Citation: Chuan-Wang ZENG, Xiao-Xiao LI, Jin-Ming ZENG, Cao LIU, Jia-Jun LAI, Xiao-Peng QI. Synergistic enhancement of catalytic water electrolysis performance of iron-cobalt-based materials by oxygen vacancies and phosphorus doping[J]. Chinese Journal of Inorganic Chemistry, ;2023, 39(2): 202-210. doi: 10.11862/CJIC.2023.006 shu

Synergistic enhancement of catalytic water electrolysis performance of iron-cobalt-based materials by oxygen vacancies and phosphorus doping

Chuan-Wang ZENG ^{1, 2} ,
Xiao-Xiao LI ^{1, 2} ,
Jin-Ming ZENG ^{1, 2} ,
Cao LIU ^{1, 2} ,
Jia-Jun LAI ^{1, 2} ,
Xiao-Peng QI ^{1, 2,,}

1.
Rare Earth College, Jiangxi University of Science and Technology, Ganzhou, Jiangxi 341400, China
2.
Ganzhou Key Laboratory of Hydrogen Materials and Devices, Ganzhou, Jiangxi 341000, China

Corresponding author: Xiao-Peng QI, qxpai@163.com
Received Date: 21 June 2022
Revised Date: 5 December 2022

Figures(7)

