Citation: He-Nan DONG, Yang-Yang GE, Xin-Ying WEI, De-Pei LIU, Yuan-Dong YAN, Shi-Cheng YAN. Electrodepositing Dense Sn/SnBi Alloy on Carbon Cloth for Electrocatalytic CO₂ Reduction[J]. Chinese Journal of Inorganic Chemistry, ;2022, 38(12): 2433-2442. doi: 10.11862/CJIC.2022.250 shu

Electrodepositing Dense Sn/SnBi Alloy on Carbon Cloth for Electrocatalytic CO₂ Reduction

1.
Electric Power Research Institute of State Grid Liaoning Electric Power Co., Ltd., Shenyang 110006, China
2.
Eco-materials and Renewable Energy Research Center (ERERC), College of Engineering and Applied Sciences, Nanjing University, Nanjing 210093, China

Corresponding author: Shi-Cheng YAN, yscfei@nju.edu.cn
Received Date: 15 June 2022
Revised Date: 12 October 2022

Figures(7)

SnBi alloy was prepared by the two-step electrodeposition method. Sn was first electrodeposited on the carbon cloth (CC). Since the electrolyte used in the second step was acidic, Sn was dissolved in the electrolyte to form a small amount of Sn²⁺. As a result, SnBi alloy dendrites formed by doping a small amount of Sn with Bi. Subsequently, SnBi alloy dendrites were transformed into SnBi alloy nanoparticles (NPs) by in-situ chemical oxidation and electrochemical reduction. Thanks to the nucleation sites provided by Sn, SnBi dendrites grow densely and uniformly on the CC, providing a high-quality precursor and finally achieving SnBi nanoparticles with a diameter of about 20 nm through two-step transformation. CC/Sn/SnBi NPs electrode exhibited 94.9% formate selectivity and current density up to 36 mA·cm^-2 at -1.08 V (vs RHE), showing high activity of electrocatalytic reduction of CO₂ with the continuous 12 h stability.
- electrocatalytic CO₂ reduction,
- SnBi alloy,
- three-dimensional electrode,
- bimetallic orbital interactions
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通讯作者: 陈斌, bchen63@163.com

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沈阳化工大学材料科学与工程学院沈阳 110142

Electrodepositing Dense Sn/SnBi Alloy on Carbon Cloth for Electrocatalytic CO2 Reduction

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通讯作者: 陈斌, bchen63@163.com

Electrodepositing Dense Sn/SnBi Alloy on Carbon Cloth for Electrocatalytic CO₂ Reduction