Citation: Yu-Kang MA, Jiao CHEN, Yi LI, Yu-Ting YANG, Hao-Yi ZHANG, Chun-Shan LU, Guang-Jun WU, Qiang XIAO. Gel-less steam-assisted crystallization of platelike MFI crystals for the fabrication of b-oriented zeolite membranes[J]. Chinese Journal of Inorganic Chemistry, ;2023, 39(2): 245-254. doi: 10.11862/CJIC.2023.005 shu

Gel-less steam-assisted crystallization of platelike MFI crystals for the fabrication of b-oriented zeolite membranes

1.
Key Laboratory of the Ministry of Education for Advanced Catalysis Materials, Institute of Advanced Fluorine Containing Materials, Zhejiang Normal University, Jinhua, Zhejiang 321004, China
2.
State Key Laboratory of Green Chemistry Synthesis Technology, Zhejiang University of Technology, Hangzhou 310032, China
3.
School of Materials Science and Engineering & National Institute for Advanced Materials, Nankai University, Tianjin 300350, China

Corresponding author: Qiang XIAO, xiaoq@zjnu.cn
Received Date: 13 July 2022
Revised Date: 29 November 2022

Figures(11)

Novel platelike MFI zeolite crystals were used as seeds to fabricate dense and flat MFI zeolite membranes with b-axis orientation on porous sintered quartz wool discs through a gel-free steam-assisted crystallization (GLSAC) method. Firstly, the platelike MFI crystals were coated on the porous support by a filtration method. Then the seeded support was dipped in a tetrapropylammonium hydroxide (TPAOH) aqueous solution followed by a drying step. Subsequently, the dried discs were heated in an autoclave with a small amount of water at the bottom to grow into continuous membranes. Influences of the TPAOH concentration, water at the autoclave bottom, temperature, and time on the MFI zeolite membranes were investigated. The results of the scanning electron microscope and X-ray diffraction show that the out-plane growth of the platelike MFI seeds was suppressed at an optimized TPAOH concentration and water content. A dense and flat MFI zeolite membrane with a thickness of about 750 nm was successfully prepared. Binary butane isomers separation tests revealed that a separation factor (SF_A/B) of 36 at a permeation rate of 1.5×10^-7 mol·m^-2·s^-1·Pa^-1 for n-butane was achieved.
- MFI zeolite membrane,
- gel-less steam-assisted crystallization,
- platelike MFI zeolite seeds,
- butane isomer separation
1. [1]
  Varoon K, Zhang X, Elyassi B, Brewer D D, Gettel M, Kumar S, Lee J A, Maheshwari S, Mittal I A, Sung C Y, Cococcioni M, Francis L F, Mccormick A V, Mkhoyan K A, Tsapatsis M. Dispersible exfoliated zeolite nanosheets and their application as a selective membrane[J]. Science, 2011,334(6052):72-75. doi: 10.1126/science.1208891
2. [2]
  Agrawal K V, Topuz B, Pham T C T, Nguyen T H, Sauer N, Rangnekar N, Zhang H, Narasimharao K, Basahel S N, Francis L F, Macosko C W, Al-Thabaiti S, Tsapatsis M, Yoon K B. Oriented MFI membranes by gel-less secondary growth of sub-100 nm MFI-nanosheet seed layers[J]. Adv. Mater., 2015,27(21):3243-3249. doi: 10.1002/adma.201405893
3. [3]
  Jeon M Y, Kim D, Kumar P, Lee P S, Rangnekar N, Bai P, Shete M, Elyassi B, Lee H S, Narasimharao K, Basahel S N, Al-Thabaiti S, Xu W, Cho H J, Fetisov E O, Thyagarajan R, Dejaco R F, Fan W, Mkhoyan K A, Siepmann J I, Tsapatsis M. Ultra-selective high-flux membranes from directly synthesized zeolite nanosheets[J]. Nature, 2017,543(7647):690-694. doi: 10.1038/nature21421
4. [4]
  Cao Z S, Zeng S X, Xu Z, Arvanitis A, Yang S W, Gu X H, Dong J H. Ultrathin ZSM-5 zeolite nanosheet laminated membrane for high-flux desalination of concentrated brines[J]. Sci. Adv., 2018,4eaau8634. doi: 10.1126/sciadv.aau8634
5. [5]
