Citation: Sha OU, Zheng-Qiu WU, Wei XIE, Ping YUE, Zu-Quan HU. Synthesis and Fluorescence Applications of Coordination Polymers Based on Isoleucine-Derived Ligand[J]. Chinese Journal of Inorganic Chemistry, ;2022, 38(12): 2372-2382. doi: 10.11862/CJIC.2022.249 shu

Synthesis and Fluorescence Applications of Coordination Polymers Based on Isoleucine-Derived Ligand

Immune Cells and Antibody Engineering Research Center of Guizhou Province, School of Biology and Engineering, Guizhou Medical University, Guiyang 550025, China

Corresponding author: Zu-Quan HU, huzuquan@gmc.edu.cn
Received Date: 9 May 2022
Revised Date: 22 September 2022

Figures(12)

Compound [Zn₂(C₁₃H₁₇NO₃)₂]_n (1) was synthesized by a traditional solvothermal method with L-isoleucine derived ligand (C₁₃H₁₉NO₃) and Zn(NO₃)₂·6H₂O as a coordination polymer. Single-crystal X-ray diffraction results show that compound 1 crystallizes in the monoclinic crystal system with the P2₁ space group. The ligands bridge the metal ions to form a 2D layer structure, which further forms a 3D supramolecular network through van der Waals forces between the adjacent layers. The addition of rhodamine B (Rho-B) into the synthetic process of compound 1 leads to a composite material 2. The fluorescence test results showed that the luminescence of compound 1 was mainly based on the ligand under the excitation at 370 nm, while composite 2 showed the additional emission peak of Rho-B at 580 nm besides the ligand. Using the relative intensity ratios of emission peaks (the ligand and Rho-B) as the detection signal, composite 2 was applied to the detection of metal cations and volatile organic compounds (VOCs). The experimental results showed that the material could selectively recognize Cr³⁺ in H₂O and demonstrate a quick response to the benzaldehyde vapor.
- coordination polymer,
- detection,
- fluorescence,
- rhodamine B
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