Citation: Ya-Ping LI, Xiao-Xia ZHANG, Cheng-Qiang QIU, Sui-Jun LIU. A Dual-Function Fluorescence Sensor Based on Cd^Ⅱ Coordination Polymer for Selective Recognition of MnO₄^- and H₂PO₄^-[J]. Chinese Journal of Inorganic Chemistry, ;2022, 38(10): 1948-1958. doi: 10.11862/CJIC.2022.213 shu

A Dual-Function Fluorescence Sensor Based on Cd^Ⅱ Coordination Polymer for Selective Recognition of MnO₄^- and H₂PO₄^-

1.
School of Chemistry and Chemical Engineering, Shanxi University, Taiyuan 030006, China
2.
School of Chemistry and Chemical Engineering, Jiangxi University of Science and Technology, Ganzhou, Jiangxi 341000, China

Corresponding author: Ya-Ping LI, yapingli2007@163.com Sui-Jun LIU, sjliu@jxust.edu.cn
Received Date: 1 February 2022
Revised Date: 23 July 2022

Figures(13)

A 3D Cd^Ⅱ -based coordination polymer with the formula of [Cd₂(DDBD)(NDC)₂]_n (JXUST-16) has been solvothermally synthesized by using 4, 7-bis(1H-1, 2, 4-triazol-1-yl)-2, 1, 3-benzothiadiazole (DDBD) as the primary ligand and 1, 4-naphthalenedicarboxylic acid (H₂NDC) as the auxiliary ligand, and structurally characterized through single crystal X-ray diffraction, powder X-ray diffraction, thermogravimetry analysis, etc. JXUST-16 belongs to the monoclinic I 2/a space group and the adjacent CdⅡ ions are bridged through the carboxylate ligand NDC^2- to form a symmetrical trinuclear CdⅡ cluster, which extends to obtain a 1D chain. The neighboring 1D chains are further linked by DDBD to form a 3D structure. JXUST-16 could keep stable in organic solvents and aqueous solutions with different pH values, and be used as a dual -function fluorescence sensor to identify MnO₄^- and H₂PO₄^- with obvious naked-eye recognition under a 365 nm UV lamp. In addition, MnO₄^- showed a turn-off effect on the fluorescence of JXUST-16 due to the competitive absorption mechanism; while H₂PO₄^- had a certain redshift and turn-on effect on the fluorescence of JXUST-16, which can be explained by the absorbance-caused enhancement mechanism.
- bistriazolyl benzothiadiazole,
- coordination polymer,
- crystal structure,
- anions fluorescence sensing
1. [1]
  Jin J, Xue J J, Liu Y C, Yang G P, Wang Y Y. Recent Progresses in Luminescent Metal-Organic Frameworks (LMOFs) as Sensors for the Detection of Anions and Cations in Aqueous Solution[J]. Dalton Trans., 2021,50(6):1950-1972. doi: 10.1039/D0DT03930F
2. [2]
  Geng Y Y, Li Z, Chen M M, Zhao H G, Zhang L. The Preparation of Graphene Foam by One-Step Reduction and Air-Drying for Oil-Water Separation[J]. J. Sol-Gel Sci. Technol., 2020,94(2):375-383. doi: 10.1007/s10971-020-05240-z
3. [3]
  Sun D T, Peng L, Reeder W S, Moosavi S M, Tiana D, Britt D K, Oveisi E, Queen W L. Rapid, Selective Heavy Metal Removal from Water by a Metal-Organic Framework/Polydopamine Composite[J]. ACS Cent. Sci., 2018,4(3):349-356. doi: 10.1021/acscentsci.7b00605
4. [4]
  Liu G C, Li Y, Chi J, Xu N, Wang X L, Lin H Y, Chen Y Q. Multi-Functional Fluorescent Responses of Cobalt Complexes Derived from Functionalized Amide-Bridged Ligand[J]. Dyes Pigment., 2020,174108064. doi: 10.1016/j.dyepig.2019.108064
5. [5]
  Ding B, Liu S X, Cheng Y, Guo C, Wu X X, Guo J H, Liu Y Y, Li Y. Heterometallic Alkaline Earth-Lanthanide Ba^Ⅱ-La^Ⅲ Microporous Metal-Organic Framework as Bifunctional Luminescent Probes of Al3+ and MnO₄^-[J]. Inorg. Chem., 2016,55(9):4391-4402. doi: 10.1021/acs.inorgchem.6b00111
