A Halogen Hydrogen-Bonded Fe(Ⅲ) Complex Showing Hysteretic Spin-Crossover Behavior above Room Temperature
- Corresponding author: Dong SHAO, shaodong@nju.edu.cn
Citation:
Xiao-Qin WEI, Zhuan GAO, Fan REN, Xiao-You CUI, Yue ZHOU, Dong SHAO. A Halogen Hydrogen-Bonded Fe(Ⅲ) Complex Showing Hysteretic Spin-Crossover Behavior above Room Temperature[J]. Chinese Journal of Inorganic Chemistry,
;2022, 38(11): 2283-2290.
doi:
10.11862/CJIC.2022.235
Halcrow M A. Spin Crossover Materials: Properties and Applications. New York: Wiley, 2013.
Ruben M, Kuppusamy S K. Sublimable Spin-Crossover Complexes: From Spin-State Switching to Molecular Devices[J]. Angew. Chem. Int. Ed., 2021,60(14):7502-7521. doi: 10.1002/anie.201911256
Sato O, Tao J, Zhang Y Z. Control of Magnetic Properties through External Stimuli[J]. Angew. Chem. Int. Ed., 2007,46(13):2152-2187. doi: 10.1002/anie.200602205
Halcrow M A. Structure: Function Relationships in Molecular Spin-Crossover Complexes[J]. Chem. Soc. Rev., 2011,40(7):4119-4142. doi: 10.1039/c1cs15046d
Shao D, Shi L, Shen F X, Wei X Q, Sato O, Wang X Y. Reversible On-Off Switching of the Hysteretic Spin Crossover in a Cobalt(Ⅱ) Complex via Crystal to Crystal Transformation[J]. Inorg. Chem., 2019,58(17):11589-11598. doi: 10.1021/acs.inorgchem.9b01436
Zhao X H, Shao D, Chen J T, Gan D X, Yang J, Zhang Y Z. A Trinuclear {Fe2ⅢFeⅡ} Complex Involving Both Spin and Non-spin Transitions Exhibits Three-Step and Wide Thermal Hysteresis[J]. Sci. China Chem., 2022,65(3):532-538. doi: 10.1007/s11426-021-1153-0
Shen K Y, Zhang C J, Qu L Y, Jiang S Q, Zhang Y, Tong M L, Bao X. Thermodriven, Acidity-Driven, and Photo-Driven Spin-State Switching in Pyridylacylhydrazoneiron(Ⅱ) Complexes at or above Room Temperature[J]. Inorg. Chem., 2021,60(23):18225-18233. doi: 10.1021/acs.inorgchem.1c02866
Wang L F, Lv B H, Wu F T, Huang G Z, Ruan Z Y, Chen Y C, Liu M, Ni Z P, Tong M L. Reversible On-Off Switching of Spin-Crossover Behavior via Photochemical[2+2] Cycloaddition Reaction[J]. Sci. China Chem., 2022,65(1):120-127. doi: 10.1007/s11426-021-1093-2
Craze A R, Zenno H, Pfrunder M C, McMurtrie J C., Hayami S, Clegg J K, Li F. Supramolecular Modulation of Spin Crossover in an Fe(Ⅱ) Dinuclear Triple Helicate[J]. norg. Chem., 2021,60(9):6731-6738.
Shen F X, Pi Q, Le S, Shao D, Li H Q, Sun Y C. Spin Crossover in Hydrogen-Bonded Frameworks of FeⅡ Complexes with Organodisulfonate Anions[J]. Dalton Trans., 2019,48(24):8815-8825. doi: 10.1039/C9DT01326A
Zhao X H, Zhang S L, Shao D, Wang X Y. Spin Crossover in[Fe(2-picolylamine)3]2+ Adjusted by Organosulfonate Anions[J]. Inorg. Chem., 2015,54(16):7857-7867. doi: 10.1021/acs.inorgchem.5b00870
Zhang S L, Zhao X H, Wang Y M, Shao D, Wang X Y. Spin Crossover Behaviour in One-Dimensional FeⅡ Compounds Based on the[M(CN)4]2- (M=Pd, Pt) Units[J]. Dalton Trans., 2015,44(20):9682-9690. doi: 10.1039/C5DT00836K
Harding D J, Harding P, Phonsri W. Spin Crossover in Iron(Ⅲ) Complexes[J]. Coord. Chem. Rev., 2016,313:38-61. doi: 10.1016/j.ccr.2016.01.006
Nakaya M, Ohtani R, Lindoy L F, Hayami S. Light-Induced Excited Spin State Trapping in Iron(Ⅲ) Complexes[J]. Inorg. Chem. Front., 2021,8(2):484-498. doi: 10.1039/D0QI01188F
WANG K J, LI H Q, SUN Y C, WANG X Y. Synthesis and Properties of an Iron Spin Crossover Compound with 1D Chains Bridged by Hydrogen Bonds[J]. Chinese J. Inorg. Chem., 2020,36(6):1143-1148.
