Citation: Jian SONG, Xing-Zhou SU, Qian-Nan YAO, Xue-Kun YANG, Yu-Long ZHAO, Ying-Huai QIANG, Chun-Guang REN. High performance perovskite solar cell based on passivation by a multifunctional amino acid derivative[J]. Chinese Journal of Inorganic Chemistry, ;2023, 39(2): 327-336. doi: 10.11862/CJIC.2022.292 shu

High performance perovskite solar cell based on passivation by a multifunctional amino acid derivative

1.
School of Materials Science and Physics, China University of Mining and Technology, Xuzhou, Jiangsu 221116, China
2.
College of Life Sciences, Yantai University, Yantai, Shandong 264000, China

Corresponding author: Jian SONG, jsoong@cumt.edu.cn Chun-Guang REN, cgren@ytu.edu.cn
Received Date: 18 September 2022
Revised Date: 28 November 2022

Figures(4)

Herein, we proposed a facial method to passivate surface defects on perovskite film by an amino acid derivative, Fmoc-Ile-OH molecule, which contains multifunctional groups, including carboxyl, amino, and Fmoc protecting group (with benzene ring). These functional groups exhibit a synergistic effect in improving perovskite film quality and stability. Specifically, we find that this modification could decrease the content of PbI₂ impurity and enlarge the particle size of perovskite film. Moreover, the optical and interface carrier transport properties were improved apparently. The better diode ideality factors, lower trap-filled limit voltages, and higher carrier recombination resistance for modified perovskite solar cells all demonstrated that Fmoc-Ile-OH could effectively passivate surface defects in perovskite films. Finally, we obtain a device with high conversion efficiency, 21.09%, which is much better than the control one, 18.00%.
- perovskite solar cell,
- passivation,
- multifunctional groups,
- amino acid derivative
1. [1]
  Kojima A, Teshima K, Shirai Y, Miyasaka T. Organometal halide perovskites as visible- light sensitizers for photovoltaic cells[J]. J. Am. Chem. Soc., 2009,131:6050-6051. doi: 10.1021/ja809598r
2. [2]
  Cai B, Xing Y D, Yang Z, Zhang W H, Qiu J S. High performance hybrid solar cells sensitized by organolead halide perovskites[J]. Energy Environ. Sci., 2013,6:1480-1485. doi: 10.1039/c3ee40343b
3. [3]
  Huang S, Shan H S, Xuan W F, Xu W J, Hu D N, Zhu L, Huang C, Sui W H, Xiao C J, Zhao Y L, Qiang Y H, Gu X Q, Song J, Zhou C. High-performance humidity sensor based on CsPdBr₃ nanocrystals for noncontact sensing of hydromechanical characteristics of unsaturated soil[J]. Phys. Status Solidi-Rapid Res. Lett., 2022,162200017. doi: 10.1002/pssr.202200017
4. [4]
  Li T T, Pan Y F, Wang Z, Xia Y D, Chen Y H, Huang W. Additive engineering for highly efficient organic - inorganic halide perovskite solar cells: Recent advances and perspectives[J]. J. Mater. Chem. A, 2017,5:12602-12652. doi: 10.1039/C7TA01798G
5. [5]
  Zheng X P, Hou Y, Bao C X, Yin J, Yuan F L, Huang Z R, Song K P, Liu J K, Troughton J, Gasparini N, Zhou C, Lin Y B, Xue D J, Chen B, Johnston A K, Wei N, Hedhili M N, Wei M Y, Alsalloum A Y, Maity P, Turedi B, Yang C, Baran D, Anthopoulos T D, Han Y, Lu Z H, Mohammed O F, Gao F, Sargent E H, Bakr O M. Managing grains and interfaces via ligand anchoring enables 22.3% - efficiency inverted perovskite solar cells[J]. Nat. Energy, 2020,5:131-140. doi: 10.1038/s41560-019-0538-4
6. [6]
  Chen Y, Yang Z, Wang S B, Zheng X J, Wu Y H, Yuan N Y, Zhang W H, Liu S Z. Design of an inorganic mesoporous hole- transporting layer for highly efficient and stable inverted perovskite solar cells[J]. Adv. Mater., 2018,301805660. doi: 10.1002/adma.201805660
7. [7]
  Xia Y R, Zhao C, Zhao P Y, Mao L Y, Ding Y C, Hong D C, Tian Y X, Yan W S, Jin Z. Pseudohalide substitution and potassium doping in FA_0.98K_0.02Pb(SCN)₂I for high-stability hole-conductor-free perovskite solar cells[J]. J. Power Sources, 2021,494229781. doi: 10.1016/j.jpowsour.2021.229781
8. [8]
  YANG Z S, KE W F, WANG Y X, HUANG L Q, GUO P C, ZHU H. Preparation and characterization of hybrid perovskite (NH₃C₆H₁₂NH₃) CuCl₄[J]. Chinese J. Inorg. Chem., 2017,33(9):1568-1572.
