 10.1021/acs.analchem.8b04523
16. [16]
  Panikar S S, Banu N, Escobar E R, García G R, Cervantes-Martínez J, Villegas T C, Salas P, Rosa E D. Stealth modified bottom up SERS substrates for label-free therapeutic drug monitoring of doxorubicin in blood serum[J]. Talanta, 2020,218121138. doi: 10.1016/j.talanta.2020.121138
17. [17]
  Tang H B, Meng G W, Huang Q, Zhang Z, Huang Z L, Zhu C H. Arrays of cone-shaped ZnO nanorods decorated with Ag nanoparticles as 3D surface-enhanced Raman scattering substrates for rapid detection of trace polychlorinated biphenyls[J]. Adv. Funct. Mater., 2012,22:218-224. doi: 10.1002/adfm.201102274
18. [18]
  Sánchez-Iglesias A, Aldeanueva-Potel P, Ni W, Pérez-Juste J, Pastoriza-Santos I, Alvarez-Puebla R A, Mbenkum B N, Liz-Marzán L M. Chemical seeded growth of Ag nanoparticle arrays and their application as reproducible SERS substrates[J]. Nano Today, 2010,5(1):21-27. doi: 10.1016/j.nantod.2010.01.002
19. [19]
  Ding C Q, Tian Y. Gold nanocluster-based fluorescence biosensor for targeted imaging in cancer cells and ratiometric determination of intracellular pH[J]. Biosens. Bioelectron., 2015,65:183-190. doi: 10.1016/j.bios.2014.10.034
20. [20]
  Li Y, Zhang Y L, Zhao M, Zhou Q Q, Wang L L, Wang H Z, Wang X H, Zhan L S. A simple aptamer-functionalized gold nanorods based biosensor for the sensitive detection of MCF-7 breast cancer cells[J]. Chem. Commun., 2016,52:3959-3961. doi: 10.1039/C6CC01014H
21. [21]
  Liao S, Luo Z, Metternich J B, Zenobi R, Stellacci F. Quantification of surface composition and segregation on AuAg bimetallic nanoparticles by MALDI MS[J]. Nanoscale, 2020,12(44):22639-22644. doi: 10.1039/D0NR05061J
22. [22]
  Liao W L, Liu K, Chen Y J, Hu J P, Gan Y. Au-Ag bimetallic nanoparticles decorated silicon nanowires with fixed and dynamic hot spots for ultrasensitive 3D SERS sensing[J]. J. Alloy. Compd., 2021,868159136. doi: 10.1016/j.jallcom.2021.159136
23. [23]
  Rao Y Y, Zhao X X, Li Z L, Huang J H. Phenolic acids induced growth of 3D ordered gold nanoshell composite array as sensitive SERS nanosensor for antioxidant capacity assay[J]. Talanta, 2018,190:174-181. doi: 10.1016/j.talanta.2018.07.069
24. [24]
  Rao Y Y, Tao Q, An M, Rong C H, Dong J, Dai Y R, Qian W P. Novel and simple route to fabricate 2D ordered gold nanobowl arrays based on 3D colloidal crystals[J]. Langmuir, 2011,27(21):13308-13313. doi: 10.1021/la203158q
25. [25]
  RAO Y Y, LI Z L, HUANG J H, JIANG Y H, ZHAO X X. Preparation and SERS properties of 3D ordered gold nanoshells arrays[J]. Chinese J. Inorg. Chem., 2018,34(7):1231-1239.
26. [26]
  Jiang J, Bosnick K, Maillard M, Brus L. Single molecule Raman spectroscopy at the junctions of large Ag nanocrystals[J]. J. Phys. Chem. B, 2003,107(37):9964-9972. doi: 10.1021/jp034632u
27. [27]
  Kim K, Choi J Y, Shin K S. Raman scattering characterization of 1,4-phenylenediisocyanide in Au-Au and Ag-Au Nanogaps[J]. Spectroc. Acta Pt. A-Molec. Biomolec. Spectr., 2013,100:3-9. doi: 10.1016/j.saa.2012.01.045
28. [28]
  Do Nascimento G M, Temperini M. Studies on the resonance Raman spectra of polyaniline obtained with near-IR excitation[J]. J. Raman Spectrosc., 2008,39(7):772-778. doi: 10.1002/jrs.1841