Oxygen vacancies and hetero atom filling play an important role in the catalytic performance of materials. To develop an efficient and stable water electrolysis catalyst, based on the oxygen vacancies and phosphorus doping, nanoflower structures with oxygen vacancy and phosphorus doping were synthesized on iron foam by in-situ immersion growth and two-step heat treatment as hydrogen evolution reaction (HER) and oxygen evolution reaction (OER) electrocatalysts. CoFe₂O₄ has been reported as a promising electrocatalyst for OER and oxygen reduction reaction (ORR). However, CoFe₂O₄ exhibits poor conductivity and slow electrocatalytic reaction in HER. The formation of oxygen vacancy (Ov) in CoFe₂O₄ can effectively regulate the electronic structure of the catalyst surface and contribute to the formation of more defects and vacancies, thus improving the activity of OER. Then, we added phosphorus atoms to fill the vacancy, and the prepared P-Ov-CoFe₂O₄/IF showed excellent performance of HER and OER in the alkaline electrocatalytic test. At the current density of 10 mA·cm^-2, the overpotentials of HER and OER were only 54 and 191 mV, and the Tafel slopes were 57 and 54 mV·dec^-1, respectively. The prepared electrocatalyst also dem-onstrated excellent cycling stability.
- oxygen vacancy,
- electrolysis,
- phosphorus doping,
- hydrogen evolution reaction,
- oxygen evolution reaction
1. [1]
  YUAN H F, MA Z Z, WANG S M, LI J P, WANG X G. Engineering oxygen vacancy-rich Co₃O₄ nanowire as high- efficiency and durable bifunctional electrocatalyst for overall alkaline water splitting[J]. CIESC Journal, 2020,71(12):5831-5841.
2. [2]
  Xu Q C, Jiang H, Zhang H X, Jiang H B, Li C Z. Phosphorus-driven mesoporous Co₃O₄ nanosheets with tunable oxygen vacancies for the enhanced oxygen evolution reaction[J]. Electrochim. Acta, 2018,259962967.
3. [3]
  FENG J W, ZHOU Q. Effect of different Co contents on structure of nanoporous Ni - Co and catalytic performance of hydrogen evolution[J]. Chinese J. Inorg. Chem., 2019,35(10):1746-1754. doi: 10.11862/CJIC.2019.215
4. [4]
  Zhu J, Hu L S, Zhao P X, Lee L Y S, Wong K Y. Recent advances in electrocatalytic hydrogen evolution using nanoparticles[J]. CrystEngComm, 2019,120(2):851-918.
5. [5]
  Jiang S H, Zhang R Y, Liu H X, Rao Y, Yu Y N, Chen S, Yue Q, Zhang Y N, Kang Y J. Promoting formation of oxygen vacancies in twodimensional cobalt-doped ceria nanosheets for efficient hydrogen evolution[J]. J. Am. Chem. Soc., 2020,142(14):6461-6466. doi: 10.1021/jacs.9b13915
6. [6]
  LI C, TIAN P, PANG H C, YE J W, NING G L. Tungsten doped ironnickel layered hydroxide for oxygen evolution and hydrogen evolution reaction[J]. Chinese J. Inorg. Chem., 2020,36(8)14921498.
7. [7]
  Huang Y R, Yang W W, Yu Y S, Hao S. Ordered mesoporous spinel CoFe₂O₄ as efficient electrocatalyst for the oxygen evolution reaction[J]. J. Electroanal. Chem., 2019,840:409-414. doi: 10.1016/j.jelechem.2019.04.010
8. [8]
  Yan Y T, Wang P C, Lin J H, Cao J, Qi J L. Modification strategies on transition metal-based electrocatalysts for efficient water splitting[J]. J. Energy Chem., 2021,58:446-462. doi: 10.1016/j.jechem.2020.10.010
9. [9]
  Zhang S F, Wei N, Yao Z J, Zhao X Y, Du M, Zhou Q S. Oxygen vacancy-based ultrathin Co₃O₄ nanosheets as a high-efficiency electrocatalyst for oxygen evolution reaction[J]. Int. J. Hydrog. Energy, 2021,46(7):5286-5295. doi: 10.1016/j.ijhydene.2020.11.072
10. [10]
  Zhang L H, Wei T, Jiang Z M, Liu C Q, Jiang H, Chang J, Sheng L Z, Zhou Q H, Yuan L B, Fan Z J. Electrostatic interaction in electrospun nanofibers: Double - layer carbon protection of CoFe₂O₄ nanosheets enabling ultralong-life and ultrahigh-rate lithium ion storage[J]. Nano Energy, 2018,48:238-247. doi: 10.1016/j.nanoen.2018.03.053
11. [11]
  Liu T T, Ma X, Liu D N, Hao S, Du G, Ma Y J, Asiri A M, Sun X P, Chen L. Mn doping of CoP nanosheets array: An efficient electrocatalyst for hydrogen evolution reaction with enhanced activity at all pH values[J]. ACS Catal., 2017,7(1):98-102. doi: 10.1021/acscatal.6b02849
12. [12]
  Nemiwal M, Gosu V, Zhang T C, Kumar D. Metal organic frameworks as electrocatalysts: Hydrogen evolution reactions and overall water splitting[J]. Int. J. Hydrog. Energy, 2021,46(17):10216-10238. doi: 10.1016/j.ijhydene.2020.12.146
13. [13]
  Zhang T W, Li Z F, Wang L K, Zhang Z X, Wang S W. Spinel CoFe₂O₄ supported by three dimensional graphene as high - performance bi-functional electrocatalysts for oxygen reduction and evolution reaction[J]. Int. J. Hydrog. Energy, 2019,44(3):1610-1619. doi: 10.1016/j.ijhydene.2018.11.120