9. [9]
  Liang J, Zhao P Y, Wang C X, Wang Y R, Hu Y, Zhu G Y, Ma L B, Liu J, Jin Z. CsPb_0.9Sn_0.1IBr₂ based all-inorganic perovskite solar cells with exceptional efficiency and stability[J]. J. Am. Chem. Soc., 2017,139:14009-14012. doi: 10.1021/jacs.7b07949
10. [10]
  Eperon G E, Stranks S D, Menelaou C, Johnston M B, Herz L M, Snaith H J. Formamidinium lead trihalide: A broadly tunable perovskite for efficient planar heterojunction solar cells[J]. Energy Environ. Sci., 2014,7:982-988. doi: 10.1039/c3ee43822h
11. [11]
  Hong D C, Zhao P Y, Du Y, Zhao C, Xia Y R, Wei Z H, Jin Z, Tian Y X. Inhibition of phase segregation in cesium lead mixed - halide perovskites by B-site doping[J]. iScience, 2020,23101415. doi: 10.1016/j.isci.2020.101415
12. [12]
  Zhang H Y, Shi J J, Zhu L F, Luo Y H, Li D M, Wu H J, Meng Q B. Polystyrene stabilized perovskite component, grain and microstructure for improved efficiency and stability of planar solar cells[J]. Nano Energy, 2018,43:383-392. doi: 10.1016/j.nanoen.2017.11.024
13. [13]
  Cho A N, Park N G. Impact of interfacial layers in perovskite solar cells[J]. ChemSusChem, 2017,10:3687-3704. doi: 10.1002/cssc.201701095
14. [14]
  Park N G, Gratzel M, Miyasaka T, Zhu K, Emery K. Towards stable and commercially available perovskite solar cells[J]. Nat. Energy, 2016,116152. doi: 10.1038/nenergy.2016.152
15. [15]
  Song J, Zhao L, Huang S, Yan X F, Qiu Q Y, Zhao Y L, Zhu L, Qiang Y H, Li H S, Li G R. A p - p⁺ homojunction enhanced hole transfer in inverted planar perovskite solar cells[J]. ChemSusChem, 2021,14:1396-1403. doi: 10.1002/cssc.202100083
16. [16]
  Yu W, Yu S W, Zhang J, Liang W S, Wang X L, Guo X, Li C. Two-in-one additive-engineering strategy for improved air stability of planar perovskite solar cells[J]. Nano Energy, 2018,45:229-235. doi: 10.1016/j.nanoen.2017.12.041
17. [17]
  Pazos-Outon L M, Xiao T P, Yablonovitch E. Fundamental efficiency limit of lead iodide perovskite solar cells[J]. J. Phys. Chem. Lett., 2018,9:1703-1711. doi: 10.1021/acs.jpclett.7b03054
18. [18]
  Stranks S D. Nonradiative losses in metal halide perovskites[J]. ACS Energy Lett., 2017,2:1515-1525. doi: 10.1021/acsenergylett.7b00239
19. [19]
  Yang J C, Tang W J, Yuan R H, Chen Y, Wang J, Wu Y H, Yin W J, Yuan N Y, Ding J N, Zhang W H. Defect mitigation using D-penicillamine for efficient methylammonium-free perovskite solar cells with high operational stability[J]. Chem. Sci., 2021,122050. doi: 10.1039/D0SC06354A
20. [20]
  Chen B, Rudd P N, Yang S, Yuan Y B, Huang J S. Imperfections and their passivation in halide perovskite solar cells[J]. Chem. Soc. Rev., 2019,48:3842-3867. doi: 10.1039/C8CS00853A
21. [21]
  LUO Y, ZHANG G L, MA S P, ZHU C T, CHEN T, ZHANG L, ZHU L, GUO X Y, YANG Y. Effect of bilayer SnO₂ electron transport layer on the interfacial charge transport in perovskite solar cells[J]. Chinese J. Inorg. Chem., 2022,38(5):850-860.
