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Citation: Zhi-Wen HU, Wei-Xia DONG, Qi-Fu BAO, Ping LI. Preparation and piezocatalytic properties of Rubik's cube-like nano-microstructure BaTiO3[J]. Chinese Journal of Inorganic Chemistry, ;2023, 39(3): 475-484. doi: 10.11862/CJIC.2023.013 shu

Preparation and piezocatalytic properties of Rubik's cube-like nano-microstructure BaTiO3

  • 1.

    School of Materials Science and Engineering, Jingdezhen Ceramic University, Jingdezhen, Jiangxi 333403, China

  • 2.

    State Key Laboratory of Silicon Materials, Zhejiang University, Hangzhou 310027, China

  • Corresponding author: Wei-Xia DONG, weixia_dong@sina.com
  • Received Date: 16 September 2022
    Revised Date: 23 December 2022

Figures(11)

  • Rubik's cube-like nano-microstructure BaTiO 3 was synthesized via a simple solvothermal method by changing the molar ratio of Ba to Ti, and its piezocatalytic performance was characterized by degrading 5 mg·L-1 rhodamine B (RhB) solution. The morphology and phase structure of as-synthesized samples were analyzed by scanning electron microscopy (SEM), X-ray diffraction (XRD), and Fourier transform infrared spectra (FT-IR). The piezo-catalytic performance of synthesized BaTiO3 was investigated. The results exhibited that as-synthesized samples presented a Rubik's cube-like tetragonal BaTiO3 which assembled from cubes when the molar ratio of Ba to Ti was 1∶1. Under the condition of ultrasonic frequency of 40 kHz and ultrasonic power of 360 W, the degradation rate reached 90% at 180 min, the degradation rate was 79.7%, and changed to 11.4% after five cycles, which is superior to photocatalytic performance. During the degradation process, as-synthesized Rubik's cube-like BaTiO3 showed more excellent piezocatalytic performance with better piezocatalytic activity and durability than photocatalytic.
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