Citation: Yan-Ling SONG, Qi-Yuan ZHANG, Ai-Hua YAO. Template-free electrodeposition and electrochromic performance of porous WO₃·2H₂O thin film[J]. Chinese Journal of Inorganic Chemistry, ;2023, 39(1): 127-134. doi: 10.11862/CJIC.2022.260 shu

Template-free electrodeposition and electrochromic performance of porous WO₃·2H₂O thin film

Yan-Ling SONG ¹ ,
Qi-Yuan ZHANG ¹ ,
Ai-Hua YAO ^{1, 2,,}

1.
School of Materials Science and Engineering, Tongji University, Shanghai 200092, China
2.
Key Laboratory of Advanced Civil Engineering Materials, Ministry of Education, Tongji University, Shanghai 200092, China

Corresponding author: Ai-Hua YAO, 07182@tongji.edu.cn
Received Date: 3 August 2022
Revised Date: 4 November 2022

Figures(6)

Compared with anhydrous WO₃, tungsten oxide dihydrate (WO₃·2H₂O) shows superior electrochromic properties because of its unique layered structure and rich interlayer structural water. In this study, WO₃·2H₂O films were successfully fabricated on indium tin oxide (ITO) glass substrates using a facile, template-free cathodic electrodeposition method. The composition of the electrodeposition solution was optimized by modifying the volume of hydrogen peroxide (H₂O₂) added into the solution, and thus highly porous films were obtained. The thus deposited WO₃·2H₂O films exhibited excellent electrochromic performance, including significant optical contrast of over 90% at 633 nm, a fast switching speed of fewer than 10 s, and a long cycling lifetime (90% original optical modulation was retained after 10 000 cycles).
- electrochromic material,
- electrodeposition,
- tungsten oxide,
- porous film
1. [1]
  Huang Y, Wang B S, Chen F X, Han Y, Zhang W S, Wu X K, Li R, Jiang Q Y, Jia X L, Zhang R F. Electrochromic materials based on ions insertion and extraction[J]. Adv. Opt. Mater., 2022,102101783. doi: 10.1002/adom.202101783
2. [2]
  Pan J B, Zheng R Z, Wang Y, Ye X K, Wan Z Q, Jia C Y, Weng X L, Xie J L, Deng L J. A high-performance electrochromic device assembled with hexagonal WO₃ and NiO/PB composite nanosheet electrodes towards energy storage smart window[J]. Sol. Energy Mater. Sol. Cells, 2020,207110337. doi: 10.1016/j.solmat.2019.110337
3. [3]
  Granqvist C G. Electrochromics for smart windows: Oxide-based thin films and devices[J]. Thin Solid Films, 2014,564:1-38. doi: 10.1016/j.tsf.2014.02.002
4. [4]
  Wang L, Guo M R, Zhan J, Jiao X L, Chen D R, Wang T. A new design of an electrochromic energy storage device with high capacity, long cycle lifetime and multicolor display[J]. J. Mater. Chem. A, 2020,8:17098-17105. doi: 10.1039/D0TA04824K
5. [5]
  Wu W, Wang M, Ma J M, Cao Y L, Deng Y H. Electrochromic metal oxides: Recent progress and prospect[J]. Adv. Electron. Mater., 2018,41800185. doi: 10.1002/aelm.201800185
6. [6]
  Wang Y A, Meng Z H, Chen H, Li T, Zheng D J, Xu Q C, Wang H, Liu X Y, Guo W X. Pulsed electrochemical deposition of porous WO₃ on silver networks for highly flexible electrochromic devices[J]. J. Mater. Chem. C, 2019,7:1966-1973. doi: 10.1039/C8TC05698F
7. [7]
  Sun W M, Yeung M T, Lech A T, Lin C W, Lee C, Li T Q, Duan X F, Zhou J, Kaner R B. High surface area tunnels in hexagonal WO₃[J]. Nano Lett., 2015,15:4834-4838. doi: 10.1021/acs.nanolett.5b02013
8. [8]
  Mitchell J B, Lo W C, Genc A, LeBeau J, Augustyn V. Transition from battery to pseudocapacitor behavior via structural water in tungsten oxide[J]. Chem. Mater., 2017,29:3928-3937. doi: 10.1021/acs.chemmater.6b05485
9. [9]
  Bi Z J, Li X M, Chen Y B, He X L, Xu X K, Gao X D. Large-scale multifunctional electrochromic-energy storage device based on tungsten trioxide monohydrate nanosheets and Prussian white[J]. ACS Appl. Mater. Interfaces, 2017,9:29872-29880. doi: 10.1021/acsami.7b08656