Boca M, Jameson R F, Linert W. Fascinating Variability in the Chemistry and Properties of 2, 6-Bis-(benzimidazol-2-yl)-pyridine and 2, 6-Bis-(benzthiazol-2-yl)-pyridine and Their Complexes[J]. Coord. Chem. Rev., 2011,255(1/2):290-317.
Ruttimann S, Moreau C M, Williams A F, Bernardinelli G, Addison A W. Complexes of Structural Analogs of Terpyridyl with Iron and Zinc—The X-ray Crystal Structure of Bis[2, 6-bis(benzimidazol-2-yl) pyridine]iron (Ⅱ) Trifluoromethylsulfonate Bis-ethanol Solvate[J]. Polyhedron, 1992,11(6):635-646. doi: 10.1016/S0277-5387(00)83320-3
Boca R, Baran P, Dlhifi L, Fuess H, Haase W, Renz F, Linert W, Svoboda I, Wemer R. Crystal Structure and Spin Crossover Studies on Bis(2, 6-bis(benzimidazol-2-yl)pyridine) Iron(Ⅱ) Perchlorate[J]. Inorg. Chim. Acta, 1997,260(2):129-136. doi: 10.1016/S0020-1693(96)05550-8
Boca R, Baran P, Boca M, Fuess H, Haase W, Linert W, Papfinkovz B, Werner R. Spin Crossover in Bis(2, 6-bis(benzimidazol-2-yl)pyridine) Iron(Ⅱ) Tetraphenylborate[J]. Inorg. Chim. Acta, 1998,278(2):190-196. doi: 10.1016/S0020-1693(98)00023-1
Boca R, Boca M, Dlhan L, Falk K, Fuess H, Haase W, Jaroščiak R, Papánková B, Renz F, Vrbová M, Werner R. Strong Cooperativeness in the Mononuclear Iron(Ⅱ) Derivative Exhibiting an Abrupt Spin Transition above 400 K[J]. Inorg. Chem., 2001,40(13):3025-3033. doi: 10.1021/ic000807s
Boca R, Renz F, Boca M, Fuess H, Haase W, Kicklbick G, Linert W, Vrbova-Schikora M. Tuning the Spin Crossover Above Room Temperature: Iron(Ⅱ) Complexes of Substituted and Deprotonated 2, 6-Bis (benzimidazol-2-yl)pyridine[J]. Inorg. Chem. Commun., 2005,8(2):227-230. doi: 10.1016/j.inoche.2004.12.014
Sheldrick G M. SHELXTL, Version 6.14. Bruker AXS, Inc., Madison, WI, 2000-2003.
Dolomanov O V, Bourhis L J, Gildea R J, Howard J A K, Puschmann H. OLEX2: A Complete Structure Solution, Refinement and Analysis Program[J]. J. Appl. Crystallogr., 2009,42:339-341. doi: 10.1107/S0021889808042726
Llunell M, Casanova D, Cirera J, Alemany P, Alvarez S. SHAPE, Version 2.1. University of Barcelona, 2013.
Ketkaew R, Tantirungrotechai Y, Harding P, Chastanet G, Guionneau P, Marchivie M, Harding D J. OctaDist: A Tool for Calculating Distortion Parameters in Spin Crossover and Coordination Complexes[J]. Dalton Trans., 2021,50(3):1086-1096. doi: 10.1039/D0DT03988H
Martin J P, Zarembowitch J, Bousseksou A, Dworkin A, Haasnoot J G, Varret F. Solid State Effects on Spin Transitions: Magnetic, Calorimetric, and Mössbauer-Effect Properties of[FexCo1-x(4, 4'-bis-1, 2, 4-triazole)2(NCS)2] ·H2O Mixed-Crystal Compounds[J]. Inorg. Chem., 1994,33(26):6325-6333. doi: 10.1021/ic00104a049
Domracheva N E, Pyataev A V, Vorobeva V E, Zueva E M. Detailed EPR Study of Spin Crossover Dendrimeric Iron(Ⅲ) Complex[J]. J. Phys. Chem. B, 2013,117(25):7833-7842. doi: 10.1021/jp403682p
Domracheva N, Pyataev A, Manapov R, Gruzdev M, Chervonova U, Kolker A. Structural, Magnetic and Dynamic Characterization of Liquid Crystalline Iron(Ⅲ) Schiff Base Complexes with Asymmetric Ligands[J]. Eur. J. Inorg. Chem., 2011(8):1219-1229.