6. [6]
  Sun P P, Zhang S S, Xiang Z Y, Zhao T, Sun D, Zhang G P, Chen M J, Guo K K, Xin X. Photoluminescent Sensing Vesicle Platform Self-Assembled by Polyoxometalate and Ionic-Liquid-Type Imidazolium Gemini Surfactants for the Detection of Cr³⁺ and MnO₄^- Ions[J]. J. Colloid Interface Sci., 2019,547:60-68. doi: 10.1016/j.jcis.2019.03.085
7. [7]
  Jia W, Ren S M, Xia H C, Zhang C, Zhang J F. An Ultra-Stable Cd Coordination Polymer Based on Double-Chelated Ligand for Efficient Dual-Response of TNP and MnO₄^-[J]. Sens. Actuators B-Chem., 2020,317128230. doi: 10.1016/j.snb.2020.128230
8. [8]
  Cao Q Y, Wang Z C, Li M, Liu J H. A Novel Anthracene-Appended Ttriazolium for Fluorescent Sensing to H₂PO₄^-[J]. Tetrahedron Lett., 2013,54(30):3933-3936. doi: 10.1016/j.tetlet.2013.05.033
9. [9]
  Dasgupta P K, Maleki F. Ion Exchange Membranes in Ion Chromatography and Related Applications[J]. Talanta, 2019,204:89-137. doi: 10.1016/j.talanta.2019.05.077
10. [10]
  Zheng D D, Zhang Y, Wang L, Kurmoo M, Zeng M H. A Rod-Spacer Mixed Ligands MOF[Mn₃(HCOO)₂(D-cam)₂(DMF)₂]_n as Coating Material for Gas Chromatography Capillary Column[J]. Inorg. Chem. Commun., 2017,82:34-38. doi: 10.1016/j.inoche.2017.05.013
11. [11]
  Guo H J, Seto T, Geng T, Zou B, Li G S, Uwatoko Y, Tang Z B, Li Z B, Wang Y H. New Phenomena of Photo-Luminescence and Persistent Luminescence of a Eu²⁺, Tb³⁺ Codoped Ca₆BaP₄O₁₇ Phosphor Under High Hydrostatic Pressure[J]. Dalton Trans., 2020,49(24):8056-8059. doi: 10.1039/D0DT00947D
12. [12]
  You T Y, Yang X R, Wang E K. Determination of Sulfadiazine and Sulfamethoxazole by Capillary Electrophoresis with End-Column Electrochemical Detection[J]. Analyst, 1998,123(24):2357-2360.
13. [13]
  Kim D C, Dunn R C. Integrating Whispering Gallery Mode Refractive Index Sensing with Capillary Electrophoresis Separations Using Phase Sensitive Detection[J]. Anal. Chem., 2016,88(2):1426-1433. doi: 10.1021/acs.analchem.5b04187
14. [14]
  de Souza S S, Rodrigues J L, Souza V C D, Barbosa F. A Fast Sample Preparation Procedure for Mercury Speciation in Hair Samples by High-Performance Liquid Chromatography Coupled to ICP-MS[J]. J. Anal. At. Spectrom., 2010,25(1):79-83. doi: 10.1039/B911696F
15. [15]
  Holá M, Salajková Z, Hrdlička A, Pořízka P, Novotný K, Čelko L, Šperka P, Prochazka D, Novotný J, Modlitbová P, Kanický V, Kaiser J. Feasibility of Nanoparticle-Enhanced Laser Ablation Inductively Coupled Plasma Mass Spectrometry[J]. Anal. Chem., 2018,90(20):11820-11826. doi: 10.1021/acs.analchem.8b01197
16. [16]
  Teuma-Castelletti R, Beauchemin D. Direct Analysis of Wheat Flour by Inductively Coupled Plasma Mass Spectrometry with Flow Injection, Slurry Nebulization, and a Mixed-Gas Plasma[J]. J. Anal. At. Spectrom., 2020,35(12):2820-2825. doi: 10.1039/D0JA00275E
17. [17]
  Tian X M, Yao S L, Wu J, Xie H M, Zheng T F, Jiang X J, Wu Y Q, Mao J G, Liu S J. Two Benzothiadiazole-Based Fluorescent Sensors for Selective Detection of Cu²⁺ and OH^- Ions[J]. Polyhedron, 2019,171:523-529. doi: 10.1016/j.poly.2019.08.002
18. [18]
  Shen M, Rodríguez-López J, Huang J, Liu Q, Zhu X H, Bard A J. Electrochemistry and Electrogenerated Chemiluminescence of Dithienylbenzothiadiazole Derivative. Differential Reactivity of Donor and Acceptor Groups and Simulations of Radical Cation-Anion and Dication-Radical Anion Annihilations[J]. J. Am. Chem. Soc., 2010,132(38):13453-13461. doi: 10.1021/ja105282u
