Citation: Ming-Hao HUANG, Zhuo LI, Lei-Lei DU, Zhi-Kang JIN, Ren-Hong LI. CuPd/MgO for Efficient Catalytic Hydrogen Production from Formaldehyde Solution at Room Temperature[J]. Chinese Journal of Inorganic Chemistry, ;2022, 38(12): 2452-2458. doi: 10.11862/CJIC.2022.247 shu

CuPd/MgO for Efficient Catalytic Hydrogen Production from Formaldehyde Solution at Room Temperature

  • Corresponding author: Ren-Hong LI, lirenhong@zstu.edu.cn
  • Received Date: 29 June 2022
    Revised Date: 9 October 2022

Figures(5)

  • The composite catalyst of CuPd alloy nanoparticles supported on MgO (CuPd/MgO) was prepared by an impregnation reduction method. CuPd/MgO showed excellent catalytic performance during formaldehyde reforming for hydrogen production at room temperature in the air. The turnover frequency (TOF) of CuPd/MgO was as high as 812.6 h-1, which was respectively 2.3 times and 23 times higher than that of Cu/MgO (TOF=356.7 h-1) and Pd/MgO (TOF=34.8 h-1) under the same reaction conditions. Based on the experimental observations and characterization results, we found that a strong metal support interaction (SMSI) between CuPd alloy nanoparticles and MgO support enriched with defects on the surface was present in CuPd/MgO. This interaction was conducive to the transfer and recombination of electrons on the catalyst, greatly promoting the adsorption, activation, and reduction of oxygen on the catalyst surface to form superoxide anion radical (·O2-). The ·O2- combined with the proton generated by the C—H bond breaking of formaldehyde to form superoxide radical (·OOH). The hydrogen radical (·H) dissociated from water molecules in the reaction system continuously combined with ·OOH to generate hydrogen and oxygen, leading to the generation of hydrogen and the regeneration of oxygen.
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    1. [1]

      Feng J X, Wu J Q, Tong Y X, Li G R. Efficient Hydrogen Evolution on Cu Nanodots-Decorated Ni3S2 Nanotubes by Optimizing Atomic Hydrogen Adsorption and Desorption[J]. J. Am. Chem. Soc., 2018,140:610-617. doi: 10.1021/jacs.7b08521

    2. [2]

      Turner J A. A Realizable Renewable Energy Future[J]. Science, 1999,285:687-689. doi: 10.1126/science.285.5428.687

    3. [3]

      Chaubey R, Sahu S, James O O, Maity S. A Review on Development of Industrial Processes and Emerging Techniques for Production of Hydrogen from Renewable and Sustainable Sources[J]. Renew. Sust. Energ. Rev., 2013,23:443-462. doi: 10.1016/j.rser.2013.02.019

    4. [4]

      Brentner L B, Peccia J, Zimmerman J B. Challenges in Developing Biohydrogen as a Sustainable Energy Source: Implications for a Research Agenda[J]. Environ. Sci. Technol., 2010,44:2243-2254. doi: 10.1021/es9030613

    5. [5]

      Wang C L, Astruc D. Recent Developments of Nanocatalyzed Liquid-Phase Hydrogen Generation[J]. Chem. Soc. Rev., 2021,50:3437-3484. doi: 10.1039/D0CS00515K

    6. [6]

      Trincado M, Sinha V, Rodriguez-Lugo R E, Pribanic B, De Bruin B, Grützmacher H. Homogeneously Catalysed Conversion of Aqueous Formaldehyde to H2 and Carbonate[J]. Nat. Commun., 2017,814990. doi: 10.1038/ncomms14990

    7. [7]

      Bi Y P, Lu G X. Morphology-Controlled Preparation of Silver Nanocrystals and Their Application in Catalysis[J]. Chem. Lett., 2008,37:514-515. doi: 10.1246/cl.2008.514

    8. [8]

      Bi Y P, Lu G X. Iodide Ions Control Galvanic Replacement Growth of Uniform Rhodium Nanotubes at Room Temperature[J]. Chem. Commun., 2008,47:6402-6404.