Thammasangwan W, Harding P, Telfer S G, Alkaş A, Phonsri W, Murray K S, Clérac R, Rouzières M, Chastanet G, Harding D J. Thermal and Light-Activated Spin Crossover in Iron(Ⅲ) qnal Complexes[J]. Eur. J. Inorg. Chem., 2020(14):1325-1330.
Ouyang Z J, Mo X Y, Yang M, Zhong L, Chen W B, Gao S, Dong W. High Temperature Fe(Ⅲ) Spin Crossover Behaviours in Three Unprecedented FeⅢ—MⅡ—FeⅢ (M=Fe, Cd) Linear Trinuclear Complexes[J]. Inorg. Chem. Front., 2020,7(7):1526-1531. doi: 10.1039/C9QI01560D
Weber B, Bauer W, Obel J. An Iron(Ⅱ) Spin-Crossover Complex with a 70 K Wide Thermal Hysteresis Loop[J]. Angew. Chem. Int. Ed., 2008,47(52):10098-10101. doi: 10.1002/anie.200802806
Hayami S, Gu Z, Yoshiki H, Fujishima A, Sato O. Iron(Ⅲ) Spin-Crossover Compounds with a Wide Apparent Thermal Hysteresis around Room Temperature[J]. J. Am. Chem. Soc., 2001,123(47):11644-11650. doi: 10.1021/ja0017920
Feng L J, Yuan Y H, Yan B J, Feng T T, Jian Y P, Zhang J C, Sun W Y, Lin K, Luo G S, Wang N. Halogen Hydrogen-Bonded Organic Framework (XHOF) Constructed by Singlet Open-Shell Diradical for Efficient Photoreduction of U(Ⅵ)[J]. Nat. Commun., 2022,131389. doi: 10.1038/s41467-022-29107-9
Yinglian LI , Chengcheng ZHANG , Xinyu ZHANG , Xinyi WANG . Spin crossover in [Co(pytpy)2]2+ complexes modified by organosulfonate anions. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1162-1172. doi: 10.11862/CJIC.20240087
Yadan SUN , Xinfeng LI , Qiang LIU , Oshio Hiroki , Yinshan MENG . Structures and magnetism of dinuclear Co complexes based on imine derivatives. Chinese Journal of Inorganic Chemistry, 2024, 40(11): 2212-2220. doi: 10.11862/CJIC.20240131
Shuai Liang , Wen-Jing Jiang , Ji-Xiang Hu . Achieving colossal anisotropic thermal expansion via synergism of spin crossover and rhombus deformation. Chinese Journal of Structural Chemistry, 2025, 44(2): 100430-100430. doi: 10.1016/j.cjsc.2024.100430
Zhenzhu Wang , Chenglong Liu , Yunpeng Ge , Wencan Li , Chenyang Zhang , Bing Yang , Shizhong Mao , Zeyuan Dong . Differentiated self-assembly through orthogonal noncovalent interactions towards the synthesis of two-dimensional woven supramolecular polymers. Chinese Chemical Letters, 2024, 35(5): 109127-. doi: 10.1016/j.cclet.2023.109127
Bingbing Shi , Yuchun Wang , Yi Zhou , Xing-Xing Zhao , Yizhou Li , Nuoqian Yan , Wen-Juan Qu , Qi Lin , Tai-Bao Wei . A supramolecular oligo[2]rotaxane constructed by orthogonal platinum(Ⅱ) metallacycle and pillar[5]arene-based host–guest interactions. Chinese Chemical Letters, 2024, 35(10): 109540-. doi: 10.1016/j.cclet.2024.109540
Guoju Guo , Xufeng Li , Jie Ma , Yongjia Shi , Jian Lv , Daoshan Yang . Photocatalyst/metal-free sequential C–N/C–S bond formation: Synthesis of S-arylisothioureas via photoinduced EDA complex activation. Chinese Chemical Letters, 2024, 35(11): 110024-. doi: 10.1016/j.cclet.2024.110024
Bing Shen , Tongwei Yuan , Wenshuang Zhang , Yang Chen , Jiaqiang Xu . Complex shell Fe-ZnO derived from ZIF-8 as high-quality acetone MEMS sensor. Chinese Chemical Letters, 2024, 35(11): 109490-. doi: 10.1016/j.cclet.2024.109490
Shuai Li , Liuting Zhang , Fuying Wu , Yiqun Jiang , Xuebin Yu . Efficient catalysis of FeNiCu-based multi-site alloys on magnesium-hydride for solid-state hydrogen storage. Chinese Chemical Letters, 2025, 36(1): 109566-. doi: 10.1016/j.cclet.2024.109566
