Citation: Wei-Wei JIANG, Jun-Jie LI, Cheng-Zhou YE, Jing ZHANG, Long HUANG, Xi WU, Zhen-Min HU, Wen-Ji LI, Yu DAI, Fu-Gen SUN. Lightweight 3D porous Al foams for the hosts of high-performance Li metal anodes[J]. Chinese Journal of Inorganic Chemistry, ;2023, 39(2): 291-299. doi: 10.11862/CJIC.2022.266 shu

Lightweight 3D porous Al foams for the hosts of high-performance Li metal anodes

School of Physics and Materials Science, Nanchang University, Nanchang 330031, China

Corresponding author: Fu-Gen SUN, sunfugen@ncu.edu.cn
Received Date: 27 July 2022
Revised Date: 4 November 2022

Figures(6)

Lightweight, 3D porous, and lithiophilic Al foams has been used as the hosts for Li metal anodes, and compounded with metallic Li by a facile mechanical extrusion method to obtain the Al@Li composite anodes. The high lithiophilicity of Al foams could provide abundant and uniform active sites for Li nucleation, thus inducing the fast nucleation and uniform electro-deposition of Li metal into the Al foams. Moreover, the 3D porous structures of Al foams could accommodate the huge volume change of Li metal anodes during the charge/discharge process and reduce the local current density, thus effectively inhibiting the growth of Li dendrites. Therefore, compared with the bare Li metal anodes, the obtained Al@Li composite anodes exhibited higher cycling stability of Li plating/stripping with a lower overpotential of ca. 5 mV at 1 mA·cm^-2 after 250 cycles in their symmetric cells. Furthermore, half-cell configurations with the Al@Li composite anodes and LiFePO₄ cathodes also presented significantly enhanced cycling capacity and rate performance.
- Li secondary batteries,
- Li metal anodes,
- Al foams,
- Li dendrites
1. [1]
  Liu D H, Bai Z Y, Li M, Yu A P, Luo D, Liu W W, Yang L, Lu J, Amine K, Chen Z W. Developing high safety Li - metal anodes for future high - energy Li - metal batteries: Strategies and perspectives[J]. Chem. Soc. Rev., 2020,49(15):5407-5445. doi: 10.1039/C9CS00636B
2. [2]
  Chu H, Noh H, Kim Y J, Yuk S, Lee J H, Lee J, Kwack H, Kim Y, Yang D K, Kim H T. Achieving three - dimensional lithium sulfide growth in lithium - sulfur batteries using high - donor - number anions[J]. Nat. Commun., 2019,10188. doi: 10.1038/s41467-018-07975-4
3. [3]
  Huang L, Shen S H, Zhong Y, Zhang Y Q, Zhang L J, Wang X L, Xia X H, Tong X L, Zhou J C, Tu J P. Multifunctional hyphae carbon powering lithium-sulfur batteries[J]. Adv. Mater., 2022,34(6)2107415. doi: 10.1002/adma.202107415
4. [4]
  Wang C H, Li Y H, Cao F, Zhang Y Q, Xia X H, Zhang L J. Employing Ni - embedded porous graphitic carbon fibers for high - efficiency lithium - sulfur batteries[J]. ACS Appl. Mater. Interfaces, 2022,14(8):10457-10466. doi: 10.1021/acsami.1c24755
5. [5]
  Pu K C, Zhang X, Qu X L, Hu J J, Li H W, Gao M X, Pan H G, Liu Y F. Recently developed strategies to restrain dendrite growth of Li metal anodes for rechargeable batteries[J]. Rare Met., 2020,39:616-635. doi: 10.1007/s12598-020-01432-2