14. [14]
  Wang Z Y, Chen J Y, Song E H, Wang N, Dong J C, Zhang X, Ajayan P M, Yao W, Wang C F, Liu J J, Shen J F, Ye M X. Manipulation on active electronic states of metastable phase β-NiMoO₄ for large current density hydrogen evolution[J]. Nat. Commun., 2021,12(1)5960. doi: 10.1038/s41467-021-26256-1
15. [15]
  Li Z H, Lv Z H, Liu X, Wang G X, Lin Y S, Xie G W, Jiang L H. Magnetic-field guided synthesis of highly active Ni-S-CoFe₂O₄ electrocatalysts for oxygen evolution reaction[J]. Renew. Energy, 2021,165:612-618. doi: 10.1016/j.renene.2020.11.083
16. [16]
  Bi J L, Zhai X J, Liu G S, Chi J Q, Wang X Y, Chen S J, Xiao Z Y, Wang L. Low loading of P modified Rh nanoparticles encapsulated in N, P-doped carbon for boosted and pH-universal hydrogen evolution reaction[J]. Int. J. Hydrog. Energy, 2022,47(6):3791-3800. doi: 10.1016/j.ijhydene.2021.11.036
17. [17]
  Guo J Q, Zhan Z X, Lei T, Yin P. Facile synthesis of self-supported intertwined columnar NiCoP as a high efficient electrocatalyst for hydrogen evolution reaction[J]. Int. J. Hydrog. Energy, 2022,47(9)59745989.
18. [18]
  Li J G, Sun H C, Lv L, Li Z S, Ao X, Xu C H, Li Y, Wang C D. Metalorganic framework - derived hierarchical (Co, Ni)Se₂@NiFe LDH hollow nanocages for enhanced oxygen evolution[J]. ACS Appl. Mater. Interfaces, 2019,11(8):8106-8114. doi: 10.1021/acsami.8b22133
19. [19]
  Wang F M, Chen J W, Qi X P, Yang H, Jiang H H, Deng Y Q, Liang T X. Increased nucleation sites in nickel foam for the synthesis of MoP@Ni₃P/NF nanosheets for bifunctional water splitting[J]. Appl. Surf. Sci., 2019,481:1403-1411. doi: 10.1016/j.apsusc.2019.03.200
20. [20]
  Wang H Q, Zhang X W, Wang J G, Liu H L, Hu S X, Zhou W J, Liu H, Wang X. Puffing quaternary Fe_xCo_yNi_1-x-yP nanoarray via kinetically controlled alkaline etching for robust overall water splitting[J]. Sci. China-Mater., 2020,63(6):1054-1064. doi: 10.1007/s40843-019-1268-7
21. [21]
  Zhuang L H, Ge L, Yang Y S, Li M R, Jia Y, Yao X D, Zhu Z H. Ultrathin iron-cobalt oxide nanosheets with abundant oxygen vacancies for the oxygen evolution reaction[J]. Adv. Mater., 2017,29(17)1606793. doi: 10.1002/adma.201606793
22. [22]
  Yan K L, Shang X, Liu Z Z, Dong B, Lu S S, Chi J Q, Gao W K, Chai Y M, Liu C G. A facile method for reduced CoFe₂O₄ nanosheets with rich oxygen vacancies for efficient oxygen evolution reaction[J]. Int. J. Hydrog. Energy, 2017,42(38):24150-24158. doi: 10.1016/j.ijhydene.2017.07.165
23. [23]
  Xiao Z H, Wang Y, Huang Y C, Wei Z X, Dong C L, Ma J M, Shen S H, Li Y F, Wang S Y. Filling the oxygen vacancies in Co₃O₄ with phosphorus: An ultra-efficient electrocatalyst for overall water splitting[J]. Energy Environ. Sci., 2017,10(12):2563-2569. doi: 10.1039/C7EE01917C
24. [24]
  Murthy A P, Theerthagiri J, Madhavan J, Murugan K. Highly active MoS₂/carbon electrocatalysts for the hydrogen evolution reaction— Insight into the effect of the internal resistance and roughness factor on the Tafel slope[J]. Phys. Chem. Chem. Phys., 2017,19(3):1988-1998. doi: 10.1039/C6CP07416B
25. [25]
  Huang L B, Zhao L, Zhang Y, Chen Y Y, Zhang Q H, Luo H, Zhang X, Tang T, Gu L, Hu J S. Self-limited on-site conversion of MoO₃ Nanodots into vertically aligned ultrasmall monolayer MoS₂ for efficient hydrogen evolution[J]. Adv. Energy Mater., 2018,8(21)1800734. doi: 10.1002/aenm.201800734
26. [26]
  Liang H F, Gandi A N, Anjum D H, Wang X B, Schwingenschlögl U, Alshareef H N. Plasma-assisted synthesis of NiCoP for efficient overall water splitting[J]. Nano Lett., 2016,16(12):7718-7725. doi: 10.1021/acs.nanolett.6b03803
1. [1]
  Qiangqiang SUN , Pengcheng ZHAO , Ruoyu WU , Baoyue CAO . Multistage microporous bifunctional catalyst constructed by P-doped nickel-based sulfide ultra-thin nanosheets for energy-efficient hydrogen production from water electrolysis. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1151-1161. doi: 10.11862/CJIC.20230454
2. [2]
  Kai CHEN , Fengshun WU , Shun XIAO , Jinbao ZHANG , Lihua ZHU . PtRu/nitrogen-doped carbon for electrocatalytic methanol oxidation and hydrogen evolution by water electrolysis. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1357-1367. doi: 10.11862/CJIC.20230350
3. [3]
  Endong YANG , Haoze TIAN , Ke ZHANG , Yongbing LOU . Efficient oxygen evolution reaction of CuCo₂O₄/NiFe-layered bimetallic hydroxide core-shell nanoflower sphere arrays. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 930-940. doi: 10.11862/CJIC.20230369
4. [4]
  Bo YANG , Gongxuan LÜ , Jiantai MA . Nickel phosphide modified phosphorus doped gallium oxide for visible light photocatalytic water splitting to hydrogen. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 736-750. doi: 10.11862/CJIC.20230346