Mianfeng Li , Haozhi Wang , Zijun Yang , Zexiang Yin , Yuan Liu , Yingmei Bian , Yang Wang , Xuerong Zheng , Yida Deng . Synergistic enhancement of alkaline hydrogen evolution reaction by role of Ni-Fe LDH introducing frustrated Lewis pairs via vacancy-engineered. Chinese Chemical Letters, 2025, 36(3): 110199-. doi: 10.1016/j.cclet.2024.110199
Ying-Yu Zhang , Jia-Qi Luo , Yan Han , Wan-Ying Zhang , Yi Zhang , Hai-Feng Lu , Da-Wei Fu . Bistable switch molecule DPACdCl4 showing four physical channels and high phase transition temperature. Chinese Chemical Letters, 2025, 36(1): 109530-. doi: 10.1016/j.cclet.2024.109530
Yang Qin , Jiangtian Li , Xuehao Zhang , Kaixuan Wan , Heao Zhang , Feiyang Huang , Limei Wang , Hongxun Wang , Longjie Li , Xianjin Xiao . Toeless and reversible DNA strand displacement based on Hoogsteen-bond triplex. Chinese Chemical Letters, 2024, 35(5): 108826-. doi: 10.1016/j.cclet.2023.108826
Conghui Wang , Lei Xu , Zhenhua Jia , Teck-Peng Loh . Recent applications of macrocycles in supramolecular catalysis. Chinese Chemical Letters, 2024, 35(4): 109075-. doi: 10.1016/j.cclet.2023.109075
Xiangjun Zhang , Xiaodi Yang , Yan Wang , Zhongping Xu , Sisi Yi , Tao Guo , Yue Liao , Xiyu Tang , Jianxiang Zhang , Ruibing Wang . A supramolecular nanoprodrug for prevention of gallstone formation. Chinese Chemical Letters, 2025, 36(2): 109854-. doi: 10.1016/j.cclet.2024.109854
Xian-Fa Jiang , Chongyun Shao , Zhongwen Ouyang , Zhao-Bo Hu , Zhenxing Wang , You Song . Generating electron spin qubit in metal-organic frameworks via spontaneous hydrolysis. Chinese Chemical Letters, 2024, 35(7): 109011-. doi: 10.1016/j.cclet.2023.109011
Rui Wang , Yang Liang , Julius Rebek Jr. , Yang Yu . Stabilization and detection of labile reaction intermediates in supramolecular containers. Chinese Chemical Letters, 2024, 35(6): 109228-. doi: 10.1016/j.cclet.2023.109228
Xiaoman Dang , Zhiying Wu , Tangxin Xiao , Zhouyu Wang , Leyong Wang . Highly robust supramolecular polymer networks crosslinked by metallacycles. Chinese Chemical Letters, 2024, 35(12): 110208-. doi: 10.1016/j.cclet.2024.110208
Ruotong Wei , Aokun Liu , Jian Kuang , Zhiwen Wang , Lu Yu , Changlin Tian . Probing the dynamic properties in the LLPS process via site-directed spin labeling-electron paramagnetic resonance (SDSL-EPR) spectroscopy. Chinese Chemical Letters, 2025, 36(4): 110029-. doi: 10.1016/j.cclet.2024.110029
Fangzhou Wang , Wentong Gao , Chenghui Li . A weak but inert hindered urethane bond for high-performance dynamic polyurethane polymers. Chinese Chemical Letters, 2024, 35(5): 109305-. doi: 10.1016/j.cclet.2023.109305
Yunkang Tong , Haiqiao Huang , Haolan Li , Mingle Li , Wen Sun , Jianjun Du , Jiangli Fan , Lei Wang , Bin Liu , Xiaoqiang Chen , Xiaojun Peng . Cooperative bond scission by HRP/H2O2 for targeted prodrug activation. Chinese Chemical Letters, 2024, 35(12): 109663-. doi: 10.1016/j.cclet.2024.109663
Junmeng Luo , Qiongqiong Wan , Suming Chen . Chemistry-driven mass spectrometry for structural lipidomics at the C=C bond isomer level. Chinese Chemical Letters, 2025, 36(1): 109836-. doi: 10.1016/j.cclet.2024.109836
Symmetry codes: a 1-x, y, 1-z; b 1-x, 1-y, z; c 1-y, x, 1-z
Inset: fitting of the χMT data by using a regular solution model