6. [6]
  Liu H D, Yue X J, Xing X, Yan Q Z, Huang J, Petrova V, Zhou H, Liu P. A scalable 3D lithium metal anode[J]. Energy Storage Mater., 2019,16:505-511. doi: 10.1016/j.ensm.2018.09.021
7. [7]
  Luo N, Ji G J, Wang H F, Li F, Liu Q C, Xu J J. Process for a free-standing and stable all - metal structure for symmetrical lithium-oxygen batteries[J]. ACS Nano, 2020,14:3281-3289. doi: 10.1021/acsnano.9b08844
8. [8]
  Shan X Y, Zhong Y, Zhang L J, Zhang Y Q, Xia X H, Wang X L, Tu J P. A brief review on solid electrolyte interphase composition characterization technology for lithium metal batteries: Challenges and perspectives[J]. J. Phys. Chem. C, 2021,125:19060-19080. doi: 10.1021/acs.jpcc.1c06277
9. [9]
  Lee Y G, Fujiki S, Jung C, Suzuki N, Yashiro N, Omoda R, Ko D S, Shiratsuchi T, Sugimoto T, Ryu S, Ku J H, Watanabe T, Park Y, Aihara Y, Im D, Han I T. High- energy long-cycling all-solid-state lithium metal batteries enabled by silver-carbon composite anodes[J]. Nat. Energy, 2020,5:299-308. doi: 10.1038/s41560-020-0575-z
10. [10]
  Guo Y P, Wang R Y, Cui C, Xiong R D, Wei Y Q, Zhai T Y, Li H Q. Shaping Li deposits from wild dendrites to regular crystals via the ferroelectric effect[J]. Nano Lett., 2020,20:7680-7687. doi: 10.1021/acs.nanolett.0c03206
11. [11]
  Xu N, Li L L, He Y, Tong Y, Lu Y Y. Understanding the molecular mechanism of lithium deposition for practical high - energy lithium-metal batteries[J]. J. Mater. Chem. A, 2020,8:6229-6237. doi: 10.1039/D0TA01044H
12. [12]
  Ouyang Y, Guo Y P, Li D, Wei Y Q, Zhai T Y, Li H Q. Single additive with dual functional - ions for stabilizing lithium anodes[J]. ACS Appl. Mater. Interfaces, 2019,11:11360-11368. doi: 10.1021/acsami.8b21420
13. [13]
  Zhuang H F, Zhao P, Xu Y. Superlithiophilic graphene-silver enabling ultra - stable hosts for lithium metal anodes[J]. Inorg. Chem. Front., 2020,7:897-904.
14. [14]
  Hou Z, Yu Y K, Wang W H, Zhao X X, Di Q, Chen Q W, Chen W, Liu Y L, Quan Z W. Lithiophilic Ag nanoparticle layer on Cu current collector toward stable Li metal anode[J]. ACS Appl. Mater. Interfaces, 2019,11:8148-8154. doi: 10.1021/acsami.9b01521
15. [15]
  Cui S Q, Zhai P B, Yang W W, Wei Y, Xiao J, Deng L B, Gong Y J. Large - scale modification of commercial copper foil with lithiophilic metal layer for Li metal battery[J]. Small, 2020,16(5)1905620. doi: 10.1002/smll.201905620
16. [16]
  Wang X S, Pan Z H, Wu Y, Ding X Y, Hong X J, Xu G G, Liu M N, Zhang Y G, Li W S. Infiltrating lithium into carbon cloth decorated with zinc oxide arrays for dendrite - free lithium metal anode[J]. Nano Res., 2019,12:525-529. doi: 10.1007/s12274-018-2245-z
17. [17]
  Pei F, Fu A, Ye W B, Peng J, Fang X L, Wang M S, Zheng N F. Robust lithium metal anodes realized by lithiophilic 3D porous current collectors for constructing high-energy lithium-sulfur batteries[J]. ACS Nano, 2019,13:8337-8346. doi: 10.1021/acsnano.9b03784
