Citation: Yu-Ao DONG, Zhe FENG, Dun-Ru ZHU. Syntheses of two Mg-based metal-organic frameworks by a coordination competitive strategy and the selective CO₂ capture[J]. Chinese Journal of Inorganic Chemistry, ;2023, 39(1): 181-190. doi: 10.11862/CJIC.2022.278 shu

Syntheses of two Mg-based metal-organic frameworks by a coordination competitive strategy and the selective CO₂ capture

Yu-Ao DONG ¹ ,
Zhe FENG ¹ ,
Dun-Ru ZHU ^{1, 2,,}

1.
College of Chemical Engineering, State Key Laboratory of Materials-Oriented Chemical Engineering, Nanjing Tech University, Nanjing 211816, China
2.
State Key Laboratory of Coordination Chemistry, Nanjing University, Nanjing 210023, China

Corresponding author: Dun-Ru ZHU, zhudr@njtech.edu.cn
Received Date: 20 August 2022
Revised Date: 6 October 2022

Figures(5)

Two Mg-based metal-organic frameworks (MOFs) were prepared using a coordination competition strategy. Under acidic conditions, the reaction of Mg(Ⅱ) ions with formic acid generated from the thermal decomposition of N, N-dimethylformamide (DMF) formed a 3D formate Mg-MOF: [Mg₃(HCO₂)6]·DMF (1). However, under the same conditions but with a competing ligand 1,1'∶3',1″-terphenyl-3,3″,5, 5″-tetracarboxylic acid (H₄L), formic acid was no longer involved in the coordination, resulting in a new 3D Mg-MOF: [Mg₂(L) (H₂O)₃]·2H₂O·2CH₃CN·DMF (2). Single-crystal X-ray analysis revealed that 1 possesses [Mg₄@Mg2] tetrahedral building units that form a dia topological network with a 1D channel size of 0.44 nm. In contrast, 2 has a unique [Mg₂] binuclear cluster to build a sra topology network after bridging the 4-connected L^4- linker. Interestingly, a dumbbell-shaped pore with a length of 1.42 nm is observed along the a-axis in 2. Gas adsorption studies reveal that 1 had a significantly accessible inner surface with a surface area of 342 m²·g^-1. However, after solvent removal, 2 could not retain the original porous character. Featuring good water stability, 1 exhibited a type-Ⅰ CO₂ adsorption isotherm with quick uptake at low pressure, and up to 14.5% of the sample weight at 298 K and 2 000 kPa. Ideal adsorption solution theory (IAST) and adsorption heat calculations show that 1 has a good ability for selective CO₂ capture from CH₄ contained mixture.
- competitive coordination,
- Mg-based metal-organic frameworks,
- crystal structure,
- selective CO₂ capture
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沈阳化工大学材料科学与工程学院沈阳 110142

Syntheses of two Mg-based metal-organic frameworks by a coordination competitive strategy and the selective CO2 capture

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通讯作者: 陈斌, bchen63@163.com

Syntheses of two Mg-based metal-organic frameworks by a coordination competitive strategy and the selective CO₂ capture