Citation: Xian-Hui QI, Hong-Gang ZHAO, Yu-Hua MA, Zhuan-Hu WANG, Yun-Peng LI, Yu-Chen LI, Jia-Wen LI, Chen-Xiang YAN. Highly efficient BiOBr/red phosphorus heterojunction photocatalyst for Cr(Ⅵ) photoreduction[J]. Chinese Journal of Inorganic Chemistry, ;2023, 39(3): 563-574. doi: 10.11862/CJIC.2023.011 shu

Highly efficient BiOBr/red phosphorus heterojunction photocatalyst for Cr(Ⅵ) photoreduction

1.
College of Chemistry and Chemical Engineering, Xinjiang Normal University, Urumqi 830054, China
2.
Xinjiang Key Laboratory of Energy Storage and Photoelectrocatalytic Materials, Xinjiang Normal University, Urumqi 830054, China

Corresponding author: Hong-Gang ZHAO, 262385441@qq.com Yu-Hua MA, 15199141253@163.com
Received Date: 18 October 2022
Revised Date: 7 December 2022

Figures(8)

Herein, hydrothermally treated red phosphorus (HRP) was combined with bismuth bromide oxide (BiOBr) to construct BiOBr/HRP heterostructure composite. Regulating and optimizing the composition ratio, 7%BiOBr/HRP (The mass fraction of BiOBr in the composite was 7%) exhibited the highest photocatalytic activity, the rate constant for visible light reduction of Cr(Ⅵ) was 0.188 min^-1, which was five times higher than that of pure HRP (0.037 6 min^-1). The heterojunction composite constructed by introducing wide band gap BiOBr into narrow band gap HRP expanded the visible spectral absorption range, enhanced the light absorption, and accelerated the separation of photo-generated electrons and holes.
- red phosphorus,
- BiOBr,
- heterojunctions,
- Cr(Ⅵ),
- photocatalysis
1. [1]
  Wei K X, Faraj Y, Yao G, Xie R Z, Lai B. Strategies for improving perovskite photocatalysts reactivity for organic pollutants degradation: A review on recent progress[J]. Chem. Eng. J., 2021,414128783. doi: 10.1016/j.cej.2021.128783
2. [2]
  Ansari S A, Khan Z, Ansari M O, Cho M H. Earth-abundant stable elemental semiconductor red phosphorus-based hybrids for environmental remediation and energy storage applications[J]. RSC Adv., 2016,6(50):44616-44629. doi: 10.1039/C6RA06145A
3. [3]
  Wu C X, Jing L, Deng J G, Liu Y X, Li S, Lv S J, Sun Y J, Zhang Q C, Dai H X. Elemental red phosphorus-based photocatalysts for environmental remediation: A review[J]. Chemosphere, 2021,274129793. doi: 10.1016/j.chemosphere.2021.129793
4. [4]
  Li S T, Wang P F, Zhao H X, Wang R D, Jing R S, Meng Z L, Li W Z, Zhang Z L, Liu Y Y, Zhang Q, Li Z. Fabrication of black phosphorus nanosheets/BiOBr visible light photocatalysts via the co-precipitation method[J]. Colloids Surf. A, 2021,612125967. doi: 10.1016/j.colsurfa.2020.125967
5. [5]
  Wang Z Z, Wang K, Li Y, Jiang L S, Zhang G K. Novel BiSbO₄/BiOBr nanoarchitecture with enhanced visible-light driven photocatalytic performance: Oxygen-induced pathway of activation and mechanism unveiling[J]. Appl. Surf. Sci., 2019,498143850. doi: 10.1016/j.apsusc.2019.143850
6. [6]
  Zhu Y K, Ren J, Zhang X L, Yang D J. Elemental red phosphorus-based materials for photocatalytic water purification and hydrogen production[J]. Nanoscale, 2020,12(25):13297-13310. doi: 10.1039/D0NR01748E
7. [7]
  Qi L L, Dong K Y, Zeng T, Liu J Y, Fan J, Hu X Y, Jia W L, Liu E Z. Three-dimensional red phosphorus: A promising photocatalyst with excellent adsorption and reduction performance[J]. Catal. Today, 2018,314:42-51. doi: 10.1016/j.cattod.2018.01.002
8. [8]
  Guo C C, Du H, Ma Y H, Qi K Z, Zhu E Q, Su Z, Huojiaaihemaiti M, Wang X. Visible-light photocatalytic activity enhancement of red phosphorus dispersed on the exfoliated kaolin for pollutant degradation and hydrogen evolution[J]. J. Colloid Interface Sci., 2021,585:167-177. doi: 10.1016/j.jcis.2020.11.055
