Citation: Min ZHAO, Dong WU, Fei-Long JIANG, Qi-Hui CHEN, Mao-Chun HONG. A Flexible Ultramicroporous Metal-Organic Framework for Size-Selective Carbon Dioxide Capture Constructed from a Semirigid Ligand[J]. Chinese Journal of Inorganic Chemistry, ;2022, 38(12): 2459-2468. doi: 10.11862/CJIC.2022.256 shu

A Flexible Ultramicroporous Metal-Organic Framework for Size-Selective Carbon Dioxide Capture Constructed from a Semirigid Ligand

1.
College of Chemistry and Materials Science, Fujian Normal University, Fuzhou 350007, China
2.
Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou 350002, China

Corresponding author: Qi-Hui CHEN, chenqh@fjirsm.ac.cn Mao-Chun HONG, hmc@fjirsm.ac.cn
Received Date: 7 September 2022
Revised Date: 4 November 2022

Figures(5)

Herein, a flexible ultramicroporous metal-organic framework {[Co(DTBDA)]·4H₂O}_n (FJI-H35) was prepared from a semirigid ligand 3', 5'-di(1H-1, 2, 4-triazol-1-yl)-(1, 1'-biphenyl)-3, 5-dicarboxylic acid (H₂DTBDA) and cobalt nitrate. After activation, FJI-H35 underwent an adaptive structural transformation, making the pore diameter shrink from 0.43 to 0.37 nm. Gas adsorption tests showed that FJI-H35 could selectively capture CO₂ from N₂ and CH₄ with a high adsorption selectivity of 178 and a relatively low adsorption enthalpy (28.2 kJ·mol^-1). Breakthrough experiments further confirmed that FJI-H35 could efficiently and selectively capture CO₂ from CO₂/N₂ (15∶85, V/V) and CO₂/CH₄ (50∶50, V/V) mixtures.
- metal-organic framework,
- structural transformation,
- carbon dioxide capture,
- molecular sieve effect,
- selective adsorption
1. [1]
  Hepburn C, Adlen E, Beddington J, Carter E A, Fuss S, Mac Dowell N, Minx J C, Smith P, Williams C K. The Technological and Economic Prospects for CO₂ Utilization and Removal[J]. Nature, 2019,575:87-97. doi: 10.1038/s41586-019-1681-6
2. [2]
  Yousef A M, El-Maghlany W M, Eldrainy Y A, Attia A. Low-Temperature Distillation Process for CO₂/N₂ Separation: A Study for Avoiding CO₂ Freeze-Out[J]. J. Heat Trans., 2018,140(4)042001. doi: 10.1115/1.4038193
3. [3]
  Zhang Y, Zhou Q, Qiu Z F, Zhang X Y, Chen J Q, Zhao Y, Gong F, Sun W Y. Tailoring Coordination Microenvironment of Cu(Ⅰ) in Metal-Organic Frameworks for Enhancing Electroreduction of CO₂ to CH₄[J]. Adv. Funct. Mater., 2022,32(36)2203677. doi: 10.1002/adfm.202203677
4. [4]
  Cheng X M, Wang P, Wang S Q, Zhao J, Sun W Y. Ti(Ⅳ)-MOF with Specific Facet-Ag Nanoparticle Composites for Enhancing the Photocatalytic Activity and Selectivity of CO₂ Reduction[J]. ACS Appl. Mater. Interfaces, 2022,14(28):32350-32359. doi: 10.1021/acsami.2c05037
5. [5]
  Eddaoudi M, Moler D B, Li H L, Chen B L, Reineke T M, O'Keeffe M, Yaghi O M. Modular Chemistry: Secondary Building Units as a Basis for the Design of Highly Porous and Robust Metal-Organic Carboxylate Frameworks[J]. Acc. Chem. Res., 2001,34(4):319-330. doi: 10.1021/ar000034b
6. [6]
  Zhou D D, Chen P, Wang C, Wang S S, Du Y, Yan H, Ye Z M, He C T, Huang R K, Mo Z W, Huang N Y, Zhang J P. Intermediate-Sized Molecular Sieving of Styrene from Larger and Smaller Analogues[J]. Nat. Mater., 2019,18(9):994-998. doi: 10.1038/s41563-019-0427-z
