Citation: Ying-Min GUO, Hui ZHAO, Xue-Dong MA, Wei WANG, Yu-Kun MA, Cun-She ZHANG. Preparation and electrochemical properties of phenanthroline copper coordination Schiff base conducting polymers[J]. Chinese Journal of Inorganic Chemistry, ;2023, 39(3): 395-405. doi: 10.11862/CJIC.2023.012 shu

Preparation and electrochemical properties of phenanthroline copper coordination Schiff base conducting polymers

Ying-Min GUO ¹ ,
Hui ZHAO ¹ ,
Xue-Dong MA ¹ ,
Wei WANG ^{1, 2,,} ,
Yu-Kun MA ¹ ,
Cun-She ZHANG ³

1.
Department of Chemical Engineering, School of Water and Environment, Chang'an University, Xi'an 710054, China
2.
Key Laboratory of Subsurface Hydrology and Ecology in Arid Areas, Ministry of Education, Chang'an University, Xi'an 710054, China
3.
Key Laboratory of Petroleum Fine Chemicals of Shaanxi Province, Shaanxi Research Design Institute of Petroleum and Chemical Industry, Xi'an 710054, China

Corresponding author: Wei WANG, wwchem@chd.edu.cn
Received Date: 14 July 2022
Revised Date: 19 December 2022

Figures(10)

Preparation and electrochemical properties of Schiff base OTTP prepared from o-toluidine and p-benzal-dehyde polymers doped with various proportions of phenanthroline copper complexes. The copper coordination poly-mer [Cu(Phen)Cl₂]_X-OTTP (X was the molar ratio of Schiff base to phenanthroline copper coordination complex, X=1, 0.8, 0.6, 0.4, 0.2) of Schiff base phenanthroline was synthesized by doping different proportions of phenanthroline copper complexes in Schiff base. The morphology and structure of the products were investigated by scanning elec-tron microscopy (SEM), X-ray diffraction (XRD), and Fourier transform infrared spectroscopy (FT-IR), and the electrochemical performance of the electrode materials [Cu(Phen)Cl₂]_X-OTTP were analyzed by cyclic voltammetry (CV), galvanostatic charge-discharge (GCD), and electrochemical impedance spectrum (EIS). The results exhibited that the morphology of the polymer Schiff base changed after doping with phenanthroline copper complexes. After doping, the Schiff base was scaly, with more holes on the surface and the layered structure was destroyed. The matrix π-π stacking was affected. In 6 mol·L^-1 KOH electrolyte three-electrode system, [Cu(Phen)Cl₂]_0.4-OTTP had a high specific capacity of 278 mAh·g^-1 at the current density of 0.5 A·g^-1. The assembled supercapacitor [Cu(Phen)Cl₂]_0.4-OTTP//AC (AC=activated carbon) had a power density of 276.99 W·kg^-1 at the energy density of 26.16 Wh·kg^-1, and kept original specific capacity of 97.13% after 10 000 GCD cycles at current density of 10 A·g^-1.
- Schiff base polymer,
- supercapattery,
- electrode material,
- π-π stacking
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