Citation: Yan-Xia CHEN, Li-Chuan TAN, Peng WANG, Guang-Song YUAN, Si-Wen FENG, Cui-Juan WANG, Yan TONG, Min XU. Hierarchical Porous Cu⁃BTC Doped with Ni(Ⅱ) for Efficient Removal of Tetracycline from Water[J]. Chinese Journal of Inorganic Chemistry, ;2022, 38(11): 2238-2248. doi: 10.11862/CJIC.2022.223 shu

Hierarchical Porous Cu⁃BTC Doped with Ni(Ⅱ) for Efficient Removal of Tetracycline from Water

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Department of Chemistry and Chemical Engineering, School of Life Science and Bioengineering, Southwest Jiaotong University, Chengdu 610031, China
2.
Chengdu Third People′s Hospital, Chengdu 610031, China

Corresponding author: Cui-Juan WANG, wangcuijuan@swjtu.edu.cn
Received Date: 14 April 2022
Revised Date: 7 September 2022

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In this study, a Ni(Ⅱ)⁃doped hierarchical porous metal⁃organic framework (HP⁃Ni⁃Cu⁃BTC, H₃BTC= benzene⁃1, 3, 5⁃tricarboxylic acid) hierarchical porous metal⁃organic framework was successfully prepared, and applied as an adsorbent for the removal of tetracycline (TC). The Ni(Ⅱ) doping and hierarchical porosity structure significantly increased the adsorption capacity of TC, which was 3.28 times that of microporous Cu⁃BTC. The adsorption kinetics and adsorption isotherm studies demonstrated that chemisorption dominated the adsorption reaction and that the adsorption of TC on HP⁃Ni⁃Cu⁃BTC proceeds through multilayer adsorption on a non⁃homogeneous adsorbent surface. Moreover, in the cycling experiments, there was still 71.45% adsorption efficiency after four times of reuse, indicating that HP⁃Ni⁃Cu⁃BTC had good reusability.
- hierarchical porous metal⁃organic framework,
- metal⁃doped,
- adsorbent,
- tetracycline
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