22. [22]
  Shan H S, Xuan W F, Li Z, Hu D N, Gu X Q, Huang S. Room temperature hydrogen sulfide sensor based on tributyltin oxide-functionalized perovskite CsPbBr₃ quantum dots[J]. ACS Appl. Nano Mater., 2022,5:6801-6809. doi: 10.1021/acsanm.2c00791
23. [23]
  Shao Y H, Xiao Z G, Bi C, Yuan Y B, Huang J S. Origin and elimination of photocurrent hysteresis by fullerene passivation in CH₃NH₃PbI₃ planar heterojunction solar cells[J]. Nat. Commun., 2014,55784. doi: 10.1038/ncomms6784
24. [24]
  Abate A, Saliba M, Hollman D J, Stranks S D, Wojciechowski K, Avolio R, Grancini G, Petrozza A, Snaith H J. Supramolecular halogen bond passivation of organic - inorganic halide perovskite solar cells[J]. Nano Lett., 2014,14:3247-3254. doi: 10.1021/nl500627x
25. [25]
  Zheng X P, Chen B, Dai J, Fang Y J, Bai Y, Lin Y Z, Wei H T, Zeng X C, Huang J S. Defect passivation in hybrid perovskite solar cells using quaternary ammonium halide anions and cations[J]. Nat. Energy, 2017,217102. doi: 10.1038/nenergy.2017.102
26. [26]
  Yang S, Dai J, Yu Z H, Shao Y C, Zhou Y, Xiao X, Zeng X C, Huang J S. Tailoring passivation molecular structures for extremely small open-circuit voltage loss in perovskite solar cells[J]. J. Am. Chem. Soc., 2019,141:5781-5787. doi: 10.1021/jacs.8b13091
27. [27]
  Braly I L, deQuilettes D W, Pazos-Outón L M, Burke S, Ziffer M W, Ginger D S, Hillhouse H W. Hybrid perovskite films approaching the radiative limit with over 90% photoluminescence quantum efficiency[J]. Nat. Photonics, 2018,12355. doi: 10.1038/s41566-018-0154-z
28. [28]
  Xu J, Buin A, Ip A H, Li W, Voznyy O, Comin R, Yuan M J, Jeon S, Ning Z J, McDowell J J, Kanjanaboos P, Sun J P, Lan X Z, Quan L N, Kim D H, Hill I G, Maksymovych P, Sargent E H. Perovskite-fullerene hybrid materials suppress hysteresis in planar diodes[J]. Nat. Commun., 2015,67081. doi: 10.1038/ncomms8081
29. [29]
  Tan H R, Jain A, Voznyy O, Lan X Z, de Arquer F P G, Fan J Z, Quintero-Bermudez R, Yuan M J, Zhang B, Zhao Y C, Fan F J, Li P C, Quan L N, Zhao Y B, Lu Z H, Yang Z Y, Hoogland S, Sargent E H. Efficient and stable solution- processed planar perovskite solar cells via contact passivation[J]. Science, 2017,355:722-726. doi: 10.1126/science.aai9081
30. [30]
  HOU W J, MA Y T, HAN G Y. Secondary crystallization and passivation of perovskite film induced by dithizone post-treatment[J]. Chinese J.Inorg. Chem., 2021,37(8):1414-1420.