7. [7]
  Zhao D, Yu K L, Han X, He Y B, Chen B L. Recent Progress on Porous MOFs for Process-Efficient Hydrocarbon Separation, Luminescent Sensing, and Information Encryption[J]. Chem. Commun., 2022,58(6):747-770. doi: 10.1039/D1CC06261A
8. [8]
  Yang H J, Wang Y X, Krishna R, Jia X X, Wang Y, Hong A N, Dang C, Castillo H E, Bu X H, Feng P Y. Pore-Space-Partition-Enabled Exceptional Ethane Uptake and Ethane-Selective Ethane-Ethylene Separation[J]. J. Am. Chem. Soc., 2020,142(5):2222-2227. doi: 10.1021/jacs.9b12924
9. [9]
  Cui Y J, Li B, He H J, Zhou W, Chen B L, Qian G D. Metal-Organic Frameworks as Platforms for Functional Materials[J]. Acc. Chem. Res., 2016,49(3):483-493. doi: 10.1021/acs.accounts.5b00530
10. [10]
  Qian Y Y, Li D D, Han Y L, Jiang H L. Photocatalytic Molecular Oxygen Activation by Regulating Excitonic Effects in Covalent Organic Frameworks[J]. J. Am. Chem. Soc., 2020,142(49):20763-20771. doi: 10.1021/jacs.0c09727
11. [11]
  Wu D, Zhou K, Tian J D, Liu C P, Tian J Y, Jiang F L, Yuan D Q, Zhang J, Chen Q, Hong M C. Induction of Chirality in a Metal-Organic Framework Built from Achiral Precursors[J]. Angew. Chem. Int. Ed., 2021,60(6):3087-3094. doi: 10.1002/anie.202013885
12. [12]
  Tian J Y, Liu L P, Zhou K, Hong Z X, Chen Q H, Jiang F L, Yuan D W, Sun Q F, Hong M C. Metal-Organic Tube or Layered Assembly: Reversible Sheet-To-Tube Transformation and Adaptive Recognition[J]. Chem. Sci., 2020,11(36):9818-9826. doi: 10.1039/D0SC01176B
13. [13]
  Tian J Y, Jiang F L, Yuan D W, Zhang L J, Chen Q H, Hong M C. Electric-Field Assisted In Situ Hydrolysis of Bulk Metal-Organic Frameworks (MOFs) into Ultrathin Metal Oxyhydroxide Nanosheets for Efficient Oxygen Evolution[J]. Angew. Chem. Int. Ed., 2020,59(31):13101-13108. doi: 10.1002/anie.202004420
14. [14]
  Yuan S, Feng L, Wang K C, Pang J D, Bosch M, Lollar C, Sun Y J, Qin J S, Yang X Y, Zhang P, Wang Q, Zou L F, Zhang Y M, Zhang L L, Fang Y, Li J L, Zhou H C. Stable Metal-Organic Frameworks: Design, Synthesis, and Applications[J]. Adv. Mater., 2018,30(37)e1704303. doi: 10.1002/adma.201704303
15. [15]
  Wang X, Dong A R, Hu Y, Qian J J, Huang S M. A Review of Recent Work on Using Metal-Organic Frameworks to Grow Carbon Nanotubes[J]. Chem. Commun., 2020,56(74):10809-10823. doi: 10.1039/D0CC04015K
16. [16]
  Xue Z Z, Meng X D, Li X Y, Han S D, Pan J, Wang G M. Luminescent Thermochromism and White-Light Emission of a 3D [Ag₄Br₆] Cluster-Based Coordination Framework with both Adamantane-like Node and Linker[J]. Inorg. Chem., 2021,60(7):4375-4379. doi: 10.1021/acs.inorgchem.1c00280
17. [17]
  Mu Y, Wang D, Meng X D, Pan J, Han S D, Xue Z Z. Construction of Iodoargentates with Diverse Architectures: Template Syntheses, Structures, and Photocatalytic Properties[J]. Cryst. Growth Des., 2020,20(2):1130-1138. doi: 10.1021/acs.cgd.9b01448
18. [18]
  ZHAO D, LIAO Z T, ZHANG W, CHEN Z Z, SUN W Y. Progress in Functional Metal-Organic Frameworks for Catalytic Conversion of Carbon Dioxide[J]. Chinese J. Inorg. Chem., 2021,37(7):1153-1176.