10. [10]
  Xie Z, Gao L N, Liang B, Wang X F, Chen G, Liu Z, Chao J F, Chen D, Shen G Z. Fast fabrication of a WO₃·2H ₂O thin film with improved electrochromic properties[J]. J. Mater. Chem., 2012,22:19904-19910. doi: 10.1039/c2jm33622g
11. [11]
  Wang Z, Gong W B, Wang X Y, Chen Z G, Chen X L, Chen J, Sun H Z, Song G, Cong S, Geng F X, Zhao Z G. Remarkable near-infrared electrochromism in tungsten oxide driven by interlayer water-induced battery-to-pseudocapacitor transition[J]. ACS Appl. Mater. Interfaces, 2020,12:33917-33925. doi: 10.1021/acsami.0c08270
12. [12]
  Cai G F, Cui M Q, Kumar V, Darmawan P, Wang J X, Wang X, Eh A L, Qian K, Lee P S. Ultra-large optical modulation of electrochromic porous WO₃ film and the local monitoring of redox activity[J]. Chem. Sci., 2016,7:1373-1382. doi: 10.1039/C5SC03727A
13. [13]
  Baeck S H, Choi K S, Stucky J G D, McFarland E W. Enhancement of photocatalytic and electrochromic properties of electrochemically fabricated mesoporous WO₃ thin films[J]. Adv. Mater., 2003,15:1269-1273. doi: 10.1002/adma.200304669
14. [14]
  Qi C X, Tan Z, Feng Z H, Yu L P. Fabrication of bowl-like porous WO₃ film by colloidal crystal template-assisted electrodeposition method[J]. J. Mater. Sci. Mater. Electron., 2014,25:1553-1558.
15. [15]
  Giannouli M, Leftheriotis G. The effect of precursor aging on the morphology and electrochromic performance of electrodeposited tungsten oxide films[J]. Sol. Energy Mater. Sol. Cells, 2011,95:1932-1939. doi: 10.1016/j.solmat.2011.02.024
16. [16]
  Kim C Y, Lee M, Huh S H, Kim E K. WO₃ thin film coating from H₂O-controlled peroxotungstic acid and its electrochromic properties[J]. J. Sol-Gel Sci. Technol., 2010,53:176-183. doi: 10.1007/s10971-009-2074-3
17. [17]
  Yamanaka K. Electrodeposited films from aqueous tungstic acidhydrogen peroxide solutions for electrochromic display devices[J]. J. Appl. Phys., 1987,26:1884-1890. doi: 10.1143/JJAP.26.1884
18. [18]
  Nakajima H, Tanaka H, Hibino M, Kudo T, Mizuno N. Reaction of nitrides of molybdenum and tungsten with hydrogen peroxide to form inorganic proton conductors[J]. Bull. Chem. Soc. Jpn., 1998,71:955-960. doi: 10.1246/bcsj.71.955
19. [19]
  LIN H Q, LI H M, YU X Y, ZHAI H S, YUAN Y Z, WAN H L. Raman study of transformation behaviors of tungsten-containing peroxo species affected by different precursors and solution acidities[J]. Acta Chim. Sinica, 2004,62(18):1780-1784. doi: 10.3321/j.issn:0567-7351.2004.18.021
20. [20]
  Pecquenard B, Castro-Garcia S, Livage J, Zavalij P Y, Whittingham S, Thouvenot R. Structure of hydrated tungsten peroxides[WO₂(O₂) H₂O]·nH₂O[J]. Chem. Mater., 1998,10:1882-1888. doi: 10.1021/cm980045n
21. [21]
  Wang S L, Dou K, Zou Y S, Dong Y H, Li J B, Ju D, Zeng H B. Assembling tungsten oxide hydrate nanocrystal colloids formed by laser ablation in liquid into fast-response electrochromic films[J]. J. Colloid Interface Sci., 2017,489:85-91. doi: 10.1016/j.jcis.2016.08.072
22. [22]
  Meulenkamp E A. Mechanism of WO₃ electrodeposition from peroxy-tungstate solution[J]. J. Electrochem. Soc., 1997,144:1664-1671. doi: 10.1149/1.1837657
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通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Template-free electrodeposition and electrochromic performance of porous WO3·2H2O thin film

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通讯作者: 陈斌, bchen63@163.com

Template-free electrodeposition and electrochromic performance of porous WO₃·2H₂O thin film