18. [18]
  Zhang H, Eshetu G G, Judez X, Li C, Rodrguez-Martnez L M, Armand M. Electrolyte additives for lithium metal anodes and rechargeable lithium metal batteries: progresses and perspectives[J]. Angew. Chem. Int. Ed., 2018,57(46):15002-15027. doi: 10.1002/anie.201712702
19. [19]
  Ren X D, Zhang Y H, Engelhard M H, Li Q Y, Zhang J G, Xu W. Guided lithium metal deposition and improved lithium coulombic efficiency through synergistic effects of LiAsF₆ and cyclic carbonate additives[J]. ACS Energy Lett., 2018,3:14-19. doi: 10.1021/acsenergylett.7b00982
20. [20]
  Ma Y L, Zhou Z X, Li C J, Wang L, Cheng X Q, Zuo P J, Du C Y, Huo H, Gao Y Z, Yin G P. Enabling reliable lithium metal batteries by a bifunctional anionic electrolyte additive[J]. Energy Storage Mater., 2018,11:197-204. doi: 10.1016/j.ensm.2017.10.015
21. [21]
  Xu K. Electrolytes and interphases in Li - ion batteries and beyond[J]. Chem. Rev., 2014,114(23):11503-11618. doi: 10.1021/cr500003w
22. [22]
  Jiang G Y, Li K Y, Yu F, Li X L, Mao J Y, Jiang W W, Sun F G, Dai B, Li Y S. Robust artificial solid - electrolyte interfaces with biomimetic ionic channels for dendrite-free Li metal anodes[J]. Adv. Energy Mater., 2020,11(6)2003496.
23. [23]
  Zuo Z F, Zhuang L B, Xu J Z, Shi Y M, Su C L, Lian P C, Tian B B. Lithiophilic silver coating on lithium metal surface for inhibiting lithium dendrites[J]. Front. Chem., 2020,8109. doi: 10.3389/fchem.2020.00109
24. [24]
  Kim J Y, Liu G C, Tran M X, Ardhi R E A, Kim H, Lee J K. Synthesis and characterization of a hierarchically structured three-dimensional conducting scaffold for highly stable Li metal anodes[J]. J. Mater. Chem. A, 2019,7:12882-12892. doi: 10.1039/C9TA03062J
25. [25]
  Yu J, Dang Y Y, Bai M H, Peng J X, Zheng D D, Zhao J K, Li L B, Fang Z. Graphene - modified 3D copper foam current collector for dendrite-free lithium deposition[J]. Front. Chem., 2019,7748. doi: 10.3389/fchem.2019.00748
26. [26]
  Wu L L, Jiang W W, Zou H T, Ye C Z, Zhang J, Xu G J, Li X M, Yue Z H, Sun F G, Zhou L. Natural forest - inspired Ag lithiophilic porous arrays grown in Cu foam hosts with bi-continuous electronic/ionic pathways for highly stable Li metal anodes[J]. J. Mater. Chem. A, 2021,9:20748-20757. doi: 10.1039/D1TA04927E
27. [27]
  Chi S S, Liu Y C, Song W L, Fan L Z, Zhang Q. Prestoring lithium into stable 3D nickel foam host as dendrite-free lithium metal anode[J]. Adv. Funct. Mater., 2017,27(24)1700348. doi: 10.1002/adfm.201700348
28. [28]
  Wang T S, Zhai P B, Legut D, Wang L, Liu X P, Li B X, Dong C X, Fan Y C, Gong Y J, Zhang Q F. S -doped graphene -regional nucleation mechanism for dendrite-free lithium metal anodes[J]. Adv. Energy Mater., 2019,9(24)1804000. doi: 10.1002/aenm.201804000
29. [29]
  Wang Z Y, Lu Z X, Guo W, Luo Q, Yin Y H, Liu X B, Li Y S, Xia B Y, Wu Z P. A dendrite-free lithium/carbon nanotube hybrid for lithium-metal batteries[J]. Adv. Mater., 2021,33(4)2006702. doi: 10.1002/adma.202006702
