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Citation: Dan LIU, Liang ZHAO, Zhen SHAO, Yin-Shan MENG, Tao LIU. A 2D cyano-bridged WⅤ-CoⅡ coordination network exhibiting reversible thermal-induced charge transfer[J]. Chinese Journal of Inorganic Chemistry, ;2023, 39(2): 367-374. doi: 10.11862/CJIC.2023.001 shu

A 2D cyano-bridged WⅤ-CoⅡ coordination network exhibiting reversible thermal-induced charge transfer

  • State Key Laboratory of Fine Chemicals, Dalian University of Technology, Dalian, Liaoning 116024, China

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  • Magnetic bistable materials featuring switchable spin states are of substantial interest in terms of their promising application in memory devices and switches. Here, we report a new magnetic bistable compound based on WⅤ-CoⅡ charge transfer. A 2D cyano-bridged heterobimetallic network {[WⅤ (CN)8]2[CoⅡ (4-nvp)4]3}·4CH3OH (1) (4-nvp=4-(2-(naphthalene-1-yl)vinyl)pyridine) is synthesized by incorporating the 4-nvp into the cyano-bridged WⅤ-CoⅡ layer framework to provide intra-and intermolecular π-π interaction. Magnetic studies show that compound 1 exhibits a reversible electron-transfer-coupled spin transition (ETCST) with interconversion between the WⅤ—CN— CoHSⅡ (HS=high spin) and WⅣ —CN—CoLSⅢ (LS=low spin) linkages, accompanied by a thermal hysteresis with a width of about 27 K.
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