  Liu Y, Qiang W L, Ji T T, Zhang M, Li M R, Lu J M. Uniform hierarchical MFI nanosheets prepared via anisotropic etching for solution-based sub-100-nm-thick oriented MFI layer fabrication[J]. Sci. Adv., 2020,6eaay5993. doi: 10.1126/sciadv.aay5993
6. [6]
  Zhang H, Xiao Q, Guo X H, Li N J, Kumar P, Rangnekar N, Jeon M Y, Al-Thabaiti S, Narasimharao K, Basahel S N, Topuz B, Onorato F J, Macosko C W, Mkhoyan K A, Tsapatsis M. Open-pore two-dimen-sional MFI zeolite nanosheets for the fabrication of hydrocarbon-isomer-selective membranes on porous polymer supports[J]. Angew. Chem. Int. Ed., 2016,55(25):7184-7187. doi: 10.1002/anie.201601135
7. [7]
  WU Y Q, ZHENG L K, CHEN Q, YU M T, WANG J G, ZHANG F M, XIAO Q, ZHU W D. Fabrication of zeolite membrane using two-dimensional open-pore MFI nanosheets as building blocks[J]. Chinese J. Inorg. Chem., 2019,35(1):89-94.
8. [8]
  Dai W J, Kouvatas C, Tai W S, Wu G, Guan N J, Li L D, Valtchev V. Platelike MFI crystals with controlled crystal faces aspect ratio[J]. J. Am. Chem. Soc., 2021,143(4):1993-2004. doi: 10.1021/jacs.0c11784
9. [9]
  Wang Z, Zhang H Y, Ma Y K, Diao D D, Lu C S, Xiao Q, Wu G J, Li L D. Transfer printing platelike MFI crystals as seeds for the preparation of silicalite-1 membranes[J]. Microporous Mesoporous Mater., 2022,336111895. doi: 10.1016/j.micromeso.2022.111895
10. [10]
  Lu X F, Yang Y W, Zhang J J, Yan Y S, Wang Z B. Solvent-free secondary growth of highly b-oriented MFI zeolite films from anhydrous synthetic powder[J]. J. Am. Chem. Soc., 2019,141(7):2916-2919. doi: 10.1021/jacs.9b00018
11. [11]
  Han S C, Liu P, Ma Y, Wu Q M, Meng X J, Xiao F S. Calcinationfree fabrication of highly b-oriented silicalite-1 zeolite films by secondary growth in the absence of organic structure-directing agents[J]. Ind. Eng. Chem. Res., 2021,60(19):7167-7173. doi: 10.1021/acs.iecr.1c01102
12. [12]
  Pham T C T, Nguyen T H, Yoon K B. Gel-free secondary growth of uniformly oriented silica MFI zeolite films and application for xylene separation[J]. Angew. Chem. Int. Ed., 2013,52(33):8693-8698. doi: 10.1002/anie.201301766
13. [13]
  Banihashemi F, Lin J Y S. b-Oriented MFI zeolite membranes for xylene isomer separation-effect of xylene activity on separation performance[J]. J. Membr. Sci., 2022,652120492. doi: 10.1016/j.memsci.2022.120492
14. [14]
  Kim D, Ghosh S, Akter N, Kraetz A, Duan X, Gwak G, Rangnekar N, Johnson J R, Narasimharao K, Malik M A, Al-Thabaiti S, Mccool B, Boscoboinik J A, Mkhoyan K A, Tsapatsis M. Twin-free, directly synthesized MFI nanosheets with improved thickness uniformity and their use in membrane fabrication[J]. Sci. Adv., 2022,8eabm8162. doi: 10.1126/sciadv.abm8162
15. [15]
  Hrabanek P, Zikanova A, Drahokoupil J, Prokopova O, Brabec L, Jirka I, Matejkova M, Fila V, Iglesia O D L, Kocirik M. Combined silica sources to prepare preferentially oriented silicalite-1 layers on various supports[J]. Microporous Mesoporous Mater., 2013,174:154-162. doi: 10.1016/j.micromeso.2013.03.007
16. [16]
  Nian P, Su M H, Yu T, Wang Z, Zhang B X, Shao X L, Jin X Y, Jiang N Z, Li S, Ma Q. Fabrication of a highly b-oriented MFI-type zeolite film-modified electrode with molecular sieving properties by langmuir-blodgett method[J]. J. Mater. Sci., 2016,51(6):3257-3270. doi: 10.1007/s10853-015-9638-0
17. [17]
  Li X M, Peng Y, Wang Z B, Yan Y S. Synthesis of highly b-oriented zeolite MFI films by suppressing twin crystal growth during the secondary growth[J]. CrystEngComm, 2011,13(11):3657-3660. doi: 10.1039/c1ce05094j
18. [18]
  Liu Y, Li M R, Chen Z G, Cui Y, Lu J M. Hierarchy control of MFI zeolite membrane towards superior butane isomer separation performance[J]. Angew. Chem. Int. Ed., 2021,60(14):7659-7663. doi: 10.1002/anie.202017087
19. [19]
