Citation: Zhao-Yu WANG, Zhao-Jie YANG, Jin-Tian CHENG, Jin-Yi CHEN, Ming-Wen ZHANG. Vis-NIR light-responsive direct Z-scheme LaNiO3/CdS heterojunction photocatalysts for H2 evolution[J]. Chinese Journal of Inorganic Chemistry, ;2023, 39(3): 533-544. doi: 10.11862/CJIC.2023.007 shu

Vis-NIR light-responsive direct Z-scheme LaNiO3/CdS heterojunction photocatalysts for H2 evolution

  • Corresponding author: Ming-Wen ZHANG, mwzhang1989@163.com
  • Received Date: 16 August 2022
    Revised Date: 4 December 2022

Figures(13)

  • The Vis-NIR light-responsive direct Z-scheme LaNiO3/CdS nanohybrid was synthesized via a refluxing method, fully characterized, and used in photocatalytic H2 evolution. The H2 evolved over LaNiO3/CdS photocatalyst in 5 h was 737 μmol under visible light irradiation, which was 4.3 times that over CdS (172 μmol) ascribed to the formed heterojunction between LaNiO3 and CdS. Moreover, the introduced LaNiO3 extended the light absorption to the NIR region and the H2 evolution increased to 996 μmol under Vis-NIR light irradiation. LaNiO3 exhibited upconversion luminescence at 406 and 628 nm when excited at 808 nm, which means that LaNiO3 can generate charge carriers under NIR light irradiation, thereby further improving the efficiency of its photocatalytic H2 evolution.
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