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Citation: Ji-Jiang WANG, Lao-Bang WANG, Er-Lin YUE, Jin-Feng LI, Chao BAI, Long TANG, Xiao WANG, Xiang-Yang HOU, Yu-Qi ZHANG. A Highly Stable Cd(Ⅱ) Coordination Polymer for Detection of Roxithromycin and B4O72-[J]. Chinese Journal of Inorganic Chemistry, ;2022, 38(12): 2491-2498. doi: 10.11862/CJIC.2022.239 shu

A Highly Stable Cd(Ⅱ) Coordination Polymer for Detection of Roxithromycin and B4O72-

  • Yan'an City Key Laboratory of New Energy & New Functional Materials, Shaanxi Key Laboratory of Chemical Reaction Engineering, College of Chemistry and Chemical Engineering, Yan'an University, Yan'an, Shaanxi 716000, China

  • Corresponding author: Ji-Jiang WANG, yadxwjj@126.com
  • Received Date: 1 May 2022
    Revised Date: 21 September 2022

Figures(3)

  • A stable coordination polymer, [Cd2(L) (bpb) (H2O)4] ·0.5H4L (1) (H4L=1, 1'-ethylbiphenyl-3, 3', 5, 5'-tetracarboxylic acid, bpb=1, 4-di(pyridin-4-yl) benzene), were successfully constructed under solvothermal conditions. 1 exhibited excellent stability in different organic solvents and water. 1 could detect roxithromycin (ROX) and B4O72- in water by fluorescence quenching, and the detection limits were 0.21 and 1.59 μmol·L-1, respectively. 1 could be successfully used for the determination of ROX and B4O72- in Yanhe River water. Moreover, the possible sensing mechanisms are also discussed in detail.
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