30. [30]
  Jiang G Y, Jiang N, Zheng N, Chen X, Mao J Y, Ding G Y, Li Y H, Sun F G, Li Y S. MOF-derived porous Co₃O₄-NC nanoflake arrays on carbon fiber cloth as stable hosts for dendrite-free Li metal anodes[J]. Energy Storage Mater., 2019,23:181-189. doi: 10.1016/j.ensm.2019.05.014
31. [31]
  Lu R C, Zhang B B, Cheng Y L, Amin K, Yang C, Zhou Q Y, Mao L J, Wei Z X. Dual -regulation of ions/electrons in a 3D Cu-Cu_xO host to guide uniform lithium growth for high-performance lithium metal anodes[J]. J. Mater. Chem. A, 2021,9:10393-10403. doi: 10.1039/D1TA01150B
32. [32]
  Jiang Y P, Wang B, Liu A M, Song R S, Bao C Y, Ning Y, Wang F, Ruan T T, Wang D L, Zhou Y. In situ growth of CuO submicro - sheets on optimized Cu foam to induce uniform Li deposition and stripping for stable Li metal batteries[J]. Electrochim. Acta, 2020,339135941. doi: 10.1016/j.electacta.2020.135941
33. [33]
  Jiang H, Dong Q Y, Bai M H, Qin F R, Yi M Y, Lai J Q, Hong B, Lai Y Q. A 3D-mixed ion/electron conducting scaffold prepared by in situ conversion for long-life lithium metal anodes[J]. Nanoscale, 2021,13(5):3144-3152. doi: 10.1039/D0NR06539K
34. [34]
  Cheng H, Gao C, Cai N, Wang M. Ag coated 3D-Cu foam as a lithiophilic current collector for enabling Li₂S-based anode-free batteries[J]. Chem. Commun., 2021,57:3708-3711. doi: 10.1039/D1CC00006C
35. [35]
  Hao C, Jin H, Liu H Y, Cai N, Gao C, Zhang P, Wang M. An interconnected silver coated carbon cloth framework as a host to reduce lithium nucleation over - potential for dendrite - free lithium metal anodes[J]. J. Electroanal. Chem., 2020,878114569. doi: 10.1016/j.jelechem.2020.114569
36. [36]
  Zhang H Y, Ju S L, Xia G L, Sun D L, Yu X B. Dendrite-free Li-metal anode enabled by dendritic structure[J]. Adv. Funct. Mater., 2021,31(16)2009712. doi: 10.1002/adfm.202009712
37. [37]
  Zhong H, Wu Y X, Ding F, Sang L, Mai Y H. An artificial Li - Al interphase layer on Li-B alloy for stable lithium-metal anode[J]. Electrochim. Acta, 2019,304:255-262. doi: 10.1016/j.electacta.2019.03.009
38. [38]
  Zhong H, Sang L, Ding F, Song J X, Mai Y H. Conformation of lithium - aluminium alloy interphase - layer on lithium metal anode used for solid state batteries[J]. Electrochim. Acta, 2018,277:268-275. doi: 10.1016/j.electacta.2018.04.191
39. [39]
  Fan L, Li S Y, Liu L, Zhang W D, Gao L N, Fu Y, Chen F, Li J, Zhuang H L, Lu Y Y. Enabling stable lithium metal anode via 3D inorganic skeleton with superlithiophilic interphase[J]. Adv. Energy Mater., 2018,8(33)1802350. doi: 10.1002/aenm.201802350
40. [40]
  Zhang R, Chen X, Shen X, Zhang X Q, Chen X R, Cheng X B, Yan C, Zhao C Z, Zhang Q. Coralloid carbon fiber-based composite lithium anode for robust lithium metal batteries[J]. Joule, 2018,2(4):764-777. doi: 10.1016/j.joule.2018.02.001
41. [41]
  WU L L, JIANG W W, DING G Y, LI Y H, ZHU Z, JING X G, YAN F Q, XU G J, YUE Z H, LI X M, SUN F G, ZHOU L. In -situ con-struction of Cu₃P nanoflake array@Cu foam 3D frameworks for high performance Li - metal anodes[J]. Chinese J. Inorg. Chem., 2021,37(4):709-716.
