Citation: Zhao-Yu WANG, Zhao-Jie YANG, Jin-Tian CHENG, Jin-Yi CHEN, Ming-Wen ZHANG. Vis-NIR light-responsive direct Z-scheme LaNiO₃/CdS heterojunction photocatalysts for H₂ evolution[J]. Chinese Journal of Inorganic Chemistry, ;2023, 39(3): 533-544. doi: 10.11862/CJIC.2023.007 shu

Vis-NIR light-responsive direct Z-scheme LaNiO₃/CdS heterojunction photocatalysts for H₂ evolution

Zhao-Yu WANG ^{1, 2} ,
Zhao-Jie YANG ¹ ,
Jin-Tian CHENG ¹ ,
Jin-Yi CHEN ¹ ,
Ming-Wen ZHANG ^{1, 2,,}

1.
Fujian Provincial Key Lab of Coastal Basin Environment, Fujian Polytechnic Normal University, Fuqing, Fujian 350300, China
2.
State Key Laboratory of Photocatalysis on Energy and Environment, College of Chemistry, Fuzhou University, Fuzhou 350002, China

Corresponding author: Ming-Wen ZHANG, mwzhang1989@163.com
Received Date: 16 August 2022
Revised Date: 4 December 2022

Figures(13)

The Vis-NIR light-responsive direct Z-scheme LaNiO₃/CdS nanohybrid was synthesized via a refluxing method, fully characterized, and used in photocatalytic H₂ evolution. The H₂ evolved over LaNiO₃/CdS photocatalyst in 5 h was 737 μmol under visible light irradiation, which was 4.3 times that over CdS (172 μmol) ascribed to the formed heterojunction between LaNiO₃ and CdS. Moreover, the introduced LaNiO₃ extended the light absorption to the NIR region and the H₂ evolution increased to 996 μmol under Vis-NIR light irradiation. LaNiO₃ exhibited upconversion luminescence at 406 and 628 nm when excited at 808 nm, which means that LaNiO₃ can generate charge carriers under NIR light irradiation, thereby further improving the efficiency of its photocatalytic H₂ evolution.
- LaNiO₃/CdS nanohybrid,
- photocatalytic H₂ evolution,
- NIR light-responsive,
- heterojunction,
- upconversion luminescence
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通讯作者: 陈斌, bchen63@163.com

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沈阳化工大学材料科学与工程学院沈阳 110142

Vis-NIR light-responsive direct Z-scheme LaNiO3/CdS heterojunction photocatalysts for H2 evolution

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通讯作者: 陈斌, bchen63@163.com

Vis-NIR light-responsive direct Z-scheme LaNiO₃/CdS heterojunction photocatalysts for H₂ evolution