Citation: Shuai LAN, Yu ZHANG, Jie REN, Si-Bo SHEN, Lei CAO, Dan-Dan JIA, Dong-Jun WANG. Ternary lanthanide complexes of 3-((4, 6-dimethyl-2-pyrimidinyl)thio)-propanoic acid and 1, 10-phenanthroline: Crystal structure and photoluminescent property[J]. Chinese Journal of Inorganic Chemistry, ;2023, 39(1): 135-140. doi: 10.11862/CJIC.2022.276 shu

Ternary lanthanide complexes of 3-((4, 6-dimethyl-2-pyrimidinyl)thio)-propanoic acid and 1, 10-phenanthroline: Crystal structure and photoluminescent property

Shuai LAN ^1,, ,
Yu ZHANG ¹ ,
Jie REN ¹ ,
Si-Bo SHEN ¹ ,
Lei CAO ¹ ,
Dan-Dan JIA ¹ ,
Dong-Jun WANG ²

1.
School of Chemical Engineering, Hebei Normal University of Science and Technology, Qinhuangdao, Hebei 066000, China
2.
Analysis and Measurement Center, Hebei Normal University of Science and Technology, Qinhuangdao, Hebei 066000, China

Corresponding author: Shuai LAN, lanshuai2000@126.com
Received Date: 6 January 2022
Revised Date: 26 October 2022

Figures(3)

Two ternary lanthanide complexes, [Eu(L)₃(Phen)]₂·2H₂O (1) and [Tb(L)₃(Phen)]₂·2H₂O (2), based on 3-((4, 6-dimethyl-2-pyrimidinyl)thio)-propanoic acid (HL) and 1, 10-phenanthroline (Phen) were prepared and structurally characterized. Single-crystal X-ray diffraction analyses reveal that they are isostructural. Two lanthanide ions (Ln) are bridged by four carboxylate ligands. The rest two carboxylate ligands and Phen coordinate with Ln with bidentate chelating mode, forming the dimeric arrangement. The coordination number of Ln is nine with a distorted mono-capped square antiprismatic coordination polyhedron. The solid-state photoluminescent measurements suggest that both complexes showcase the characteristic emission bands of the metal center.
- 1, 10-phenanthroline,
- 3-((4, 6-dimethyl-2-pyrimidinyl)thio)-propanoic acid,
- lanthanide complex,
- crystal structure,
- photoluminescent
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