Citation: Qi YUAN, Gao-Bin LIU, Sen WANG. Effect of B₂O₃-Bi₂O₃-ZnO-Al₂O₃ glass additive on sintering condition, crystal structure, and dielectric properties of BaTiO₃ ceramics[J]. Chinese Journal of Inorganic Chemistry, ;2023, 39(3): 485-491. doi: 10.11862/CJIC.2023.014 shu

Effect of B₂O₃-Bi₂O₃-ZnO-Al₂O₃ glass additive on sintering condition, crystal structure, and dielectric properties of BaTiO₃ ceramics

School of Materials and Metallurgy Engineering, University of Science and Technology Liaoning, Anshan, Liaoning 114051, China

Corresponding author: Sen WANG, wsenl@yeah.net
Received Date: 23 September 2022
Revised Date: 12 December 2022

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The effects of B₂O₃-Bi₂O₃-ZnO-Al₂O₃ (BBZA) glass on the sintering conditions, crystal structure, and dielectric properties of barium titanate (BaTiO ₃) ceramics were investigated. The results show that the addition of the appropriate amount of BBZA glass powder can effectively reduce the sintering temperature of BaTiO₃ ceramics from 1 350 to 950 ℃ and make it densified. Consequently, the structure of BaTiO₃ phase changed (cubic phase → tetragonal phase) with the increase of sintering temperature after adding BBZA glass. Additionally, the Curie peak of BaTiO₃ ceramics were effectively suppressed and broadened. The ceramic microstructure showed that the glass phase was uniformly distributed on the surface of BaTiO₃ grains. The optimized preparing conditions for the BaTiO₃ ceramics were as follows: the addition (mass fraction) of BBZA glass was 2.0% and the sintering temperature was 950 ℃. The BaTiO₃ ceramics prepared under these conditions had a dielectric constant of 1 364 and a dielectric loss as low as 1.2%. When the sintering temperature was higher than 950℃, the addition amount of BBZA glass should not be greater than 2.0%, too much BBZA glass will lead to the semiconducting of BaTiO₃.
- BaTiO₃,
- B₂O₃-Bi₂O₃-ZnO-Al₂O₃ glass,
- low-temperature sintering
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Effect of B2O3-Bi2O3-ZnO-Al2O3 glass additive on sintering condition, crystal structure, and dielectric properties of BaTiO3 ceramics

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通讯作者: 陈斌, bchen63@163.com

Effect of B₂O₃-Bi₂O₃-ZnO-Al₂O₃ glass additive on sintering condition, crystal structure, and dielectric properties of BaTiO₃ ceramics