Citation: Yan XU, Xuan WANG, Zhao-Wen LIU, Xiao-Yang WANG, Wen-Kang GAO, Lei CUI. Pyridinium/imidazolium-triggered modulation of structure and properties of cobalt naphthalene-diphosphates[J]. Chinese Journal of Inorganic Chemistry, ;2023, 39(2): 193-201. doi: 10.11862/CJIC.2022.291 shu

Pyridinium/imidazolium-triggered modulation of structure and properties of cobalt naphthalene-diphosphates

Department of Materials Science and Engineering, Suqian University, Suqian, Jiangsu 223800, China

Corresponding author: Yan XU, xuyan0511@126.com Lei CUI, 16077@squ.edu.cn
Received Date: 28 September 2022
Revised Date: 12 December 2022

Figures(6)

By the introduction of protonated 1, 3-di(4-pyridyl)propane (1, 3-dppH₂²⁺) and protonated bis(imidazol-1- ylmethyl)benzene (1, 4-bixH₂²⁺) as a cationic template, three new cobalt naphthalene-diphosphate coordination poly- mers based on 1, 4-naphthalenediphosphonic acid (1, 4-ndpaH₄), namely (1, 3-dppH₂)₂[Co₄(1, 4-ndpa)(1, 4-ndpaH)₂(1, 4-ndpaH₂)]·6H₂O (1), (1, 4-bixH₂)_0.5[Co(1, 4-ndpaH)] (2), and (1, 4-bixH₂)_0.5[Co₂(1, 4-ndpaH)(1, 4-ndpaH₂)(H₂O)₂] (3), have been hydrothermally synthesized. Complexes 1-3 were characterized by elemental analysis, infrared spectros- copy, single crystal X -ray diffraction, powder X -ray diffraction, and thermogravimetric analysis, respectively. In complexes 1 and 2, inorganic chains of corner-sharing {CoO₄} and {PO₃C} tetrahedron are cross-linked by naphtha- lene ligands into 3D open-framework structures. The protonated di-pyridinium/imidazolium moieties, 1, 3-dppH₂²⁺ for 2 and 1, 4-bixH₂²⁺ for 2, lie inside the skeletal voids of the crystal structure, respectively. Interestingly, complex 3 with similar chemical composition to 2 except for an additional 1, 4-ndpaH₂^2- ligand and two coordinated water mole- cules shows a 2D undulating layer structure, where the chains of corner-sharing {CoO₅} trigonal bipyramid, {CoO6} octahedron, and {PO₃C} tetrahedron are cross - linked by naphthalene groups. Adjacent layers are packed in AB stacking into the supramolecular structure, in which 1, 4-bixH₂²⁺ ions fill and balance the charge of 3. Magnetic stud- ies reveal that dominant antiferromagnetic interactions between the magnetic centers are propagated in complexes 1 and 2.
- coordination polymers,
- naphthalene-diphosphate ligand,
- template,
- crystal structure,
- magnetism
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