Citation: Ying LÜ, Xiu-Mei LI, Yan-Ju HUANG, Bo LIU, Shi ZHOU. Synthesis, Structure, and Properties of Zinc/Cadmium Complexes Based on Succinic Acid Ligand[J]. Chinese Journal of Inorganic Chemistry, ;2022, 38(12): 2511-2520. doi: 10.11862/CJIC.2022.246 shu

Synthesis, Structure, and Properties of Zinc/Cadmium Complexes Based on Succinic Acid Ligand

Ying LÜ ^1,, ,
Xiu-Mei LI ¹ ,
Yan-Ju HUANG ¹ ,
Bo LIU ^2,, ,
Shi ZHOU ²

1.
Faculty of Chemistry, Tonghua Normal University, Tonghua, Jilin 134002, China
2.
Key Laboratory of Preparation and Applications of Environmental Friendly Materials (Jilin Normal University), Ministry of Education, Siping, Jilin 136000, China

Corresponding author: Ying LÜ, lvying719@126.com Bo LIU, 112363305@qq.com
Received Date: 8 June 2022
Revised Date: 15 October 2022

Figures(9)

Two transition-metal complexes, [Zn(suc)(HL)]_n (1) and [Cd(suc)0.5(L)]_n (2) (H₂suc=succinic acid, HL=3-(2-pyridyl)pyrazole), have been achieved under hydrothermal conditions and structurally characterized by elemental analysis, IR spectrum, single-crystal X-ray diffraction, thermogravimetric analysis, fluorescent spectroscopy, and powder X-ray diffraction. In complex 1, the carboxyl ligand suc^2- bridges the metal centers via bidentate and monodentate modes. The metal centers are coordinated by suc^2- to form a 2D network structure. In 2, suc^2- and L-ligands linked the Cd (Ⅱ) ions to form a 2D framework too. Besides, the quantum-chemical calculations were finished on 'molecular fragments'selected from the crystal structure of 1 and 2 by the PBE0/LANL2DZ method in the Gaussian16 program. The calculation results indicate the distinct covalent interaction between the coordinated atoms and Zn(Ⅱ) ion/Cd(Ⅱ) ion.
- Zn(Ⅱ) complex,
- Cd(Ⅱ) complex,
- succinic acid,
- 3-(2-pyridyl)pyrazole,
- crystal structure
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