29. [29]
  Su Q Q, Ma X Y, Dong J, Jiang C Y, Qian W P. A reproducible SERS substrate based on electrostatically assisted APTES-functionalized surface-assembly of gold nanostars[J]. ACS Appl. Mater. Interfaces, 2011,3(6):1873-1879. doi: 10.1021/am200057f
1. [1]
  Liang MA , Honghua ZHANG , Weilu ZHENG , Aoqi YOU , Zhiyong OUYANG , Junjiang CAO . Construction of highly ordered ZIF-8/Au nanocomposite structure arrays and application of surface-enhanced Raman spectroscopy. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1743-1754. doi: 10.11862/CJIC.20240075
2. [2]
  Ce Liang , Qiuhui Sun , Adel Al-Salihy , Mengxin Chen , Ping Xu . Recent advances in crystal phase induced surface-enhanced Raman scattering. Chinese Chemical Letters, 2024, 35(9): 109306-. doi: 10.1016/j.cclet.2023.109306
3. [3]
  Chengde Wang , Liping Huang , Shanshan Wang , Lihao Wu , Yi Wang , Jun Dong . A distinction of gliomas at cellular and tissue level by surface-enhanced Raman scattering spectroscopy. Chinese Chemical Letters, 2024, 35(5): 109383-. doi: 10.1016/j.cclet.2023.109383
4. [4]
  Xue Xin , Qiming Qu , Islam E. Khalil , Yuting Huang , Mo Wei , Jie Chen , Weina Zhang , Fengwei Huo , Wenjing Liu . Hetero-phase zirconia encapsulated with Au nanoparticles for boosting electrocatalytic nitrogen reduction. Chinese Chemical Letters, 2024, 35(5): 108654-. doi: 10.1016/j.cclet.2023.108654
5. [5]
  Guorong Li , Yijing Wu , Chao Zhong , Yixin Yang , Zian Lin . Predesigned covalent organic framework with sulfur coordination: Anchoring Au nanoparticles for sensitive colorimetric detection of Hg(Ⅱ). Chinese Chemical Letters, 2024, 35(5): 108904-. doi: 10.1016/j.cclet.2023.108904
6. [6]
  Peng ZHOU , Xiao CAI , Qingxiang MA , Xu LIU . Effects of Cu doping on the structure and optical properties of Au₁₁(dppf)₄Cl₂ nanocluster. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1254-1260. doi: 10.11862/CJIC.20240047
7. [7]
  Bing LIU , Huang ZHANG , Hongliang HAN , Changwen HU , Yinglei ZHANG . Visible light degradation of methylene blue from water by triangle Au@TiO₂ mesoporous catalyst. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 941-952. doi: 10.11862/CJIC.20230398
8. [8]
  Gengchen Guo , Tianyu Zhao , Ruichang Sun , Mingzhe Song , Hongyu Liu , Sen Wang , Jingwen Li , Jingbin Zeng . Au-Fe₃O₄ dumbbell-like nanoparticles based lateral flow immunoassay for colorimetric and photothermal dual-mode detection of SARS-CoV-2 spike protein. Chinese Chemical Letters, 2024, 35(6): 109198-. doi: 10.1016/j.cclet.2023.109198
9. [9]
  Yuan Zhang , Shenghao Gong , A.R. Mahammed Shaheer , Rong Cao , Tianfu Liu . Plasmon-enhanced photocatalytic oxidative coupling of amines in the air using a delicate Ag nanowire@NH₂-UiO-66 core-shell nanostructures. Chinese Chemical Letters, 2024, 35(4): 108587-. doi: 10.1016/j.cclet.2023.108587
10. [10]
  Jun-Jie Fang , Zheng Liu , Yun-Peng Xie , Xing Lu . Superatomic Ag₅₈ nanoclusters incorporating a [MS₄@Ag₁₂]²⁺ (M = Mo or W) kernel show aggregation-induced emission. Chinese Chemical Letters, 2024, 35(10): 109345-. doi: 10.1016/j.cclet.2023.109345