31. [31]
  Rajagopal A, Stoddard R J, Jo S B, Hillhouse H W, Jen A K. Overcoming the photovoltage plateau in large bandgap perovskite photovoltaics[J]. Nano Lett., 2018,18:3985-3993. doi: 10.1021/acs.nanolett.8b01480
32. [32]
  Wang F, Geng W, Zhou Y, Fang H H, Tong C J, Loi M A, Liu L M, Zhao N. Phenylalkylamine passivation of organolead halide perovskites enabling high - efficiency and air - stable photovoltaic cells[J]. Adv. Mater., 2016,28:9986-9992. doi: 10.1002/adma.201603062
33. [33]
  Cao Y, Wang N N, Tian H, Guo J S, Wei Y Q, Chen H, Miao Y F, Zou W, Pan K, He Y R, Cao H, Ke Y, Xu M M, Wang Y, Yang M, Du K, Fu Z W, Kong D C, Dai D X, Jin Y Z, Li G Q, Li H, Peng Q M, Wang J P, Huang W. Perovskite light - emitting diodes based on spontaneously formed submicrometre-scale structures[J]. Nature, 2018,562:249-253. doi: 10.1038/s41586-018-0576-2
34. [34]
  Zhang W W, Lei X L, Liu J H, Dong J, Yan X W, Gao W, Dong H, Ran C X, Wu Z X. Efficient charge collection promoted by interface passivation using amino acid toward high performance perovskite solar cells[J]. Phys. Status Solidi-Rapid Res. Lett., 2018,131800505.
35. [35]
  Choi M J, Lee Y S, Cho I H, Kim S S, Kim D H, Kwon S N, Na S I. Functional additives for high-performance inverted planar perovskite solar cells with exceeding 20% efficiency: Selective complexation of organic cations in precursors[J]. Nano Energy, 2020,71104639. doi: 10.1016/j.nanoen.2020.104639
36. [36]
  Zhang W Y, He L, Tang D Y, Li X. Surfactant sodium dodecyl ben-zene sulfonate improves the efficiency and stability of air-processed perovskite solar cells with negligible hysteresis[J]. Solar RRL, 2020,42000376. doi: 10.1002/solr.202000376
37. [37]
  Zhao L, Sun X W, Yao Q N, Huang S, Zhu L, Song J, Zhao Y L, Qiang Y H. Field-effect control in hole transport layer composed of Li: NiO/NiO for highly efficient inverted planar perovskite solar cells[J]. Adv. Mater. Interfaces, 2022,92101562. doi: 10.1002/admi.202101562
38. [38]
  Cui Q P, Zhao L, Sun X W, Yao Q N, Huang S, Zhu L, Zhao Y L, Song J, Qiang Y H. Charge transfer modification of inverted planar perovskite solar cells by NiO_x/Sr: NiO_x bilayer hole transport layer[J]. Chin. Phys. B, 2022,31038801. doi: 10.1088/1674-1056/ac1fda
39. [39]
  Qin Y S, Song J, Qiu Q Y, Liu Y, Zhao Y L, Zhu L, Qing Y H. High-quality NiO thin film by low - temperature spray combustion method for perovskite solar cells[J]. J. Alloy. Compd., 2019,810151970. doi: 10.1016/j.jallcom.2019.151970
40. [40]
  Yun S C, Ma S, Kwon H C, Kim K, Jang G, Yang H, Moon J. Amino acid salt - driven planar hybrid perovskite solar cells with enhanced humidity stability[J]. Nano Energy, 2019,59:481-491. doi: 10.1016/j.nanoen.2019.02.064
41. [41]
  Pretsch E, Bühlmann P, Badertscher M. Structure determination of organic compounds. Berlin: Springer-Verlag, 2000: 217
42. [42]
  Abdelmageed G, Mackeen C, Hellier K, Jewell L, Seymour L, Tingwald M, Bridges F, Zhang J, Carter S. Effect of temperature on light induced degradation in methylammonium lead iodide perovskite thin films and solar cells[J]. Sol. Energy Mater. Sol. Cells, 2018,174:566-571. doi: 10.1016/j.solmat.2017.09.053
43. [43]