9. [9]
  Yuan Y P, Cao S W, Liao Y S, Yin L S, Xue C. Red phosphor/g-C₃N₄ heterojunction with enhanced photocatalytic activities for solar fuels production[J]. Appl. Catal. B-Environ., 2013,140-141:164-168. doi: 10.1016/j.apcatb.2013.04.006
10. [10]
  Zhu Y K, Li J Z, Dong C L, Ren J, Huang Y C, Zhao D M, Cai R S, Wei D X, Yang X F, Lv C X, Theis W G, Bu Y Y, Han W, Shen S H, Yang D J. Red phosphorus decorated and doped TiO₂ nanofibers for efficient photocatalytic hydrogen evolution from pure water[J]. Appl. Catal. B-Environ., 2019,255117764. doi: 10.1016/j.apcatb.2019.117764
11. [11]
  Zhu E Q, Ma Y H, Du H, Qi K Z, Ainiwa M, Su Z. Three-dimensional bismuth oxide/red phosphorus heterojunction composite with enhanced photoreduction activity[J]. Appl. Surf. Sci., 2020,528146932. doi: 10.1016/j.apsusc.2020.146932
12. [12]
  Wang J, Pi M Y, Zhang D K, Chen S J. The visible-light photocatalytic activity for enhancing RhB degradation and hydrogen evolution from SrTiO₃ nanoparticles decorated red phosphorus nanorods as photocatalysts[J]. J. Phys. D: Appl. Phys., 2020,53(8)085501. doi: 10.1088/1361-6463/ab58df
13. [13]
  Zong S K, Wei W, Cui H L, Jiang Z F, Lü X M, Zhang M, Xie J M. A novel synthesis of P/BiPO₄ nanocomposites with enhanced visible-light photocatalysis[J]. Mater. Res. Innovations, 2015,19(5):361-367. doi: 10.1179/1433075X15Y.0000000013
14. [14]
  Majhi D, Das K, Mishra A, Dhiman R, Mishra B G. One pot synthesis of CdS/BiOBr/Bi₂O₂CO₃: A novel ternary double Z-scheme heterostructure photocatalyst for efficient degradation of atrazine[J]. Appl. Catal. B-Environ., 2020,260118222. doi: 10.1016/j.apcatb.2019.118222
15. [15]
  Imam S S, Adnan R, Mohd Kaus N H. Immobilization of BiOBr into cellulose acetate matrix as hybrid film photocatalyst for facile and multicycle degradation of ciprofloxacin[J]. J. Alloy. Compd., 2020,843155990. doi: 10.1016/j.jallcom.2020.155990
16. [16]
  Gao Z Y, Yao B H, Xu T T, Ma M M. Effect and study of reducing agent NaBH₄ on Bi/BiOBr/CdS photocatalyst[J]. Mater. Lett., 2020,259126874. doi: 10.1016/j.matlet.2019.126874
17. [17]
  Mao W T, Bao K Y, Cao F P, Chen B K, Liu G Y, Wang W B, Li B B. Synthesis of a CoTiO₃/BiOBr heterojunction composite with enhanced photocatalytic performance[J]. Ceram. Int., 2017,43(3):3363-3368. doi: 10.1016/j.ceramint.2016.11.180
18. [18]
  Ren X Z, Wu K, Qin Z G, Zhao X C, Yang H. The construction of type Ⅱ heterojunction of Bi₂WO₆/BiOBr photocatalyst with improved photocatalytic performance[J]. J. Alloy. Compd., 2019,788:102-109. doi: 10.1016/j.jallcom.2019.02.211
19. [19]
  Zhang J L, Zhang L S, Shen X F, Xu P F, Liu J S. Synthesis of BiO-Br/WO₃ p-n heterojunctions with enhanced visible light photocatalytic activity[J]. CrystEngComm, 2016,18(21):3856-3865. doi: 10.1039/C6CE00824K
20. [20]
  Bai Y, Shi X, Wang P Q, Wnag L, Zhang K, Zhou Y, Xie H Q, Wang J N, Ye L Q. BiOBr_xI_1-x/BiOBr heterostructure engineering for efficient molecular oxygen activation[J]. Chem. Eng. J., 2019,356:34-42. doi: 10.1016/j.cej.2018.09.006
21. [21]
  Heidari S, Haghighi M, Shabani M. Sunlight-activated BiOCl/BiOBr-Bi₂₄O₃₁Br₁₀ photocatalyst for the removal of pharmaceutical compounds[J]. J. Cleaner Prod., 2020,259120679. doi: 10.1016/j.jclepro.2020.120679
22. [22]
  Zou X J, Dong Y Y, Zhang X D, Cui Y B, Ou X X, Qi X H. The highly enhanced visible light photocatalytic degradation of gaseous o-dichlorobenzene through fabricating like-flowers BiPO₄/BiOBr p-n heterojunction composites[J]. Appl. Surf. Sci., 2017,391:525-534. doi: 10.1016/j.apsusc.2016.06.003
23. [23]
