Citation: Yan-Ling SONG, Qi-Yuan ZHANG, Ai-Hua YAO. Template-free electrodeposition and electrochromic performance of porous WO3·2H2O thin film[J]. Chinese Journal of Inorganic Chemistry, ;2023, 39(1): 127-134. doi: 10.11862/CJIC.2022.260 shu

Template-free electrodeposition and electrochromic performance of porous WO3·2H2O thin film

  • Corresponding author: Ai-Hua YAO, 07182@tongji.edu.cn
  • Received Date: 3 August 2022
    Revised Date: 4 November 2022

Figures(6)

  • Compared with anhydrous WO3, tungsten oxide dihydrate (WO3·2H2O) shows superior electrochromic properties because of its unique layered structure and rich interlayer structural water. In this study, WO3·2H2O films were successfully fabricated on indium tin oxide (ITO) glass substrates using a facile, template-free cathodic electrodeposition method. The composition of the electrodeposition solution was optimized by modifying the volume of hydrogen peroxide (H2O2) added into the solution, and thus highly porous films were obtained. The thus deposited WO3·2H2O films exhibited excellent electrochromic performance, including significant optical contrast of over 90% at 633 nm, a fast switching speed of fewer than 10 s, and a long cycling lifetime (90% original optical modulation was retained after 10 000 cycles).
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    1. [1]

      Huang Y, Wang B S, Chen F X, Han Y, Zhang W S, Wu X K, Li R, Jiang Q Y, Jia X L, Zhang R F. Electrochromic materials based on ions insertion and extraction[J]. Adv. Opt. Mater., 2022,102101783. doi: 10.1002/adom.202101783

    2. [2]

      Pan J B, Zheng R Z, Wang Y, Ye X K, Wan Z Q, Jia C Y, Weng X L, Xie J L, Deng L J. A high-performance electrochromic device assembled with hexagonal WO3 and NiO/PB composite nanosheet electrodes towards energy storage smart window[J]. Sol. Energy Mater. Sol. Cells, 2020,207110337. doi: 10.1016/j.solmat.2019.110337

    3. [3]

      Granqvist C G. Electrochromics for smart windows: Oxide-based thin films and devices[J]. Thin Solid Films, 2014,564:1-38. doi: 10.1016/j.tsf.2014.02.002

    4. [4]

      Wang L, Guo M R, Zhan J, Jiao X L, Chen D R, Wang T. A new design of an electrochromic energy storage device with high capacity, long cycle lifetime and multicolor display[J]. J. Mater. Chem. A, 2020,8:17098-17105. doi: 10.1039/D0TA04824K

    5. [5]

      Wu W, Wang M, Ma J M, Cao Y L, Deng Y H. Electrochromic metal oxides: Recent progress and prospect[J]. Adv. Electron. Mater., 2018,41800185. doi: 10.1002/aelm.201800185

    6. [6]

      Wang Y A, Meng Z H, Chen H, Li T, Zheng D J, Xu Q C, Wang H, Liu X Y, Guo W X. Pulsed electrochemical deposition of porous WO3 on silver networks for highly flexible electrochromic devices[J]. J. Mater. Chem. C, 2019,7:1966-1973. doi: 10.1039/C8TC05698F

    7. [7]

      Sun W M, Yeung M T, Lech A T, Lin C W, Lee C, Li T Q, Duan X F, Zhou J, Kaner R B. High surface area tunnels in hexagonal WO3[J]. Nano Lett., 2015,15:4834-4838. doi: 10.1021/acs.nanolett.5b02013

    8. [8]

      Mitchell J B, Lo W C, Genc A, LeBeau J, Augustyn V. Transition from battery to pseudocapacitor behavior via structural water in tungsten oxide[J]. Chem. Mater., 2017,29:3928-3937. doi: 10.1021/acs.chemmater.6b05485

    9. [9]

      Bi Z J, Li X M, Chen Y B, He X L, Xu X K, Gao X D. Large-scale multifunctional electrochromic-energy storage device based on tungsten trioxide monohydrate nanosheets and Prussian white[J]. ACS Appl. Mater. Interfaces, 2017,9:29872-29880. doi: 10.1021/acsami.7b08656

