Citation: Zi-Xiang HAO, Yang CHEN, Lin-Rui WANG, Xiao-Li CUI. Synthesis of γ-Graphyne and Its Applications in the Fields of Energy Storage and Conversion[J]. Chinese Journal of Inorganic Chemistry, ;2022, 38(12): 2321-2341. doi: 10.11862/CJIC.2022.254 shu

Synthesis of γ-Graphyne and Its Applications in the Fields of Energy Storage and Conversion

Zi-Xiang HAO ¹ ,
Yang CHEN ^{1, 2,,} ,
Lin-Rui WANG ¹ ,
Xiao-Li CUI ^1,,

1.
Department of Material Science, Fudan University, Shanghai 200433, China
2.
College of Chemistry and Materials Science, Shanghai Normal University, Shanghai 200234, China

Corresponding author: Yang CHEN, yangchen@fudan.edu.cn Xiao-Li CUI, xiaolicui@fudan.edu.cn
Received Date: 10 July 2022
Revised Date: 27 September 2022

Figures(17)

Alkyne carbon material is a novel two-dimensional carbon allotrope with good electrical conductivity and high specific surface area. The porous structure composed of sp²- and sp-hybridized carbon promotes charge transfer and ion transport, which endows alkyne carbon material with broad application prospects in the field of energy storage and conversion. Theoretically, γ-graphyne (γ-GY) has the highest stability among the γ-GY-like carbon materials due to its stable conjugated system and unique triangular pore structure, which promotes the ionic intercalation/ de-intercalation process in alkali metal ion batteries. Given its excellent semiconductor properties, γ-GY is also an ideal candidate for photoelectrochemical and photocatalytic oxygen evolution and hydrogen evolution. Besides, the molecular framework and electron configuration of γ-GY can be regulated by heteroatom doping or rational molecular structural design of organic precursors. This review summarized synthesis methods of γ-GY and its applications in lithium (sodium and potassium) ion batteries, electrocatalysis, and photocatalysis, then further proposed the challenges and opportunities in the energy field.
- γ-graphyne,
- alkali metal ion batteries,
- photoelectrocatalysis,
- energy
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