Citation: Qing-Tang ZHANG, Zong-Qiang XU, Qi-Qi SHU, Fei LIAN. Preparation and lithium storage properties of nitrogen, sulfur heteroatom hard carbon by pyrolysis of conjugated microporous polymers[J]. Chinese Journal of Inorganic Chemistry, ;2023, 39(1): 45-54. doi: 10.11862/CJIC.2022.263 shu

Preparation and lithium storage properties of nitrogen, sulfur heteroatom hard carbon by pyrolysis of conjugated microporous polymers

School of Petrochemical Engineering, Lanzhou University of Technology, Lanzhou 730050, China

Corresponding author: Qing-Tang ZHANG, zhqt137@163.com Zong-Qiang XU, 1967685817@qq.com
Received Date: 30 May 2022
Revised Date: 6 October 2022

Figures(9)

A bottom-up approach was employed to build a thiazole-containing conjugated microporous polymer (NSCMP) by choosing bromo-thiazole and triacetylene benzene as monomers. The pyrolyzation and KOH-assisted pyrolyzation of NSCMP were performed to obtain the N, S heteroatom hard carbon (NSHC) and KOH-activated NSHC (KNSHC). NSHC and KNSHC were further characterized by scanning electronic microscope, energy-dispersive spectra (EDS), nitrogen adsorption-desorption, galvanostatic charge-discharging test, etc. The EDS revealed that the N and S mass fractions of KNSHC were 10.42% and 2.23%, respectively. The specific surface area of KNSHC was as high as 2 140 m²·g^-1, which was distinctly higher than that of NSHC (657 m²·g^-1). The specific capacity of KNSHC after 500 cycles at 0.2 A·g^-1 was as high as 946.2 mAh·g^-1, while that of NSHC was only 493.7 mAh·g^-1. The excellent electrochemical performance of KNSHC may be due to the synergistic effect of N and S heteroatoms as well as the unique porous structure.
- conjugated microporous polymer,
- hard carbon,
- anode material,
- lithium ion battery
1. [1]
  Rajkamal A, Thapa R. Carbon allotropes as anode material for lithiumion batteries[J]. Adv. Mater. Technol., 2019,4(10)1900307. doi: 10.1002/admt.201900307
2. [2]
  Hasani A H, Mansor M, Kumaran V, Zuhdi A W M, Ying Y J, Hannan M A, Hamid F A, Rahman M S A, Salim N A. Thermal behavior of lithium-ion battery in microgrid application: Impact and management system[J]. Int. J. Energy Res., 2020,45(4):4967-5005.
3. [3]
  Roy P, Srivastava S K. Nanostructured anode materials for lithium ion batteries[J]. J. Mater. Chem. A, 2015,3(6):2454-2484. doi: 10.1039/C4TA04980B
4. [4]
  WANG J J, ZHANG J, WANG J Y, WANG L, LI X K. Effect of heat treatment on structure and lithium ion storage of N-rich carbon nanofibers[J]. Chinese J. Inorg. Chem., 2020,36(1):31-39.
5. [5]
  Yuan Y, Chen Z W, Yu H X, Zhang X K, Liu T T, Xia M T, Zheng R T, Shui M, Shu J. Heteroatom-doped carbon-based materials for lithium and sodium ion batteries[J]. Energy Storage Mater., 2020,32:65-90. doi: 10.1016/j.ensm.2020.07.027
6. [6]
  Zhang Q T, Dai Q Q, Yan C, Su C, Li A. Nitrogen-doped porous carbon nanoparticle derived from nitrogen containing conjugated microporous polymer as high performance lithium battery anode[J]. J. Alloy. Compd., 2017,714:204-212. doi: 10.1016/j.jallcom.2017.04.207
7. [7]
  Orthner H, Wiggers H, Loewenich M, Kilian S, Bade S, Lyubina J. Direct gas phase synthesis of amorphous Si/C nanoparticles as anode material for lithium ion battery[J]. J. Alloy. Compd., 2021,870159315. doi: 10.1016/j.jallcom.2021.159315
8. [8]
  Fan P, Mu T S, Lou S F, Cheng X Q, Gao Y Z, Du C Y, Zuo P J, Ma Y L, Yin G P. Amorphous carbon-encapsulated Si nanoparticles loading on MCMB with sandwich structure for lithium ion batteries[J]. Electrochim. Acta, 2019,306:590-598. doi: 10.1016/j.electacta.2019.03.154
9. [9]
  Zhang Q T, Dai Q Q, Li M, Wang X M, Li A. Incorporation of MnO nanoparticles inside porous carbon nanotubes originated from conjugated microporous polymers for lithium storage[J]. J. Mater. Chem. A, 2016,4(48):19132-19139. doi: 10.1039/C6TA08464H
10. [10]
  Gan Q M, Wu B C, Qin N, Chen J L, Luo W, Xiao D J, Feng J, Liu W L, Zhu Y H, Zhang P S. Sandwich-like dual carbon layers coated NiO hollow spheres with superior lithium storage performances[J]. Electrochim. Acta, 2020,343(20)136121.
11. [11]
  Wan H R, Hu X F. Sulfur-doped honeycomb-like carbon with outstanding electrochemical performance as an anode material for lithium and sodium ion batteries[J]. J. Colloid Interface Sci., 2020,558:242-250. doi: 10.1016/j.jcis.2019.09.124