19. [19]
  Lin R B, Xiang S, Zhou W, Chen B. Microporous Metal-Organic Framework Materials for Gas Separation[J]. Chem, 2020,6(2):337-363. doi: 10.1016/j.chempr.2019.10.012
20. [20]
  Liang W, Bhatt P M, Shkurenko A, Adil K, Mouchaham G, Aggarwal H, Mallick A, Jamal A, Belmabkhout Y, Eddaoudi M. A Tailor-Made Interpenetrated MOF with Exceptional Carbon-Capture Performance from Flue Gas[J]. Chem, 2019,5(4):950-963. doi: 10.1016/j.chempr.2019.02.007
21. [21]
  Liao P Q, Chen X W, Liu S Y, Li X Y, Xu Y T, Tang M, Rui Z, Ji H, Zhang J P, Chen X M. Putting an Ultrahigh Concentration of Amine Groups into a Metal-Organic Framework for CO₂ Capture at Low Pressures[J]. Chem. Sci., 2016,7(10):6528-6533. doi: 10.1039/C6SC00836D
22. [22]
  Zhang L, Jiang K, Jiang M D, Yue D, Wan Y T, Xing H B, Yang Y, Cui Y J, Chen B L, Qian G D. A Highly Stable Amino-Coordinated MOF for Unprecedented Block Off N₂ Adsorption and Extraordinary CO₂/N₂ Separation[J]. Chem. Commun., 2016,52(93):13568-13571. doi: 10.1039/C6CC07858C
23. [23]
  Ding M, Flaig R W, Jiang H L, Yaghi O M. Carbon Capture and Conversion Using Metal-Organic Frameworks and MOF-Based Materials[J]. Chem. Soc. Rev., 2019,48(10):2783-2828. doi: 10.1039/C8CS00829A
24. [24]
  Han L, Pham T, Zhuo M J, Forrest K A, Suepaul S, Space B, Zaworotko M J, Shi W, Chen Y, Cheng P, Zhang Z J. Molecular Sieving and Direct Visualization of CO₂ in Binding Pockets of an Ultramicroporous Lanthanide Metal-Organic Framework Platform[J]. ACS Appl. Mater. Interfaces, 2019,11(26):23192-23197. doi: 10.1021/acsami.9b04619
25. [25]
  Yang L F, Cui X L, Zhang Y B, Wang Q J, Zhang Z Q, Suo X, Xing H B. Anion Pillared Metal-Organic Framework Embedded with Molecular Rotors for Size-Selective Capture of CO₂ from CH₄ and N₂[J]. ACS Sustain. Chem. Eng., 2019,7(3):3138-3144. doi: 10.1021/acssuschemeng.8b04916
26. [26]
  Gong Y N, Xiong P, He C T, Deng J H, Zhong D C. A Lanthanum Carboxylate Framework with Exceptional Stability and Highly Selective Adsorption of Gas and Liquid[J]. Inorg. Chem., 2018,57(9):5013-5018. doi: 10.1021/acs.inorgchem.8b00082
27. [27]
  Cui P, Li J J, Dong J, Zhao B. Modulating CO₂ Adsorption in Metal-Organic Frameworks via Metal-Ion Doping[J]. Inorg. Chem., 2018,57(10):6135-6141. doi: 10.1021/acs.inorgchem.8b00730
28. [28]
  MENG L L, CHENG H T, XUE D X, WANG Q, BAI J F. Synthesis and Selective CO₂ Adsorption of a rtl-MOF Based upon 5-(3-Amino-pyridin-4-yl)-isophthalic Acid and [Cu₂(COO₄)] -Paddlewheel Unit[J]. Chinese J. Inorg. Chem., 2020,36(6):1098-1104.