5. [5]
  Zhengyu Zhou , Huiqin Yao , Youlin Wu , Teng Li , Noritatsu Tsubaki , Zhiliang Jin . Synergistic Effect of Cu-Graphdiyne/Transition Bimetallic Tungstate Formed S-Scheme Heterojunction for Enhanced Photocatalytic Hydrogen Evolution. Acta Physico-Chimica Sinica, 2024, 40(10): 2312010-. doi: 10.3866/PKU.WHXB202312010
6. [6]
  Wenlong LI , Xinyu JIA , Jie LING , Mengdan MA , Anning ZHOU . Photothermal catalytic CO₂ hydrogenation over a Mg-doped In₂O_3-x catalyst. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 919-929. doi: 10.11862/CJIC.20230421
7. [7]
  Jinyi Sun , Lin Ma , Yanjie Xi , Jing Wang . Preparation and Electrocatalytic Nitrogen Reduction Performance Study of Vanadium Nitride@Nitrogen-Doped Carbon Composite Nanomaterials: A Recommended Comprehensive Chemistry Experiment. University Chemistry, 2024, 39(4): 184-191. doi: 10.3866/PKU.DXHX202310094
8. [8]
  Chuanming GUO , Kaiyang ZHANG , Yun WU , Rui YAO , Qiang ZHAO , Jinping LI , Guang LIU . Performance of MnO₂-0.39IrO_x composite oxides for water oxidation reaction in acidic media. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1135-1142. doi: 10.11862/CJIC.20230459
9. [9]
  Tongtong Zhao , Yan Wang , Shiyue Qin , Liang Xu , Zhenhua Li . New Experiment Development: Upgrading and Regeneration of Discarded PET Plastic through Electrocatalysis. University Chemistry, 2024, 39(3): 308-315. doi: 10.3866/PKU.DXHX202309003
10. [10]
  Xi Xu , Chaokai Zhu , Leiqing Cao , Zhuozhao Wu , Cao Guan . Experiential Education and 3D-Printed Alloys: Innovative Exploration and Student Development. University Chemistry, 2024, 39(2): 347-357. doi: 10.3866/PKU.DXHX202308039
11. [11]
  Hailang JIA , Hongcheng LI , Pengcheng JI , Yang TENG , Mingyun GUAN . Preparation and performance of N-doped carbon nanotubes composite Co₃O₄ as oxygen reduction reaction electrocatalysts. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 693-700. doi: 10.11862/CJIC.20230402
12. [12]
  Wenjiang LI , Pingli GUAN , Rui YU , Yuansheng CHENG , Xianwen WEI . C₆₀-MoP-C nanoflowers van der Waals heterojunctions and its electrocatalytic hydrogen evolution performance. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 771-781. doi: 10.11862/CJIC.20230289
13. [13]
  Wenxiu Yang , Jinfeng Zhang , Quanlong Xu , Yun Yang , Lijie Zhang . Bimetallic AuCu Alloy Decorated Covalent Organic Frameworks for Efficient Photocatalytic Hydrogen Production. Acta Physico-Chimica Sinica, 2024, 40(10): 2312014-. doi: 10.3866/PKU.WHXB202312014
14. [14]
  Yue Zhao , Yanfei Li , Tao Xiong . Copper Hydride-Catalyzed Nucleophilic Additions of Unsaturated Hydrocarbons to Aldehydes and Ketones. University Chemistry, 2024, 39(4): 280-285. doi: 10.3866/PKU.DXHX202309001
15. [15]
  Renxiao Liang , Zhe Zhong , Zhangling Jin , Lijuan Shi , Yixia Jia . A Palladium/Chiral Phosphoric Acid Relay Catalysis for the One-Pot Three-Step Synthesis of Chiral Tetrahydroquinoline. University Chemistry, 2024, 39(5): 209-217. doi: 10.3866/PKU.DXHX202311024
16. [16]
  Yifan LIU , Zhan ZHANG , Rongmei ZHU , Ziming QIU , Huan PANG . A three-dimensional flower-like Cu-based composite and its low-temperature calcination derivatives for efficient oxygen evolution reaction. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 979-990. doi: 10.11862/CJIC.20240008
17. [17]
  Pingping HAO , Fangfang LI , Yawen WANG , Houfen LI , Xiao ZHANG , Rui LI , Lei WANG , Jianxin LIU . Hydrogen production performance of the non-platinum-based MoS₂/CuS cathode in microbial electrolytic cells. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1811-1824. doi: 10.11862/CJIC.20240054
18. [18]
  Zongfei YANG , Xiaosen ZHAO , Jing LI , Wenchang ZHUANG . Research advances in heteropolyoxoniobates. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 465-480. doi: 10.11862/CJIC.20230306
19. [19]
  Heng Zhang . Determination of All Rate Constants in the Enzyme Catalyzed Reactions Based on Michaelis-Menten Mechanism. University Chemistry, 2024, 39(4): 395-400. doi: 10.3866/PKU.DXHX202310047
20. [20]
  Rui PAN , Yuting MENG , Ruigang XIE , Daixiang CHEN , Jiefa SHEN , Shenghu YAN , Jianwu LIU , Yue ZHANG . Selective electrocatalytic reduction of Sn(Ⅳ) by carbon nitrogen materials prepared with different precursors. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 1015-1024. doi: 10.11862/CJIC.20230433

Get Citation

PDF

XML

Metrics

PDF Downloads(18)
Abstract views(1136)
HTML views(154)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142