Citation: Liang WEI, Jian-Kai WANG, Kai-Ge LIU, Qing-Yun ZHOU, Hao-Xin PAN, Shan FAN, Yong ZHANG. Nanocellulose/reduced graphene oxide composites for high performance supercapacitors[J]. Chinese Journal of Inorganic Chemistry, ;2023, 39(3): 456-464. doi: 10.11862/CJIC.2022.287 shu

Nanocellulose/reduced graphene oxide composites for high performance supercapacitors

Liang WEI ^{1, 2} ,
Jian-Kai WANG ³ ,
Kai-Ge LIU ^{1, 2} ,
Qing-Yun ZHOU ^{1, 2} ,
Hao-Xin PAN ^{1, 2} ,
Shan FAN ^{1, 2,,} ,
Yong ZHANG ^{1, 2,,}

1.
School of Materials Science and Engineering, Qiqihar University, Qiqihar, Heilongjiang 161006, China
2.
Heilongjiang Province Key Laboratory of Polymeric Composition Material, Qiqihar, Heilongjiang 161006, China
3.
School of Chemistry and Chemical Engineering, Qiqihar University, Qiqihar, Heilongjiang 161006, China

Corresponding author: Shan FAN, leon1981@163.com Yong ZHANG, 15804528735@163.com
Received Date: 23 August 2022
Revised Date: 2 November 2022

Figures(7)