  Zhu K P, Cong S, Lu Z, Lou Y H, He L, Li J M, Ding J N, Yuang N Y, Rümmeli M H, Zou G F. Enhanced perovskite solar cell performance via defect passivation with ethylamine alcohol chlorides additive[J]. J. Power Sources, 2019,428:82-87. doi: 10.1016/j.jpowsour.2019.04.056
44. [44]
  Yuan S H, Qian F, Yang S M, Cai Y, Wang Q, Sun J, Liu Z K, Liu S Z. NbF₅: A novel alpha - phase stabilizer for FA - based perovskite solar cells with high efficiency[J]. Adv. Funct. Mater., 2019,291807850. doi: 10.1002/adfm.201807850
45. [45]
  Wu S F, Li Z, Zhang J, Liu T T, Zhu Z L, Jen A K Y. Efficient large guanidinium mixed perovskite solar cells with enhanced photovoltage and low energy losses[J]. Chem. Commun., 2019,55:4315-4318. doi: 10.1039/C9CC00016J
46. [46]
  Song J, Qiu Q Y, Sun X W, Wang L L. Surface modification of perovskite film by an amino acid derivative for perovskite solar cell[J]. Org. Electron., 2022,108106598. doi: 10.1016/j.orgel.2022.106598
47. [47]
  Zhang P Y, Chen J J, Song L X, Gu N X, Du P F, Chen X, Zha L Y, Chen W H, Xiong J. Passivation of perovskite surfaces using 2-hydroxyacetophenone to fabricate solar cells with over 20.7% efficiency under air environment[J]. Appl. Surf. Sci., 2022,598153842. doi: 10.1016/j.apsusc.2022.153842
48. [48]
  Zhang M M, Hu W P, Shang Y B, Zhou W R, Zhang W F, Yang S F. Surface passivation of perovskite film by sodium toluenesulfonate for highly efficient solar cells[J]. Solar RRL, 2020,42000113. doi: 10.1002/solr.202000113
49. [49]
  Jiang H, Yan Z, Zhao H, Yuan S H, Yang Z, Li J, Liu B, Niu T Q, Feng J S, Wang Q, Wang D P, Yang H Q, Liu Z K, Liu S F. Bifunctional hydroxylamine hydrochloride incorporated perovskite films for efficient and stable planar perovskite solar cells[J]. ACS Appl. Energy Mater., 2018,1:900-909. doi: 10.1021/acsaem.8b00060
50. [50]
  Yang X Y, Luo D Y, Xiang Y R, Zhao L C, Anaya M, Shen Y L, Wu J, Yang W Q, Chiang Y H, Tu Y G, Su R, Hu Q, Yu H Y, Shao G S, Huang W, Russell T P, Gong Q H, Stranks S D, Zhang W, Zhu R. Buried interfaces in halide perovskite photovoltaics[J]. Adv. Mater., 2021,332006435. doi: 10.1002/adma.202006435
51. [51]
  Hu J L, Xu X, Chen Y J, Wu S H, Wang Z, Wang Y S, Jiang X F, Cai B Y, Shi T T, Brabec C J, Mai Y H, Guo F. Overcoming photovoltage deficit via natural amino acid passivation for efficient perovskite solar cells and modules[J]. J. Mater. Chem. A, 2021,9:5857-5865. doi: 10.1039/D0TA12342K
52. [52]
  Song J, Ren Y F, Gong S J, Zhao L, Xuan W F, Zhu L, Zhao Y L, Qiang Y H, Gao L L, Huang S. Performance enhancement of crystal silicon solar cell by a CsPbBr₃ - Cs₄PbBr₆ perovskite quantum dot@ZnO/ethylene vinyl acetate copolymer downshifting composite film[J]. Solar RRL, 2022,62200336. doi: 10.1002/solr.202200336
53. [53]
  Heo J, Im K, Lee H, Kim J, Im S. Ni, Ti-co-doped MoO₂ nanoparticles with high stability and improved conductivity for hole transporting material in planar metal halide perovskite solar cells[J]. J. Ind. Eng. Chem., 2021,94:376-383. doi: 10.1016/j.jiec.2020.11.010
54. [54]
  Protesescu L, Yakunin S, Bodnarchuk M I, Krieg F, Caputo R, Hendon C H, Yang R X, Walsh A, Kovalenko M V. Nanocrystals of cesium lead halide perovskites (CsPbX ₃, X=Cl, Br, and I): Novel optoelectronic materials showing bright emission with wide color gamut[J]. Nano Lett., 2015,15:3692-3696. doi: 10.1021/nl5048779
55. [55]