    9. [9]

      LI S P. Pd Catalyst Formaldehyde to Produce Hydrogen at Room Temperature. Lanzhou: Lanzhou University of Technology, 2016: 26-27

    10. [10]

      Du X R, Tang H L, Qiao B T. Oxidative Strong Metal-Support Interactions[J]. Catalysts, 2021,11896. doi: 10.3390/catal11080896

    11. [11]

      Li R H, Liu Z Q, Trinh Q T, Miao Z Q, Chen S, Qian K C, Wong R J, Xi S B, Yan Y, Borgna A, Liang S P, Wei T, Dai Y H, Wang P, Tang Y, Yan X Q, Choksi S T, Liu W. Strong Metal-Support Interaction for 2D Materials: Application in Noble Metal/TiB2 Heterointerfaces and Their Enhanced Catalytic Performance for Formic Acid Dehydrogenation[J]. Adv. Mater., 2021,332101536. doi: 10.1002/adma.202101536

    12. [12]

      Liu X Y, Liu M H, Luo Y C, Mou C Y, Lin S D, Cheng H K, Chen J M, Lee J F, Lin T S. Strong Metal-Support Interactions Between Gold Nanoparticles and ZnO Nanorods in CO Oxidation[J]. J. Am. Chem. Soc., 2012,134:10251-10258. doi: 10.1021/ja3033235

    13. [13]

      Tauster S J, Fung S C, Baker R T K, Horsley J A. Strong-Interactions in Supported-Metal Catalysts[J]. Science, 1981,211:1121-1125. doi: 10.1126/science.211.4487.1121

    14. [14]

      Belton D N, Sun Y M, White J M. Encapsulation and Electronic Effects in a Thin-Film Model of a Rhodium-Titania Catalyst[J]. J. Am. Chem. Soc., 1984,106:3059-3060. doi: 10.1021/ja00322a066

    15. [15]

      Li R H, Zhu X H, Yan X Q, Kobayashi H, Yoshida S, Chen W X, Du L L, Qian K C, Wu B L, Zou S H, Lu L F, Yi W Z, Zhou Y H, Fan J. Oxygen-Controlled Hydrogen Evolution Reaction: Molecular Oxygen Promotes Hydrogen Production from Formaldehyde Solution Using Ag/MgO Nanocatalyst[J]. ACS Catal., 2017,7:1478-1484. doi: 10.1021/acscatal.6b03370

    16. [16]

      Wang H, Wang L, Lin D, Feng X, Niu Y M, Zhang B S, Xiao F S. Strong Metal-Support Interactions on Gold Nanoparticle Catalysts Achieved through Le Chatelier's Principle[J]. Nat. Catal., 2021,4:418-424. doi: 10.1038/s41929-021-00611-3

    17. [17]

      Chen D, Sun P C, Liu H, Yang J. Bimetallic Cu-Pd Alloy Multipods and Their Highly Electrocatalytic Performance for Formic Acid Oxidation and Oxygen Reduction[J]. J. Mater. Chem. A, 2017,5:4421-4429. doi: 10.1039/C6TA10476B

    18. [18]

      Li R H, Zhu X H, Du L L, Qian K C, Wu B L, Kawabata S, Kobayashi H, Yan X Q, Chen W X. All-Solid-State Magnesium Oxide Supported Group Ⅷ and ⅠB Metal Catalysts for Selective Catalytic Reforming of Aqueous Aldehydes into Hydrogen[J]. Int. J. Hydrog. Energy, 2017,42:10834-10843. doi: 10.1016/j.ijhydene.2017.02.041

    19. [19]

      Chen S, Liang S P, Wu B L, Lan Z H, Guo Z W, Kobayashi H, Yan X Q, Li R H. Ultrasmall Silver Clusters Stabilized on MgO for Robust Oxygen-Promoted Hydrogen Production from Formaldehyde Reforming[J]. ACS Appl. Mater. Interfaces, 2019,11:33946-33954. doi: 10.1021/acsami.9b11023

    20. [20]

      Qian K C, Du L L, Zhu X H, Laing S P, Chen S, Kobayashi H, Yan X Q, Xu M, Dai Y H, Li R H. Directional Oxygen Activation by Oxygen-Vacancy Rich WO2 Nanorods for Superb Hydrogen Evolution via Formaldehyde Reforming[J]. J. Mater. Chem. A, 2019,7:14592-14601. doi: 10.1039/C9TA03051D

    21. [21]

      Liang S P, Chen S, Guo Z W, Lan Z H, Kobayashi H, Yan X Q, Li R H. In Situ Generated Electron-Deficient Metallic Copper as the Catalytically Active Site for Enhanced Hydrogen Production from Alkaline Formaldehyde Solution[J]. Catal. Sci. Technol., 2019,9:5292-5300. doi: 10.1039/C9CY01136F

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