29. [29]
  Wu D, Liu C P, Tian J Y, Jiang F L, Yuan D W, Chen Q H, Hong M C. Acid-Base-Resistant Metal-Organic Framework for Size-Selective Carbon Dioxide Capture[J]. Inorg. Chem., 2020,59(18):13542-13550. doi: 10.1021/acs.inorgchem.0c01912
30. [30]
  Guo Z Y, Yan D, Wang H L, Tesfagaber D, Li X L, Chen Y S, Huang W Y, Chen B L. A Three-Dimensional Microporous Metal-Metallo-porphyrin Framework[J]. Inorg. Chem., 2015,54(1):200-204. doi: 10.1021/ic502116k
31. [31]
  Liu S, Dong Q B, Wang D Q, Wang Y, Wang H J, Huang Y H, Wang S N, Liu L T, Duan J G. Interplay of Tri-and Bidentate Linkers to Evolve Micropore Environment in a Family of Quasi-3D and 3D Porous Coordination Polymers for Highly Selective CO₂ Capture[J]. Inorg. Chem., 2019,58(23):16241-16249. doi: 10.1021/acs.inorgchem.9b02774
32. [32]
  Wang Z, Zhang J H, Jiang J J, Wang H P, Wei Z W, Zhu X J, Pan M, Su C Y. A Stable Metal Cluster-Metalloporphyrin MOF with High Capacity for Cationic Dye Removal[J]. J. Mater. Chem. A, 2018,6(36):17698-17705. doi: 10.1039/C8TA06249H
33. [33]
  Chen K J, Madden D G, Pham T, Forrest K A, Kumar A, Yang Q Y, Xue W, Space B, Perry J J, Zhang J P, Chen X M, Zaworotko M J. Tuning Pore Size in Square-Lattice Coordination Networks for Size-Selective Sieving of CO₂[J]. Angew. Chem. Int. Ed., 2016,55(35):10268-10272. doi: 10.1002/anie.201603934
34. [34]
  Nandi S, Collins S, Chakraborty D, Banerjee D, Thallapally P K, Woo T K, Vaidhyanathan R. Ultralow Parasitic Energy for Postcombustion CO₂ Capture Realized in a Nickel Lsonicotinate Metal-Organic Framework with Excellent Moisture Stability[J]. J. Am. Chem. Soc., 2017,139(5):1734-1737. doi: 10.1021/jacs.6b10455
35. [35]
  Ye Y X, Zhang H, Chen L J, Chen S M, Lin Q J, Wei F F, Zhang Z J, Xiang S C. Metal-Organic Framework with Rich Accessible Nitrogen Sites for Highly Efficient CO₂ Capture and Separation[J]. Inorg. Chem., 2019,58(12):7754-7759. doi: 10.1021/acs.inorgchem.9b00182
36. [36]
  Wang Z S, Li M, Peng Y L, Zhang Z, Chen W, Huang X C. An Ultrastable Metal Azolate Framework with Binding Pockets for Optimal Carbon Dioxide Capture[J]. Angew. Chem. Int. Ed., 2019,58(45):16071-16076. doi: 10.1002/anie.201909046
37. [37]
  Shi C D, Tian J D, Jiang F L, Chen Q H, Hong M C. A Novel Co(Ⅱ)-Organic Framework with Multiple Active Sites for Selective Gas Adsorption[J]. Chin. J. Struct. Chem., 2021,40(2):169-174.
38. [38]
  Yu M H, Zhang P, Feng R, Yao Z Q, Yu Y C, Hu T L, Bu X H. Construction of a Multi-cage-Based MOF with a Unique Network for Efficient CO₂ Capture[J]. ACS Appl. Mater. Interfaces, 2017,9(31):26177-26183. doi: 10.1021/acsami.7b06491
39. [39]
  Li N, Chang Z, Huang H L, Feng R, He W W, Zhong M, Madden D G, Zaworotko M J, Bu X H. Specific K⁺ Binding Sites as CO₂ Traps in a Porous MOF for Enhanced CO₂ Selective Sorption[J]. Small, 2019,15(22)e1900426. doi: 10.1002/smll.201900426
40. [40]
  Zhang D S, Zhang Y Z, Zhang X, Wang F, Zhang J, Hu H, Gao J, Yan H, Liu H L, Ma H Y, Geng L L, Li Y W. Nanocage-Based Porous Metal-Organic Frameworks Constructed from Icosahedrons and Tetrahedrons for Selective Gas Adsorption[J]. ACS Appl. Mater. Interfaces, 2019,11(22):20104-20109. doi: 10.1021/acsami.9b05655
41. [41]
  Liang L F, Liu C P, Jiang F L, Chen Q H, Zhang L J, Xue H, Jiang H L, Qian J J, Yuan D Q, Hong M C. Carbon Dioxide Capture and Conversion by an Acid-Base Resistant Metal-Organic Framework[J]. Nat. Commun., 2017,81233. doi: 10.1038/s41467-017-01166-3
42. [42]