  Sun K, Liu B, Zhong S L, Wu A M, Wang B, Zhou R F, Kita H. Fast preparation of oriented silicalite-1 membranes by microwave heating for butane isomer separation[J]. Sep. Purif. Technol., 2019,219:90-99. doi: 10.1016/j.seppur.2019.03.018
20. [20]
  Stoeger J A, Choi J, Tsapatsis M. Rapid thermal processing and separation performance of columnar MFI membranes on porous stainless steel tubes[J]. Energy Environ. Sci., 2011,4(9):3479-3486. doi: 10.1039/c1ee01700d
21. [21]
  Qiu H, Xu N, Kong L, Zhang Y, Kong X, Wang M Q, Tang X X, Meng D N, Zhang Y F. Fast synthesis of thin silicalite-1 zeolite membranes at low temperature[J]. J. Membr. Sci., 2020,611118361. doi: 10.1016/j.memsci.2020.118361
22. [22]
  Kim E, Choi J, Tsapatsis M. On defects in highly a-oriented MFI membranes[J]. Microporous Mesoporous Mater., 2013,170:1-8. doi: 10.1016/j.micromeso.2012.11.023
23. [23]
  Jareman F, Hedlund J, Sterte J. Effects of aluminum content on the separation properties of MFI membranes[J]. Sep. Purif. Technol., 2003,32:159-163. doi: 10.1016/S1383-5866(03)00029-7
24. [24]
  Choi J, Jeong H K, Snyder M A, Stoeger J A, Masel R I, Tsapatsis M. Grain boundary defect elimination in a zeolite membrane by rapid thermal processing[J]. Science, 2009,325(5940):590-593. doi: 10.1126/science.1176095
25. [25]
  Wu A M, Tang C Y, Zhong S L, Wang B, Zhou J J, Zhou R F. Synthesis optimization of (h0h)-oriented silicalite-1 membranes for butane isomer separation[J]. Sep. Purif. Technol., 2019,214:51-60. doi: 10.1016/j.seppur.2018.02.023
1. [1]
  Jiao CHEN , Yi LI , Yi XIE , Dandan DIAO , Qiang XIAO . Vapor-phase transport of MFI nanosheets for the fabrication of ultrathin b-axis oriented zeolite membranes. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 507-514. doi: 10.11862/CJIC.20230403
2. [2]
  Conghao Shi , Ranran Wang , Juli Jiang , Leyong Wang . The Illustration on Stereoisomers of Macrocycles Containing Multiple Chiral Centers via Tröger Base-based Macrocycles. University Chemistry, 2024, 39(7): 394-397. doi: 10.3866/PKU.DXHX202311034
3. [3]
  Xiaolei Jiang , Fangdong Hu . Exploring the Mirror World in Organic Chemistry: the Teaching Design of “Enantiomers” from the Perspective of Curriculum and Ideological Education. University Chemistry, 2024, 39(10): 174-181. doi: 10.3866/PKU.DXHX202402052
4. [4]
  Yinyin Qian , Rui Xu . Utilizing VESTA Software in the Context of Material Chemistry: Analyzing Twin Crystal Nanostructures in Indium Antimonide. University Chemistry, 2024, 39(3): 103-107. doi: 10.3866/PKU.DXHX202307051
5. [5]
  Xingyang LI , Tianju LIU , Yang GAO , Dandan ZHANG , Yong ZHOU , Meng PAN . A superior methanol-to-propylene catalyst: Construction via synergistic regulation of pore structure and acidic property of high-silica ZSM-5 zeolite. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1279-1289. doi: 10.11862/CJIC.20240026
6. [6]
  Lan Ma , Cailu He , Ziqi Liu , Yaohan Yang , Qingxia Ming , Xue Luo , Tianfeng He , Liyun Zhang . Magical Surface Chemistry: Fabrication and Application of Oil-Water Separation Membranes. University Chemistry, 2024, 39(5): 218-227. doi: 10.3866/PKU.DXHX202311046
7. [7]
  Yan LIU , Jiaxin GUO , Song YANG , Shixian XU , Yanyan YANG , Zhongliang YU , Xiaogang HAO . Exclusionary recovery of phosphate anions with low concentration from wastewater using a CoNi-layered double hydroxide/graphene electronically controlled separation film. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1775-1783. doi: 10.11862/CJIC.20240043
8. [8]
  Yufang GAO , Nan HOU , Yaning LIANG , Ning LI , Yanting ZHANG , Zelong LI , Xiaofeng LI . Nano-thin layer MCM-22 zeolite: Synthesis and catalytic properties of trimethylbenzene isomerization reaction. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1079-1087. doi: 10.11862/CJIC.20240036