  Kim S R, Jo W K. Boosted photocatalytic decomposition of nocuous organic gases over tricomposites of N-doped carbon quantum dots, ZnFe₂O ₄, and BiOBr with different junctions[J]. J. Hazard. Mater., 2019,380120866. doi: 10.1016/j.jhazmat.2019.120866
24. [24]
  Cao Q W, Cui X, Zheng Y F, Song X C. A novel CdWO₄/BiOBr p-n heterojunction as visible light photocatalyst[J]. J. Alloy. Compd., 2016,670:12-17. doi: 10.1016/j.jallcom.2016.02.061
25. [25]
  Fu S, Yuan W, Liu X M, Yan Y H, Liu H P, Li L, Zhao F Y, Zhou J G. A novel 0D/2D WS₂/BiOBr heterostructure with rich oxygen vacancies for enhanced broad-spectrum photocatalytic performance[J]. J. Colloid Interface Sci., 2020,569:150-163. doi: 10.1016/j.jcis.2020.02.077
26. [26]
  Guo Y X, Huang H W, He Y, Tian N, Zhang T R, Chu P K, An Q, Zhang Y H. In situ crystallization for fabrication of a core-satellite structured BiOBr-CdS heterostructure with excellent visible-light-responsive photoreactivity[J]. Nanoscale, 2015,7(27):11702-11711. doi: 10.1039/C5NR02246K
27. [27]
  Han A J, Zhang H W, Lu D, Sun J L, Chuah G K, Jaenicke S. Efficient photodegradation of chlorophenols by BiOBr/NaBiO₃ heterojunctioned composites under visible light[J]. J. Hazard. Mater., 2018,341:83-92. doi: 10.1016/j.jhazmat.2017.07.031
28. [28]
  Hu T P, Yang Y, Dai K, Zhang J F, Liang C H. A novel Z-scheme Bi₂MoO₆/BiOBr photocatalyst for enhanced photocatalytic activity under visible light irradiation[J]. Appl. Surf. Sci., 2018,456:473-481. doi: 10.1016/j.apsusc.2018.06.186
29. [29]
  Zhu E Q, Zhao S X, Du H, Ma Y H, Qi K Z, Guo C C, Su Z, Wang X, Wu Z D, Wang Z H. Construction of Bi₂Fe₄O₉/red phosphorus heterojunction for rapid and efficient photoreduction of Cr(Ⅵ)[J]. J. Am. Ceram. Soc., 2021,104(10):5411-5423. doi: 10.1111/jace.17782
30. [30]
  Chen X, Zhang X, Li Y H, Qi M Y, Li J Y, Tang Z R, Zhou Z, Xu Y J. Transition metal doping BiOBr nanosheets with oxygen vacancy and exposed {102} facets for visible light nitrogen fixation[J]. Appl. Catal. B-Environ., 2021,281119516. doi: 10.1016/j.apcatb.2020.119516
31. [31]
  Kannan V, Arredondo M, Johann F, Hesse D, Labrugere C, Maglione M, Vrejoiu I. Strain dependent microstructural modifications of BiCrO₃ epitaxial thin films[J]. Thin Solid Films, 2013,545:130-139. doi: 10.1016/j.tsf.2013.07.053
32. [32]
  Gao M C, Zhang D F, Pu X P, Li H, Lv D D, Zhang B B, Shao X. Facile hydrothermal synthesis of Bi/BiOBr composites with enhanced visible-light photocatalytic activities for the degradation of rhodamine B[J]. Sep. Purif. Technol., 2015,154:211-216. doi: 10.1016/j.seppur.2015.09.063
33. [33]
  Basaleh A, Ismail A A, Mohamed R M. Novel visible light heterojunction CdS/Gd₂O ₃ nanocomposites photocatalysts for Cr(Ⅵ) photoreduction[J]. J. Alloy. Compd., 2022,927166988. doi: 10.1016/j.jallcom.2022.166988
34. [34]
  Bao Y C, Chen K Z. Novel Z-scheme BiOBr/reduced graphene oxide/protonated g-C₃N ₄ photocatalyst: Synthesis, characterization, visible light photocatalytic activity and mechanism[J]. Appl. Surf. Sci., 2018,437:51-61. doi: 10.1016/j.apsusc.2017.12.075
35. [35]
  CHEN Y S, ZHENG J F, ZHU S L, XIONG M Y, NIE L H. One-step hydrothermal preparation and performance of BiOBr/BiPO₄ p-n heterojunction photocatalyst[J]. Chinese J. Inorg. Chem., 2021,37(10):1828-1838. doi: 10.11862/CJIC.2021.213
36. [36]
  An W J, Cui W Q, Liang Y H, Hu J S, Liu L. Surface decoration of BiPO ₄ with BiOBr nanoflakes to build heterostructure photocatalysts with enhanced photocatalytic activity[J]. Appl. Surf. Sci., 2015,351:1131-1139. doi: 10.1016/j.apsusc.2015.06.098
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