  Humby J D, Benson O, Smith G L, Argent S P, da Silva I, Cheng Y, Rudic S, Manuel P, Frogley M D, Cinque G, Saunders L K, Vitorica-Yrezabal I J, Whitehead G F S, Easun T L, Lewis W, Blake A J, Ramirez-Cuesta A J, Yang S, Schroder M. Host-Guest Selectivity in a Series of Isoreticular Metal-Organic Frameworks: Observation of Acetylene-To-Alkyne and Carbon Dioxide-To-Amide Interactions[J]. Chem. Sci., 2019,10(4):1098-1106. doi: 10.1039/C8SC03622E
43. [43]
  Song X H, Zhang M X, Chen C, Duan J G, Zhang W W, Pan Y, Bai J F. Pure-Supramolecular-Linker Approach to Highly Connected Metal-Organic Frameworks for CO₂ Capture[J]. J. Am. Chem. Soc., 2019,141(37):14539-14543. doi: 10.1021/jacs.9b07422
44. [44]
  Song X H, Zhang M X, Chen C, Duan J G, Zhang W W, Pan Y, Bai J F. Constructing and Finely Tuning the CO₂ Traps of Stable and Various-Pore-Containing MOFs towards Highly Selective CO₂ Capture[J]. Chem. Commun., 2019,55(24):3477-3480. doi: 10.1039/C8CC10116G
45. [45]
  Zhang J W, Qu P, Hu M C, Li S N, Jiang Y C, Zhai Q G. Topology-Guided Design for Sc-soc-MOFs and Their Enhanced Storage and Separation for CO₂ and C₂-Hydrocarbons[J]. Inorg. Chem., 2019,58(24):16792-16799. doi: 10.1021/acs.inorgchem.9b02959
1. [1]
  Xiaoling LUO , Pintian ZOU , Xiaoyan WANG , Zheng LIU , Xiangfei KONG , Qun TANG , Sheng WANG . Synthesis, crystal structures, and properties of lanthanide metal-organic frameworks based on 2, 5-dibromoterephthalic acid ligand. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1143-1150. doi: 10.11862/CJIC.20230271
2. [2]
  Peiran ZHAO , Yuqian LIU , Cheng HE , Chunying DUAN . A functionalized Eu³⁺ metal-organic framework for selective fluorescent detection of pyrene. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 713-724. doi: 10.11862/CJIC.20230355
3. [3]
  Youlin SI , Shuquan SUN , Junsong YANG , Zijun BIE , Yan CHEN , Li LUO . Synthesis and adsorption properties of Zn(Ⅱ) metal-organic framework based on 3, 3', 5, 5'-tetraimidazolyl biphenyl ligands. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1755-1762. doi: 10.11862/CJIC.20240061
4. [4]
  Lu XU , Chengyu ZHANG , Wenjuan JI , Haiying YANG , Yunlong FU . Zinc metal-organic framework with high-density free carboxyl oxygen functionalized pore walls for targeted electrochemical sensing of paracetamol. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 907-918. doi: 10.11862/CJIC.20230431
5. [5]
  Tiantian MA , Sumei LI , Chengyu ZHANG , Lu XU , Yiyan BAI , Yunlong FU , Wenjuan JI , Haiying YANG . Methyl-functionalized Cd-based metal-organic framework for highly sensitive electrochemical sensing of dopamine. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 725-735. doi: 10.11862/CJIC.20230351
6. [6]
  Jie ZHAO , Sen LIU , Qikang YIN , Xiaoqing LU , Zhaojie WANG . Theoretical calculation of selective adsorption and separation of CO₂ by alkali metal modified naphthalene/naphthalenediyne. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 515-522. doi: 10.11862/CJIC.20230385
7. [7]
  Ruolin CHENG , Haoran WANG , Jing REN , Yingying MA , Huagen LIANG . Efficient photocatalytic CO₂ cycloaddition over W₁₈O₄₉/NH₂-UiO-66 composite catalyst. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 523-532. doi: 10.11862/CJIC.20230349
8. [8]
  Jiahong ZHENG , Jingyun YANG . Preparation and electrochemical properties of hollow dodecahedral CoNi₂S₄ supported by MnO₂ nanowires. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1881-1891. doi: 10.11862/CJIC.20240170
9. [9]
