Citation: Quan-Liang YANG, Meng-Jiao XU, Xia FENG, ROUZITUOHUTI Amannisaihan, MULATI Kulisen, JUMA Asihati. Preparation, luminescence properties, and energy transfer of color-tunable whitlockite-type Ca₈MgBi(PO₄)₇∶Ce³⁺, Tb³⁺ phosphors[J]. Chinese Journal of Inorganic Chemistry, ;2023, 39(3): 415-421. doi: 10.11862/CJIC.2023.016 shu

Preparation, luminescence properties, and energy transfer of color-tunable whitlockite-type Ca₈MgBi(PO₄)₇∶Ce³⁺, Tb³⁺ phosphors

State Key Laboratory of Chemistry and Utilization of Carbon Based Energy Resources, College of Chemistry, Xinjiang University, Urumqi 830017, China

Corresponding author: Meng-Jiao XU, xmj_1117@163.com
Received Date: 26 July 2022
Revised Date: 3 January 2023

Figures(4)

A series of Ca₈MgBi(PO₄)₇∶Ce³⁺, Tb³⁺ phosphors with whitlockite-type structure and adjustable color were prepared by the high-temperature solid-phase method. The phase composition, microstructure, and luminescence properties were studied by X-ray powder diffraction (XRD), scanning electron microscope (SEM), and fluorescence spectroscopy. X-ray diffraction results confirmed doping a small amount of Ce³⁺ and Tb³⁺ did not change the crystal structure of the matrix. The energy transfer between Ce³⁺-Tb³⁺ was confirmed by the fluorescence spectrum and fluorescence lifetime curve. The energy transfer mechanism was quadrupole-quadrupole interaction, and the energy transfer efficiency could reach 81%. The emission color of the series Ca₈MgBi(PO₄)₇∶0.08Ce³⁺, yTb³⁺ phosphors can be adjusted from blue light to green light by changing the doping concentrations of Tb³⁺, realizing the controllable emission color change.
- whitlockite structure,
- color-tunable,
- luminescence material,
- Ce³⁺,
- Tb³⁺,
- energy transfer
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Preparation, luminescence properties, and energy transfer of color-tunable whitlockite-type Ca8MgBi(PO4)7∶Ce3+, Tb3+ phosphors

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通讯作者: 陈斌, bchen63@163.com

Preparation, luminescence properties, and energy transfer of color-tunable whitlockite-type Ca₈MgBi(PO₄)₇∶Ce³⁺, Tb³⁺ phosphors