  De Roo J, Ibáñez M, Geiregat P, Nedelcu G, Walravens W, Maes J, Martins J, Van Driessche I, Kovalenko M, Hens Z. Highly dynamic ligand binding and light absorption coefficient of cesium lead bromide perovskite nanocrystals[J]. ACS Nano, 2016,10:2071-2081. doi: 10.1021/acsnano.5b06295
56. [56]
  Lindblad R, Bi D, Park B W, Oscarsson J, Gorgoi M, Siegbahn H, Odelius M, Johansson E M J, Rensmo H. Electronic structure of TiO₂/CH ₃NH₃PbI₃ perovskite solar cell interfaces[J]. J. Phys. Chem. Lett., 2014,5:648-653. doi: 10.1021/jz402749f
57. [57]
  Singh T, Miyasaka T. Stabilizing the efficiency beyond 20% with a mixed cation perovskite solar cell fabricated in ambient air under controlled humidity[J]. Adv. Energy Mater., 2018,81700677. doi: 10.1002/aenm.201700677
58. [58]
  Jia J B, Dong J, Wu J H, Wei H M, Cao B Q. Combustion procedure deposited SnO₂ electron transport layers for high efficient perovskite solar cells[J]. J. Alloy. Compd., 2020,844156032. doi: 10.1016/j.jallcom.2020.156032
59. [59]
  Liu X P, Wu J H, Guo Q Y, Yang Y Q, Luo H, Liu Q Z, Wang X B, He X, Huang M L, Lan Z. Pyrrole: An additive for improving the efficiency and stability of perovskite solar cells[J]. J. Mater. Chem. A, 2019,7:11764-11770. doi: 10.1039/C9TA02916H
60. [60]
  Nguyen M, Yoon S H, Kim K S. Hydrothermally fabricated TiO₂ heterostructure boosts efficiency of MAPbI₃ perovskite solar cells[J]. J. Ind. Eng. Chem., 2022,106:382-392. doi: 10.1016/j.jiec.2021.11.013
61. [61]
  Duan J L, Wang Y D, Yang X Y, Tang Q W. Alkyl-chain-regulated charge transfer in fluorescent inorganic CsPbBr₃ perovskite solar cells[J]. Angew. Chem. Int. Ed., 2020,59:4391-4395. doi: 10.1002/anie.202000199
62. [62]
  Song J, Yang Y, Zhao Y L, Che M, Zhu L, Gu X Q, Qiang Y H. Morphology modification of perovskite film by a simple post-treatment process in perovskite solar cell[J]. Mater. Sci. Eng. B, 2017,217:18-25. doi: 10.1016/j.mseb.2017.01.004
63. [63]
  Song J, Li S P, Zhao Y L, Yuan J, Zhu Y, Fang Y, Zhu L, Gu X Q, Qiang Y H. Performance enhancement of perovskite solar cells by doping TiO₂ blocking layer with group VB elements[J]. J. Alloy. Compd., 2017,694:1232-1238. doi: 10.1016/j.jallcom.2016.10.106
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  Pengyu Dong , Yue Jiang , Zhengchi Yang , Licheng Liu , Gu Li , Xinyang Wen , Zhen Wang , Xinbo Shi , Guofu Zhou , Jun-Ming Liu , Jinwei Gao . NbSe₂纳米片优化钙钛矿太阳能电池的埋底界面. Acta Physico-Chimica Sinica, 2025, 41(3): 2407025-. doi: 10.3866/PKU.WHXB202407025
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  Xinxin JING , Weiduo WANG , Hesu MO , Peng TAN , Zhigang CHEN , Zhengying WU , Linbing SUN . Research progress on photothermal materials and their application in solar desalination. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1033-1064. doi: 10.11862/CJIC.20230371
16. [16]
  Yuanyin Cui , Jinfeng Zhang , Hailiang Chu , Lixian Sun , Kai Dai . Rational Design of Bismuth Based Photocatalysts for Solar Energy Conversion. Acta Physico-Chimica Sinica, 2024, 40(12): 2405016-. doi: 10.3866/PKU.WHXB202405016
17. [17]
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18. [18]
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19. [19]
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20. [20]
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沈阳化工大学材料科学与工程学院沈阳 110142