  Zhiquan Zhang , Baker Rhimi , Zheyang Liu , Min Zhou , Guowei Deng , Wei Wei , Liang Mao , Huaming Li , Zhifeng Jiang . Insights into the Development of Copper-based Photocatalysts for CO₂ Conversion. Acta Physico-Chimica Sinica, 2024, 40(12): 2406029-. doi: 10.3866/PKU.WHXB202406029
10. [10]
  Yinuo Wang , Siran Wang , Yilong Zhao , Dazhen Xu . Selective Synthesis of Diarylmethyl Anilines and Triarylmethanes via Multicomponent Reactions: Introduce a Comprehensive Experiment of Organic Chemistry. University Chemistry, 2024, 39(8): 324-330. doi: 10.3866/PKU.DXHX202401063
11. [11]
  Tianyun Chen , Ruilin Xiao , Xinsheng Gu , Yunyi Shao , Qiujun Lu . Synthesis, Crystal Structure, and Mechanoluminescence Properties of Lanthanide-Based Organometallic Complexes. University Chemistry, 2024, 39(5): 363-370. doi: 10.3866/PKU.DXHX202312017
12. [12]
  Xilin Zhao , Xingyu Tu , Zongxuan Li , Rui Dong , Bo Jiang , Zhiwei Miao . Research Progress in Enantioselective Synthesis of Axial Chiral Compounds. University Chemistry, 2024, 39(11): 158-173. doi: 10.12461/PKU.DXHX202403106
13. [13]
  Shicheng Yan . Experimental Teaching Design for the Integration of Scientific Research and Teaching: A Case Study on Organic Electrooxidation. University Chemistry, 2024, 39(11): 350-358. doi: 10.12461/PKU.DXHX202408036
14. [14]
  Jingjing QING , Fan HE , Zhihui LIU , Shuaipeng HOU , Ya LIU , Yifan JIANG , Mengting TAN , Lifang HE , Fuxing ZHANG , Xiaoming ZHU . Synthesis, structure, and anticancer activity of two complexes of dimethylglyoxime organotin. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1301-1308. doi: 10.11862/CJIC.20240003
15. [15]
  Aiai WANG , Lu ZHAO , Yunfeng BAI , Feng FENG . Research progress of bimetallic organic framework in tumor diagnosis and treatment. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1825-1839. doi: 10.11862/CJIC.20240225
16. [16]
  Junjie Zhang , Yue Wang , Qiuhan Wu , Ruquan Shen , Han Liu , Xinhua Duan . Preparation and Selective Separation of Lightweight Magnetic Molecularly Imprinted Polymers for Trace Tetracycline Detection in Milk. University Chemistry, 2024, 39(5): 251-257. doi: 10.3866/PKU.DXHX202311084
17. [17]
  Shasha Ma , Zujin Yang , Jianyong Zhang . Facile Synthesis of FeBTC Metal-Organic Gel and Its Adsorption of Cr₂O₇²⁻: A Physical Chemistry Innovation Experiment. University Chemistry, 2024, 39(8): 314-323. doi: 10.3866/PKU.DXHX202401008
18. [18]
  Yuhao SUN , Qingzhe DONG , Lei ZHAO , Xiaodan JIANG , Hailing GUO , Xianglong MENG , Yongmei GUO . Synthesis and antibacterial properties of silver-loaded sod-based zeolite. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 761-770. doi: 10.11862/CJIC.20230169
19. [19]
  Jing SU , Bingrong LI , Yiyan BAI , Wenjuan JI , Haiying YANG , Zhefeng Fan . Highly sensitive electrochemical dopamine sensor based on a highly stable In-based metal-organic framework with amino-enriched pores. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1337-1346. doi: 10.11862/CJIC.20230414
20. [20]
  Shengbiao Zheng , Liang Li , Nini Zhang , Ruimin Bao , Ruizhang Hu , Jing Tang . Metal-Organic Framework-Derived Materials Modified Electrode for Electrochemical Sensing of Tert-Butylhydroquinone: A Recommended Comprehensive Chemistry Experiment for Translating Research Results. University Chemistry, 2024, 39(7): 345-353. doi: 10.3866/PKU.DXHX202310096

Get Citation

PDF

XML

Metrics

PDF Downloads(7)
Abstract views(610)
HTML views(31)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142