1. [1]
  Zhiyuan TONG , Ziyuan LI , Ke ZHANG . Three-dimensional porous collector based on Cu-Li_6.4La₃Zr_1.4Ta_0.6O₁₂ composite layer for the construction of stable lithium metal anode. Chinese Journal of Inorganic Chemistry, 2025, 41(3): 499-508. doi: 10.11862/CJIC.20240238
2. [2]
  .
  南开大学师唯/华北电力大学（保定）刘景维：二维配位聚合物中有序的亲锂冠醚位点用于无枝晶锂沉积
  . CCS Chemistry, 2025, 7(0): -.
3. [3]
  Xueyu Lin , Ruiqi Wang , Wujie Dong , Fuqiang Huang . 高性能双金属氧化物负极的理性设计及储锂特性. Acta Physico-Chimica Sinica, 2025, 41(3): 2311005-. doi: 10.3866/PKU.WHXB202311005
4. [4]
  Ping ZHANG , Chenchen ZHAO , Xiaoyun CUI , Bing XIE , Yihan LIU , Haiyu LIN , Jiale ZHANG , Yu'nan CHEN . Preparation and adsorption-photocatalytic performance of ZnAl@layered double oxides. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1965-1974. doi: 10.11862/CJIC.20240014
5. [5]
  Junke LIU , Kungui ZHENG , Wenjing SUN , Gaoyang BAI , Guodong BAI , Zuwei YIN , Yao ZHOU , Juntao LI . Preparation of modified high-nickel layered cathode with LiAlO₂/cyclopolyacrylonitrile dual-functional coating. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1461-1473. doi: 10.11862/CJIC.20240189
6. [6]
  Xuejie Gao , Xinyang Chen , Ming Jiang , Hanyan Wu , Wenfeng Ren , Xiaofei Yang , Runcang Sun . Long-lifespan thin Li anode achieved by dead Li rejuvenation and Li dendrite suppression for all-solid-state lithium batteries. Chinese Chemical Letters, 2024, 35(10): 109448-. doi: 10.1016/j.cclet.2023.109448
7. [7]
  Yongjian Li , Xinyu Zhu , Chenxi Wei , Youyou Fang , Xinyu Wang , Yizhi Zhai , Wenlong Kang , Lai Chen , Duanyun Cao , Meng Wang , Yun Lu , Qing Huang , Yuefeng Su , Hong Yuan , Ning Li , Feng Wu . Unraveling the chemical and structural evolution of novel Li-rich layered/rocksalt intergrown cathode for Li-ion batteries. Chinese Chemical Letters, 2024, 35(12): 109536-. doi: 10.1016/j.cclet.2024.109536
8. [8]
  Tianyi Hou , Yunhui Huang , Henghui Xu . Interfacial engineering for advanced solid-state Li-metal batteries. Chinese Journal of Structural Chemistry, 2024, 43(7): 100313-100313. doi: 10.1016/j.cjsc.2024.100313
9. [9]
  Zihao Wang , Jing Xue , Zhicui Song , Jianxiong Xing , Aijun Zhou , Jianmin Ma , Jingze Li . Li-Zn alloy patch for defect-free polymer interface film enables excellent protection effect towards stable Li metal anode. Chinese Chemical Letters, 2024, 35(10): 109489-. doi: 10.1016/j.cclet.2024.109489
10. [10]
  Yu Guo , Zhiwei Huang , Yuqing Hu , Junzhe Li , Jie Xu . 钠离子电池中铁基异质结构负极材料的最新研究进展. Acta Physico-Chimica Sinica, 2025, 41(3): 2311015-. doi: 10.3866/PKU.WHXB202311015
11. [11]
  Kunyao Peng , Xianbin Wang , Xingbin Yan . Converting LiNO₃ additive to single nitrogenous component Li₂N₂O₂ SEI layer on Li metal anode in carbonate-based electrolyte. Chinese Chemical Letters, 2024, 35(9): 109274-. doi: 10.1016/j.cclet.2023.109274
12. [12]