11. [11]
  Yifen He , Chao Qu , Na Ren , Dawei Liang . Enhanced degradation of refractory organics in ORR-EO system with a blue TiO₂ nanotube array modified Ti-based Ni-Sb co-doped SnO₂ anode. Chinese Chemical Letters, 2024, 35(8): 109262-. doi: 10.1016/j.cclet.2023.109262
12. [12]
  Kexin Dong , Chuqi Shen , Ruyu Yan , Yanping Liu , Chunqiang Zhuang , Shijie Li . Integration of Plasmonic Effect and S-Scheme Heterojunction into Ag/Ag₃PO₄/C₃N₅ Photocatalyst for Boosted Photocatalytic Levofloxacin Degradation. Acta Physico-Chimica Sinica, 2024, 40(10): 2310013-. doi: 10.3866/PKU.WHXB202310013
13. [13]
  Guangming YIN , Huaiyao WANG , Jianhua ZHENG , Xinyue DONG , Jian LI , Yi'nan SUN , Yiming GAO , Bingbing WANG . Preparation and photocatalytic degradation performance of Ag/protonated g-C₃N₄ nanorod materials. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1491-1500. doi: 10.11862/CJIC.20240086
14. [14]
  Yi YANG , Shuang WANG , Wendan WANG , Limiao CHEN . Photocatalytic CO₂ reduction performance of Z-scheme Ag-Cu₂O/BiVO₄ photocatalyst. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 895-906. doi: 10.11862/CJIC.20230434
15. [15]
  Min WANG , Dehua XIN , Yaning SHI , Wenyao ZHU , Yuanqun ZHANG , Wei ZHANG . Construction and full-spectrum catalytic performance of multilevel Ag/Bi/nitrogen vacancy g-C₃N₄/Ti₃C₂T_x Schottky junction. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1123-1134. doi: 10.11862/CJIC.20230477
16. [16]
  Zhaohong Chen , Mengzhen Li , Jinfei Lan , Shengqian Hu , Xiaogang Chen . Organic ferroelastic enantiomers with high T_c and large dielectric switching ratio triggered by order-disorder and displacive phase transition. Chinese Chemical Letters, 2024, 35(10): 109548-. doi: 10.1016/j.cclet.2024.109548
17. [17]
  Wenhao Chen , Jian Du , Hanbin Zhang , Hancheng Wang , Kaicheng Xu , Zhujun Gao , Jiaming Tong , Jin Wang , Junjun Xue , Ting Zhi , Longlu Wang . Surface treatment of GaN nanowires for enhanced photoelectrochemical water-splitting. Chinese Chemical Letters, 2024, 35(9): 109168-. doi: 10.1016/j.cclet.2023.109168
18. [18]
  Tiantian Man , Fulin Zhu , Yaqi Huang , Yuhao Piao , Yan Su , Shengyuan Deng , Ying Wan . Mobile mini-fluorimeter for antibiotic aptasensing based on surface-plasmonic effect of burlike nanogolds enhanced by digitized imaging diagnosis. Chinese Chemical Letters, 2024, 35(5): 109036-. doi: 10.1016/j.cclet.2023.109036
19. [19]
  Jie Ren , Hao Zong , Yaqun Han , Tianyi Liu , Shufen Zhang , Qiang Xu , Suli Wu . Visual identification of silver ornament by the structural color based on Mie scattering of ZnO spheres. Chinese Chemical Letters, 2024, 35(9): 109350-. doi: 10.1016/j.cclet.2023.109350
20. [20]
  Zhiwei Zhong , Yanbin Huang , Wantai Yang . A simple photochemical method for surface fluorination using perfluoroketones. Chinese Chemical Letters, 2024, 35(5): 109339-. doi: 10.1016/j.cclet.2023.109339

Get Citation

PDF

XML

Metrics

PDF Downloads(4)
Abstract views(658)
HTML views(70)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142