    10. [10]

      Xie Z, Gao L N, Liang B, Wang X F, Chen G, Liu Z, Chao J F, Chen D, Shen G Z. Fast fabrication of a WO3·2H 2O thin film with improved electrochromic properties[J]. J. Mater. Chem., 2012,22:19904-19910. doi: 10.1039/c2jm33622g

    11. [11]

      Wang Z, Gong W B, Wang X Y, Chen Z G, Chen X L, Chen J, Sun H Z, Song G, Cong S, Geng F X, Zhao Z G. Remarkable near-infrared electrochromism in tungsten oxide driven by interlayer water-induced battery-to-pseudocapacitor transition[J]. ACS Appl. Mater. Interfaces, 2020,12:33917-33925. doi: 10.1021/acsami.0c08270

    12. [12]

      Cai G F, Cui M Q, Kumar V, Darmawan P, Wang J X, Wang X, Eh A L, Qian K, Lee P S. Ultra-large optical modulation of electrochromic porous WO3 film and the local monitoring of redox activity[J]. Chem. Sci., 2016,7:1373-1382. doi: 10.1039/C5SC03727A

    13. [13]

      Baeck S H, Choi K S, Stucky J G D, McFarland E W. Enhancement of photocatalytic and electrochromic properties of electrochemically fabricated mesoporous WO3 thin films[J]. Adv. Mater., 2003,15:1269-1273. doi: 10.1002/adma.200304669

    14. [14]

      Qi C X, Tan Z, Feng Z H, Yu L P. Fabrication of bowl-like porous WO3 film by colloidal crystal template-assisted electrodeposition method[J]. J. Mater. Sci. Mater. Electron., 2014,25:1553-1558.

    15. [15]

      Giannouli M, Leftheriotis G. The effect of precursor aging on the morphology and electrochromic performance of electrodeposited tungsten oxide films[J]. Sol. Energy Mater. Sol. Cells, 2011,95:1932-1939. doi: 10.1016/j.solmat.2011.02.024

    16. [16]

      Kim C Y, Lee M, Huh S H, Kim E K. WO3 thin film coating from H2O-controlled peroxotungstic acid and its electrochromic properties[J]. J. Sol-Gel Sci. Technol., 2010,53:176-183. doi: 10.1007/s10971-009-2074-3

    17. [17]

      Yamanaka K. Electrodeposited films from aqueous tungstic acidhydrogen peroxide solutions for electrochromic display devices[J]. J. Appl. Phys., 1987,26:1884-1890. doi: 10.1143/JJAP.26.1884

    18. [18]

      Nakajima H, Tanaka H, Hibino M, Kudo T, Mizuno N. Reaction of nitrides of molybdenum and tungsten with hydrogen peroxide to form inorganic proton conductors[J]. Bull. Chem. Soc. Jpn., 1998,71:955-960. doi: 10.1246/bcsj.71.955

    19. [19]

      LIN H Q, LI H M, YU X Y, ZHAI H S, YUAN Y Z, WAN H L. Raman study of transformation behaviors of tungsten-containing peroxo species affected by different precursors and solution acidities[J]. Acta Chim. Sinica, 2004,62(18):1780-1784. doi: 10.3321/j.issn:0567-7351.2004.18.021

    20. [20]

      Pecquenard B, Castro-Garcia S, Livage J, Zavalij P Y, Whittingham S, Thouvenot R. Structure of hydrated tungsten peroxides[WO2(O2) H2O]·nH2O[J]. Chem. Mater., 1998,10:1882-1888. doi: 10.1021/cm980045n

    21. [21]

      Wang S L, Dou K, Zou Y S, Dong Y H, Li J B, Ju D, Zeng H B. Assembling tungsten oxide hydrate nanocrystal colloids formed by laser ablation in liquid into fast-response electrochromic films[J]. J. Colloid Interface Sci., 2017,489:85-91. doi: 10.1016/j.jcis.2016.08.072

    22. [22]

      Meulenkamp E A. Mechanism of WO3 electrodeposition from peroxy-tungstate solution[J]. J. Electrochem. Soc., 1997,144:1664-1671. doi: 10.1149/1.1837657

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