  Xi Tang , Chunlei Zhu , Yulu Yang , Shihan Qi , Mengqiu Cai , Abdullah N. Alodhayb , Jianmin Ma . Additive regulating Li⁺ solvation structure to construct dual LiF−rich electrode electrolyte interphases for sustaining 4.6 V Li||LiCoO₂ batteries. Chinese Chemical Letters, 2024, 35(12): 110014-. doi: 10.1016/j.cclet.2024.110014
13. [13]
  Yue Wang , Caixia Xu , Xingtao Tian , Siyu Wang , Yan Zhao . Challenges and Modification Strategies of High-Voltage Cathode Materials for Li-ion Batteries. Chinese Journal of Structural Chemistry, 2023, 42(10): 100167-100167. doi: 10.1016/j.cjsc.2023.100167
14. [14]
  Zizhuo Liang , Fuming Du , Ning Zhao , Xiangxin Guo . Revealing the reason for the unsuccessful fabrication of Li3Zr2Si2PO12 by solid state reaction. Chinese Journal of Structural Chemistry, 2023, 42(11): 100108-100108. doi: 10.1016/j.cjsc.2023.100108
15. [15]
  Qingyan JIANG , Yanyong SHA , Chen CHEN , Xiaojuan CHEN , Wenlong LIU , Hao HUANG , Hongjiang LIU , Qi LIU . Constructing a one-dimensional Cu-coordination polymer-based cathode material for Li-ion batteries. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 657-668. doi: 10.11862/CJIC.20240004
16. [16]
  Zhenqiang Guo , Huicong Yang , Qian Wei , Shengjun Xu , Guangjian Hu , Shuo Bai , Feng Li . Dual-additives enable stable electrode-electrolyte interfaces for long life Li-SPAN batteries. Chinese Chemical Letters, 2024, 35(5): 108622-. doi: 10.1016/j.cclet.2023.108622
17. [17]
  Peng Jia , Yunna Guo , Dongliang Chen , Xuedong Zhang , Jingming Yao , Jianguo Lu , Liqiang Zhang . In-situ imaging electrocatalysis in a solid-state Li-O₂ battery with CuSe nanosheets as air cathode. Chinese Chemical Letters, 2024, 35(5): 108624-. doi: 10.1016/j.cclet.2023.108624
18. [18]
  Yu ZHANG , Fangfang ZHAO , Cong PAN , Peng WANG , Liangming WEI . Application of double-side modified separator with hollow carbon material in high-performance Li-S battery. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1218-1232. doi: 10.11862/CJIC.20230412
19. [19]
  Long Li , Kang Yang , Chenpeng Xi , Mengchao Li , Borong Li , Gui Xu , Yuanbin Xiao , Xiancai Cui , Zhiliang Liu , Lingyun Li , Yan Yu , Chengkai Yang . Highly-chlorinated inert and robust interphase without mineralization of oxide enhancing high-rate Li metal batteries. Chinese Chemical Letters, 2024, 35(6): 108814-. doi: 10.1016/j.cclet.2023.108814
20. [20]
  Cuiwu MO , Gangmin ZHANG , Chao WU , Zhipeng HUANG , Chi ZHANG . A(NH₂SO₃) (A=Li, Na): Two ultraviolet transparent sulfamates exhibiting second harmonic generation response. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1387-1396. doi: 10.11862/CJIC.20240045

Get Citation

PDF

XML

Metrics

PDF Downloads(10)
Abstract views(979)
HTML views(117)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Lightweight 3D porous Al foams for the hosts of high-performance Li metal anodes

南开大学师唯/华北电力大学（保定）刘景维：二维配位聚合物中有序的亲锂冠醚位点用于无枝晶锂沉积

Metrics

通讯作者: 陈斌, bchen63@163.com