Nanocellulose/reduced graphene oxide (NC/rGO) composites were prepared by a simple one-step hydrothermal method using high-concentration graphene oxide (GO) solution as the reaction precursor and nanocellulose (NC) as the physical spacer and electrolyte reservoirs. Subsequently, we explored the potential of NC/rGO as electrode materials for supercapacitors. Due to its dense porous structure and large oxygen-containing functional group content, NC/rGO-1 prepared with 1 mL NC exhibited the best electrochemical performance. The binder-free symmetric supercapacitor based on NC/rGO-1 showed high gravimetric and volumetric specific capacitance of 269.33 F·g^-1 and 350.13 F·cm^-3 at a current density of 0.3 A·g^-1. These values can still reach 215.88 F·g^-1 and 280.62 F·cm^-3 at 10.0 A·g^-1 (80.15% of its initial value). The assembled device also displayed high gravimetric and volumetric energy densities (9.3 Wh·kg^-1 and 12.13 Wh·L^-1) and excellent cycling performance (the initial specific capacitance decreased by only 6.02% after 10 000 cycles at 10 A·g^-1).
- graphene,
- nanocellulose,
- supercapacitor
1. [1]
  Yang B Y, Qian Z M, Howard S W, Vaughn M G, Fan S J, Liu K K, Dong G H. Global association between ambient air pollution and blood pressure: A systematic review and meta-analysis[J]. Environ. Pollut., 2018,235:576-588. doi: 10.1016/j.envpol.2018.01.001
2. [2]
  Chu S, Majumdar A. Opportunities and challenges for a sustainable energy future[J]. Nature, 2012,488(7411):294-303. doi: 10.1038/nature11475
3. [3]
  Nechodom M, Schuetzle D, Ganz D, Cooper J. Sustainable forests, renewable energy, and the environment[J]. Environ. Sci. Technol., 2008,42(1):13-18. doi: 10.1021/es0870350
4. [4]
  LIU H, YANG D H, WANG X Y, HAN B H. Metal-organic framework-derived hollow carbon materials for electrochemical energy storage and oxygen reduction reaction[J]. Chinese J. Inorg. Chem., 2019,35(11):1921-1933.
5. [5]
  WU K, ZHANG G J. Energy and materials chemistry[J]. Acta Phys.-Chim. Sin., 2021,37(11):7-9.
6. [6]
  Choi J W, Aurbach D. Promise and reality of post-lithium-ion batteries with high energy densities[J]. Nat. Rev. Mater., 2016,1(4)16013. doi: 10.1038/natrevmats.2016.13
7. [7]
  Larcher D, Tarascon J M. Towards greener and more sustainable batteries for electrical energy storage[J]. Nat. Chem., 2015,7(1):19-29. doi: 10.1038/nchem.2085
8. [8]
  YANG L, WU T T, LI H Q, JIN B Y, HE X J. Preparation of nitrogendoped carbon nanonets for high-performance supercapacitors[J]. Chinese J. Inorg. Chem., 2021,37(6):1017-1026.
9. [9]
  Xu T Z, Li Z W, Wang D, Zhang M R, Ai L F, Chen Z Y, Zhang J H, Zhang X G, Shen L F. A fast proton-induced pseudocapacitive supercapacitor with high energy and power density[J]. Adv. Funct. Mater., 2022,322107720. doi: 10.1002/adfm.202107720
10. [10]
  Asl M S, Hadi R, Salehghadimi L, Tabrizi A G, Farhoudian S, Babapoor A, Pahlevani M. Flexible all-solid-state supercapacitors with high capacitance, long cycle life, and wide operational potential window: Recent progress and future perspectives[J]. J. Energy Storage, 2022,50104223. doi: 10.1016/j.est.2022.104223
11. [11]
  El-Kady M F, Shao Y L, Kaner R B. Graphene for batteries, supercapacitors and beyond[J]. Nat. Rev. Mater., 2016,1(7)16033. doi: 10.1038/natrevmats.2016.33
12. [12]
  Li P, Wang W Y, Su F Y, Wang X Y, Zhang X L, Zheng X C. N-doped interconnected porous graphene as advanced electrode material for supercapacitors[J]. J. Alloy. Compd., 2022,893162218. doi: 10.1016/j.jallcom.2021.162218
13. [13]
  Moreno-Fernandez G, Gomez-Urbano J L, Enterria M, Rojo T, Carriazo D. Correction: Flat-shaped carbon-graphene microcomposites as electrodes for high energy supercapacitors[J]. J. Mater. Chem. A, 2020,8(3)1486. doi: 10.1039/C9TA90299F
14. [14]
  Wang J, Xu Y L, Ding B, Chang Z, Zhang X G, Yamauchi Y, Wu K C W. Confined self-assembly in two-dimensional interlayer space: Monolayered mesoporous carbon nanosheets with in-plane orderly arranged mesopores and a highly graphitized framework[J]. Angew. Chem. Int. Ed., 2018,57(11):2894-2898. doi: 10.1002/anie.201712959
15. [15]
  Liu R N, Wang Y H, Wu X L. Two-dimensional nitrogen and oxygen Co-doping porous carbon nanosheets for high volumetric performance supercapacitors[J]. Microporous Mesoporous Mater., 2020,295109954. doi: 10.1016/j.micromeso.2019.109954
16. [16]
  Kumar H, Sharma R, Yadav A, Kumari R. Recent advancement made in the field of reduced graphene oxide-based nanocomposites used in the energy storage devices: A review[J]. J. Energy Storage., 2020,33102032.