9. [9]
  Xiao Liu , Guangzhong Cao , Mingli Gao , Hong Wu , Hongyan Feng , Chenxiao Jiang , Tongwen Xu . Seawater Salinity Gradient Energy’s Job Application in the Field of Membranes. University Chemistry, 2024, 39(9): 279-282. doi: 10.3866/PKU.DXHX202306043
10. [10]
  Shuyu Liu , Xiaomin Sun , Bohan Song , Gaofeng Zeng , Bingbing Du , Chongshen Guo , Cong Wang , Lei Wang . Design and Fabrication of Phospholipid-Vesicle-based Artificial Cells towards Biomedical Applications. University Chemistry, 2024, 39(11): 182-188. doi: 10.12461/PKU.DXHX202404113
11. [11]
  Kexin Dong , Chuqi Shen , Ruyu Yan , Yanping Liu , Chunqiang Zhuang , Shijie Li . Integration of Plasmonic Effect and S-Scheme Heterojunction into Ag/Ag₃PO₄/C₃N₅ Photocatalyst for Boosted Photocatalytic Levofloxacin Degradation. Acta Physico-Chimica Sinica, 2024, 40(10): 2310013-. doi: 10.3866/PKU.WHXB202310013
12. [12]
  Lijun Huo , Mingcun Wang , Tianyi Zhao , Mingjie Liu . Exploration of Undergraduate and Graduate Integrated Teaching in Polymer Chemistry with Aerospace Characteristics. University Chemistry, 2024, 39(6): 103-111. doi: 10.3866/PKU.DXHX202312059
13. [13]
  Qiying Xia , Guokui Liu , Yunzhi Li , Yaoyao Wei , Xia Leng , Guangli Zhou , Aixiang Wang , Congcong Mi , Dengxue Ma . Construction and Practice of “Teaching-Learning-Assessment Integration” Model Based on Outcome Orientation: Taking “Structural Chemistry” as an Example. University Chemistry, 2024, 39(10): 361-368. doi: 10.3866/PKU.DXHX202311007
14. [14]
  Shengjuan Huo , Xiaoyan Zhang , Xiangheng Li , Xiangning Li , Tianfang Chen , Yuting Shen . Unveiling the Marvels of Titanium: Popularizing Multifunctional Colored Titanium Product Films. University Chemistry, 2024, 39(5): 184-192. doi: 10.3866/PKU.DXHX202310127
15. [15]
  Yingran Liang , Fei Wang , Jiabao Sun , Hongtao Zheng , Zhenli Zhu . Construction and Application of a New Experimental Device for Determination of Alkaline Metal Elements by Plasma Atomic Emission Spectrometry Based on Solution Cathode Glow Discharge: An Alternative Approach for Fundamental Teaching Experiments in Emission Spectroscopy. University Chemistry, 2024, 39(5): 380-387. doi: 10.3866/PKU.DXHX202312024
16. [16]
  Xuanzhu Huo , Yixi Liu , Qiyu Wu , Zhiqiang Dong , Chanzi Ruan , Yanping Ren . Integrated Experiment of “Electrolytic Preparation of Cu₂O and Gasometric Determination of Avogadro’s Constant: Implementation, Results, and Discussion: A Micro-Experiment Recommended for Freshmen in Higher Education at Various Levels Across the Nation. University Chemistry, 2024, 39(3): 302-307. doi: 10.3866/PKU.DXHX202308095
17. [17]
  Yuena Yang , Xufang Hu , Yushan Liu , Yaya Kuang , Jian Ling , Qiue Cao , Chuanhua Zhou . The Realm of Smart Hydrogels. University Chemistry, 2024, 39(5): 172-183. doi: 10.3866/PKU.DXHX202310125
18. [18]
  Peipei Sun , Jinyuan Zhang , Yanhua Song , Zhao Mo , Zhigang Chen , Hui Xu . 引入内建电场增强光载流子分离以促进H₂的生产. Acta Physico-Chimica Sinica, 2024, 40(11): 2311001-. doi: 10.3866/PKU.WHXB202311001
19. [19]
  Gonglan Ye , Xia Yin , Feng Xu , Peng Yang , Yingpeng Wu , Huilong Fei . Innovations in “Four-in-One” Inorganic Chemistry Education. University Chemistry, 2024, 39(8): 136-141. doi: 10.3866/PKU.DXHX202401071
20. [20]
  Zhuoming Liang , Ming Chen , Zhiwen Zheng , Kai Chen . Multidimensional Studies on Ketone-Enol Tautomerism of 1,3-Diketones By ¹H NMR. University Chemistry, 2024, 39(7): 361-367. doi: 10.3866/PKU.DXHX202311029

Get Citation

PDF

XML

Metrics

PDF Downloads(4)
Abstract views(699)
HTML views(69)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142