Citation: Qian-Xing YUAN, Wei-Min CHEN, Xin-Rong LÜ. Effect of One-Dimensional/Two-Dimensional Composite Carbon Support on Methanol Oxidation Performance of Pd Catalysts[J]. Chinese Journal of Inorganic Chemistry, ;2022, 38(11): 2165-2172. doi: 10.11862/CJIC.2022.232 shu

Effect of One-Dimensional/Two-Dimensional Composite Carbon Support on Methanol Oxidation Performance of Pd Catalysts

School of Environmental and Chemical Engineering, Shenyang Ligong University, Shenyang 110159, China

Corresponding author: Wei-Min CHEN, cwm@sylu.edu.cn
Received Date: 14 February 2022
Revised Date: 28 September 2022

Figures(9)

CNTs-GNPs, hybrid support composed of carbon nanotubes (CNTs) and graphene nanoplates (GNPs) was prepared by a solid phase -liquid phase two-step mixing method. The Pd/CNTs -GNPs catalyst was prepared by depo- sition of Pd nanoparticles on composite carbon support by the ethylene glycol reduction method. The morphologies, compositions, and structures of catalysts were characterized by transmission electron microscopy, X-ray diffraction, and X-ray photoelectron spectroscopy. The performances of catalysts for methanol electrooxidation were investigated by electrochemical methods. The results showed that Pd/CNTs -GNPs(1/4) (the mass fraction of GNPs was 1/4) cata- lyst exhibited a large electrochemical surface area and high performances for methanol electrooxidation, and its peak current density of methanol oxidation was 1.97 times that of the Pd/CNTs catalyst. The high activity of the cata- lyst is attributed to the good dispersion of Pd nanoparticles on the one - dimensional/two - dimensional composite CNTs - GNPs support. The chronoamperometry test showed that Pd catalysts supported on the CNTs - GNPs hybrid support had stronger anti-poisoning abilities as compared to the Pd catalyst supported on a single carbon support.
- catalyst,
- palladium,
- carbon nanotubes,
- graphene nanoplates,
- electrooxidation of methanol
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