Citation: Man-Rong LIU, Er-Lin YUE, Ji-Jiang WANG, Wang-Chuan ZHU, Hang QUAN, Long TANG, Xiao WANG, Xiang-Yang HOU, Yu-Qi ZHANG. Selective detection of 2, 4, 6-trinitrophenol and fluazinam in water based on a 1D Zn(Ⅱ) coordination polymer[J]. Chinese Journal of Inorganic Chemistry, ;2023, 39(2): 375-384. doi: 10.11862/CJIC.2023.002 shu

Selective detection of 2, 4, 6-trinitrophenol and fluazinam in water based on a 1D Zn(Ⅱ) coordination polymer

Yan′an Key Laboratory of New Energy & New Functional Materials, Shaanxi Key Laboratory of Chemical Reaction Engineering, College of Chemistry and Chemical Engineering, Yan′an University, Yan′an, Shaanxi 716000, China

Corresponding author: Er-Lin YUE, yueerlin@yau.edu.com Ji-Jiang WANG, yadxwjj@126.com
Received Date: 11 October 2022
Revised Date: 23 November 2022

Figures(13)

A 1D coordination polymer [Zn₂(H₂L)₂(4, 4′-bpy)₂(H₂O)]_n (1) (H₄L=1, 1′∶4′, 1″∶4″, 1‴-quterphenyl-2, 4, 2‴, 4‴-tetracarboxylic acid, 4, 4′-bpy=4, 4′-bipyridine) was synthesized by hydrothermal method, and its structure was characterized by single-crystal X-ray diffraction analysis, elemental analysis, infrared spectroscopy, thermogravimetric analysis, etc. The crystallographic analysis shows that complex 1 belongs to the triclinic crystal system with the space group of P1. Complex 1 consists of two zinc ions with different coordination geometries, which lie in a distorted trigonal bipyramidal {ZnNO₄} and octahedral {ZnNO₅} geometrical configuration, respectively. The two H₂L^2-ligands in complex 1 are linked to each other by zinc ions, forming an infinite 1D zigzag planar structure. The fluorescence sensing experiments indicated that the fluorescence of complex 1 could be quenched by 2, 4, 6-trinitrophenol and fluazinam with high sensitivity and selectivity. Moreover, the anti-interference of detection was also quite excellent.
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