17. [17]
  Olabi A G, Abdelkareem M A, Wilberforce T, Sayed E T. Application of graphene in energy storage device—A review[J]. Renew. Sust. Energ. Rev., 2021,135110026. doi: 10.1016/j.rser.2020.110026
18. [18]
  Lin Y M, Su S Y, Wang R, Dai H M, Lai L Q, Jiang Y, Zhu X H. Hydrothermal synthesis of reduced graphene oxide for supercapacitor electrode materials and the effect of added sodium alginate on its structure and performance[J]. J. Mater. Sci.-Mater. Electron., 2021,32(22):26688-26699. doi: 10.1007/s10854-021-07046-3
19. [19]
  Yi T, Zhao H Y, Mo Q, Pan D L, Liu Y, Huang L J, Xu H, Hu B, Song H N. From cellulose to cellulose nanofibrils—A comprehensive review of the preparation and modification of cellulose nanofibrils[J]. Materials, 2020,13(22)5062. doi: 10.3390/ma13225062
20. [20]
  Tian W G, Gao X X, Zhang J M, Yu J, Zhang J. Cellulose nanosphere: Preparation and applications of the novel nanocellulose[J]. Carbohydr. Polym., 2022,277118863. doi: 10.1016/j.carbpol.2021.118863
21. [21]
  Miyashiro D, Hamano R, Umemura K. A review of applications using mixed materials of cellulose, nanocellulose and carbon nanotubes[J]. Nanomaterials, 2020,10(2)186. doi: 10.3390/nano10020186
22. [22]
  Dutta S, Kim J, Ide Y, Kim J H, Hossain M S A, Bando Y, Yamauchi Y, Wu K C W. 3D network of cellulose-based energy storage devices and related emerging applications[J]. Mater. Horiz., 2017,4(4):522-545. doi: 10.1039/C6MH00500D
23. [23]
  Ummartyotin S, Manuspiya H. An overview of feasibilities and challenge of conductive cellulose for rechargeable lithium based battery[J]. Renew. Sust. Energ. Rev., 2015,50:204-213. doi: 10.1016/j.rser.2015.05.014
24. [24]
  Klemm D, Kramer F, Moritz S, Lindstrom T, Ankerfors M, Gray D, Dorris A. Nanocelluloses: a new family of nature-based materials[J]. Angew. Chem. Int. Ed., 2011,50(24):5438-5466. doi: 10.1002/anie.201001273
25. [25]
  Du X, Zhang Z, Liu W, Deng Y L. Nanocellulose-based conductive materials and their emerging applications in energy devices—A review[J]. Nano Energy, 2017,35:299-320. doi: 10.1016/j.nanoen.2017.04.001
26. [26]
  Chen W S, Yu H P, Lee S Y, Wei T, Li J, Fan Z J. Nanocellulose: A promising nanomaterial for advanced electrochemical energy storage[J]. Chem. Soc. Rev., 2018,47(8):2837-2872.
27. [27]
  Habibi Y. Key advances in the chemical modification of nanocelluloses[J]. Chem. Soc. Rev., 2014,43(5):1519-1542.
28. [28]
  Fan S, Wei L, Liu X J, Ma W H, Lou C H, Wang J K, Zhang Y. High-density oxygen-enriched graphene hydrogels for symmetric supercapacitors with ultrahigh gravimetric and volumetric performance[J]. Int. J. Hydrog. Energy, 2021,46(80):39969-39982. doi: 10.1016/j.ijhydene.2021.09.227
29. [29]
  Luzi F, Puglia D, Sarasini F, Tirillo J, Maffei G, Zuorro A, Lavecchia R, Kenny J M, Torre L. Valorization and extraction of cellulose nanocrystals from North African grass: Ampelodesmos mauritanicus (Diss)[J]. Cabohydr. Polym., 2019,209:328-337.
30. [30]
  Kasiri N, Fathi M. Production of cellulose nanocrystals from pistachio shells and their application for stabilizing Pickering emulsions[J]. Int. J. Biol. Macromol., 2018,106:1023-1031.
31. [31]
  Xu Y X, Sheng K X, Li C, Shi G Q. Self-assembled graphene hydrogel via a one-step hydrothermal process[J]. ACS Nano, 2010,4:4324-4330.
32. [32]
  Xue B C, Wang X F, Feng Y, Chen Z M, Liu X Y. Self-template synthesis of nitrogen-doped porous carbon derived from rice husks for the fabrication of high volumetric performance supercapacitors[J]. J. Energy Storage, 2020,30101405.
33. [33]
  Chao Y Z, Chen S B, Chen H Q, Hu X J, Ma Y, Gao W S, Bai Y X. Densely packed porous graphene film for high volumetric performance supercapacitor[J]. Electrochim. Acta, 2018,276:118-124.
34. [34]
  Ma H Y, Zhou Q Q, Wu M M, Zhang M, Yao B W, Gao T T, Wang H Y, Li C, Sui D, Chen Y S, Shi G Q. Tailoring the oxygenated groups of graphene hydrogels for high-performance supercapacitors with large areal mass loadings[J]. J. Mater. Chem. A, 2018,6(15):6587-6594.
35. [35]
  Zhou Q Q, Wu M M, Zhang M, Xu G C, Yao B W, Li C, Shi G Q. Graphene-based electrochemical capacitors with integrated high performance[J]. Mater. Today Energy, 2017,6:181-188.
36. [36]
  Chen S B, Gao W S, Chao Y Z, Ma Y, Zhang Y H, Ren N, Chen H Q, Jin L J, Li J G, Bai Y X. Low temperature preparation of pore structure controllable graphene for high volumetric performance supercapacitors[J]. Electrochim. Acta, 2018,273:181-190.
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