12. [12]
  Kou Y, Xu Y H, Guo Z Q, Jiang D L. Supercapacitive energy storage and electric power supply using an aza-fused π-conjugated microporous framework[J]. Angew. Chem. Int. Ed., 2011,50:8753-8757. doi: 10.1002/anie.201103493
13. [13]
  Wang Z J, Ghasimi S, Landfester K, Zhang K A I. Highly porous conjugated polymers for selective oxidation of organic sulfides under visible light[J]. Chem. Commun., 2014,50:8177-8180. doi: 10.1039/C4CC02861A
14. [14]
  Lu W G, Yuan D Q, Zhao D, Schilling C I, Plietzsch O, Muller T, Bräse S, Guenther J, Blümel J, Krishna R, Li Z, Zhou H C. Porous polymer networks: Synthesis, porosity, and applications in gas storage/separation[J]. Chem. Mater., 2010,22:5964-5972. doi: 10.1021/cm1021068
15. [15]
  Dawson R, Adams D, Cooper A. Chemical tuning of CO₂ sorption in robust nanoporous organic polymers[J]. Chem. Sci., 2011,2(6):1173-1177. doi: 10.1039/c1sc00100k
16. [16]
  Lindemann P, Tsotsalas M, Shishatskiy S, Abetz V, Krolla-Sidenstein P, Azucena C, Monnereau L, Beyer A, Gölzhäuser A, Mugnaini V. Preparation of freestanding conjugated microporous polymer nanomembranes for gas separation[J]. Chem. Mater., 2014,26:7189-7193. doi: 10.1021/cm503924h
17. [17]
  Li R Z, Huang J F, Li J Y, Cao L Y, Zhong X Z, Yu A M, Lu G X. Nitrogen-doped porous hard carbons derived from shaddock peel for high-capacity lithiumion battery anodes[J]. J. Electroanal. Chem., 2020,862114044. doi: 10.1016/j.jelechem.2020.114044
18. [18]
  Wang X, Weng Q H, Liu X Z, Wang X B, Tang D M, Tian W, Zhang C, Yi W, Liu D Q, Bando Y, Golberg D. Atomistic origins of high rate capability and capacity of N-doped graphene for lithium storage[J]. Nano Lett., 2014,14(3):1164-1171. doi: 10.1021/nl4038592
19. [19]
  Cai D D, Wang S Q, Lian P C, Zhu X F, Li D D, Yang W S, Wang H H. Superhigh capacity and rate capability of high-level nitrogen-doped graphene sheets as anode materials for lithium-ion batteries[J]. Electrochim. Acta, 2013,90(15):492-497.
20. [20]
  Yuan Q H, Ma Z W, Chen J B, Huang Z R, Fang Z M, Zhang P, Lin Z D, Cui J. N, S-codoped activated carbon material with ultra-high surface area for high-performance supercapacitors[J]. Polymers, 2020,12(9):1-14.
21. [21]
  Xin G X, Wang M M, Zhang W H, Song J L, Zhang B W. Preparation of high-capacitance N, S co-doped carbon nanospheres with hierarchical pores as supercapacitors[J]. Electrochim. Acta, 2018,291:168-176. doi: 10.1016/j.electacta.2018.08.137
22. [22]
  Li Y J, Wang G L, Wei T, Fan Z J, Yan P. Nitrogen and sulfur codoped porous carbon nanosheets derived from willow catkin for supercapacitors[J]. Nano Energy, 2016,19:165-175. doi: 10.1016/j.nanoen.2015.10.038
23. [23]
  Zhao X C, Zhang Q, Chen C M, Zhang B S, Reiche S, Wang A Q, Zhang T, Schlögl R, Su D S. Aromatic sulfide, sulfoxide, and sulfone mediated mesoporous carbon monolith for use in supercapacitor[J]. Nano Energy, 2012,1(4):624-630. doi: 10.1016/j.nanoen.2012.04.003
24. [24]
  Zhong S Y, Liu H Z, Wei D H, Hu J, Zhang H, Hou H S, Peng M X, Zhang G H, Duan H G. Long-aspect-ratio N-rich carbon nanotubes as anode material for sodium and lithium ion batteries[J]. Chem. Eng. J., 2020,395125054. doi: 10.1016/j.cej.2020.125054
25. [25]
  Zhang D M, Chen Z W, Bai J, Yang C C, Jiang Q. Highly nitrogen doped porous carbon nanosheets as high-performance anode for potassium-ion batteries[J]. Batteries Supercaps, 2020,3(2):185-193. doi: 10.1002/batt.201900144
26. [26]
  Zhou C L, Wang D K, Yang H, Li A, Song H H, Chen X H, Xing G J, Yang H J, Liu H Y. N, O co-doped urchin-like carbon microspheres as high-performance anode materials for lithium ion batteries[J]. Solid State Ionics, 2021,361115562.
27. [27]
  Chao D L, Zhu C R, Yang P H, Xia X H, Liu J L, Wang J, Fan X F, Savilov S, Lin J Y, Fan H J, Shen Z X. Array of nanosheets render ultrafast and high-capacity Na-ion storage by tunable pseudocapacitance[J]. Nat. Commun., 2016,712122. doi: 10.1038/ncomms12122
28. [28]
  CHEN X D, KE J N, YAN P, LIU J H, WANG Y W, ZHAN C C, JIANG X D. Core-shell nanosphere cobalt-based metal-organic polymer: Preparation and lithium storage performance[J]. Chinese J. Inorg. Chem., 2022,38(5):836-842.
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