Citation: Min ZHAO, Dong WU, Fei-Long JIANG, Qi-Hui CHEN, Mao-Chun HONG. A Flexible Ultramicroporous Metal-Organic Framework for Size-Selective Carbon Dioxide Capture Constructed from a Semirigid Ligand[J]. Chinese Journal of Inorganic Chemistry, ;2022, 38(12): 2459-2468. doi: 10.11862/CJIC.2022.256 shu

A Flexible Ultramicroporous Metal-Organic Framework for Size-Selective Carbon Dioxide Capture Constructed from a Semirigid Ligand

1.
College of Chemistry and Materials Science, Fujian Normal University, Fuzhou 350007, China
2.
Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou 350002, China

Corresponding author: Qi-Hui CHEN, chenqh@fjirsm.ac.cn Mao-Chun HONG, hmc@fjirsm.ac.cn
Received Date: 7 September 2022
Revised Date: 4 November 2022

Figures(5)

Herein, a flexible ultramicroporous metal-organic framework {[Co(DTBDA)]·4H₂O}_n (FJI-H35) was prepared from a semirigid ligand 3', 5'-di(1H-1, 2, 4-triazol-1-yl)-(1, 1'-biphenyl)-3, 5-dicarboxylic acid (H₂DTBDA) and cobalt nitrate. After activation, FJI-H35 underwent an adaptive structural transformation, making the pore diameter shrink from 0.43 to 0.37 nm. Gas adsorption tests showed that FJI-H35 could selectively capture CO₂ from N₂ and CH₄ with a high adsorption selectivity of 178 and a relatively low adsorption enthalpy (28.2 kJ·mol^-1). Breakthrough experiments further confirmed that FJI-H35 could efficiently and selectively capture CO₂ from CO₂/N₂ (15∶85, V/V) and CO₂/CH₄ (50∶50, V/V) mixtures.
- metal-organic framework,
- structural transformation,
- carbon dioxide capture,
- molecular sieve effect,
- selective adsorption
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