19. [19]
  Voitekhovich S V, Grigoriev Y V, Lyakhov A S, Matulis V E, Ivashkevich L S, Bogomyakov A S, Lavrenova L G, Ivashkevich O A. 1-(1, 2, 4-Triazol-3-yl)-1H-tetrazoles and Their Complexation with Copper Chloride[J]. Polyhedron, 2020,176114299. doi: 10.1016/j.poly.2019.114299
20. [20]
  Cai H, Zou Y L, Li Y, Lian X X, Tong X Q, Li J G. Structural Diversity and Magnetic Properties of Two Metal-Organic Polymers Based on Bifunctional Ligand of 2, 5-Di(1H-1, 2, 4-triazol-1-yl)terephthalic Acid[J]. Inorg. Chem. Commun., 2019,107107499. doi: 10.1016/j.inoche.2019.107499
21. [21]
  Li H Y, Yan B, Ma H X, Sun Z Y, Ma Y J, Zhang Z F. Crystal Structure, Thermodynamic Properties and Detonation Characterization of Bis(5-amino-1, 2, 4-triazol-3-yl)methane[J]. Acta Crystallogr. Sect. C, 2020,C76:64-68.
22. [22]
  Shi W J, Li Y Z, Hu Q X, Wang G D, Hou L, Wang Y Y. New scu Topological MOF Based on Azolyl-Carboxyl Bifunctional Linker: Gas Adsorption and Luminescence Properties[J]. J. Solid State Chem., 2020,283121170. doi: 10.1016/j.jssc.2019.121170
23. [23]
  Zhang H K, Wang X, Wang S, Wang X D. catena-Poly[[bis(nitrato-κO)cadmium]-bis[μ-1, 3-bis[(1H-1, 2, 4-triazol-1-yl)-methyl]benzene-κ²N⁴∶N^4']][J]. Acta Crystallogr. Sect. E, 2012,E68m856.
24. [24]
  Qiu C Q, Li L Q, Yao S L, Liu S J, Xu H, Zheng T F. Two Benzothiadiazole-Based Compounds as Multifunctional Fluorescent Sensors for Detection of Organic Amines and Anions[J]. Polyhedron, 2021,199115100. doi: 10.1016/j.poly.2021.115100
25. [25]
  Llunell M, Casanova D, Cirera J. SHAPE, Version 2.1, University of Barcelona, Spain, 2013.
26. [26]
  Wu L H, Yao S L, Li J, Xu H, Zheng T F, Liu S J, Chen J L, Wen H R. A Novel CdⅡ-Based Metal-Organic Framework as a Multi-responsive Luminescent Sensor for Fe3+, MnO₄^-, Cr₂O₇^2-, Salicylaldehyde and Ethylenediamine Detection with High Selectivity and Sensitivity[J]. CrystEngComm, 2021,23(2):482-491. doi: 10.1039/D0CE01575J
27. [27]
  Li L, Deng Z Y, Xie X, Zou J Y, You S Y, Chen K H, Le J F. A Luminescent Zinc(Ⅱ) Coordination Polymer as a Highly Selective and Sensitive Chemosensor for Fe(Ⅲ) Cation and Cr(Ⅳ) Anions Detection in Aqueous Solution[J]. Inorg. Chim. Acta, 2020,513119940. doi: 10.1016/j.ica.2020.119940
28. [28]
  Abdollahi N, Morsali A. Highly Sensitive Fluorescent Metal-Organic Framework as a Selective Sensor of Mn^Ⅶ and Cr^Ⅵ Anions (MnO₄^-/ Cr₂O₇^2-/CrO ₄^2-) in Aqueous Solutions[J]. Anal. Chim. Acta, 2019,1064:119-125. doi: 10.1016/j.aca.2019.02.061
29. [29]
  Zhao Y, Xu X Y, Qiu L, Kang X J, Wen L L, Zhang B G. Metal-Organic Frameworks Constructed from a New Thiophene-Functionalized Dicarboxylate: Luminescence Sensing and Pesticide Removal[J]. ACS Appl. Mater. Interfaces, 2017,9(17):15164-15175. doi: 10.1021/acsami.6b11797
30. [30]
  Wang S L, Hu F L, Zhou J Y, Zhou Y, Huang Q, Lang J P. Rigidity versus Flexibility of Ligands in the Assembly of Entangled Coordination Polymers Based on Bi-and Tetra Carboxylates and N-Donor Ligands[J]. Cryst. Growth Des., 2015,15(8):4087-4097. doi: 10.1021/acs.cgd.5b00642
31. [31]
  Zhang D W, Cochrane J R, Martinez A, Gao G H. Recent Advances in H₂ PO₄^- Fluorescent Sensors[J]. RSC Adv., 2014,4(56):29735-29749. doi: 10.1039/C4RA02828G
32. [32]
  Tian X M, Yao S L, Qiu C Q, Zheng T F, Chen Y Q, Huang H P, Chen J L, Liu S J, Wen H R. Turn-On Luminescent Sensor toward Fe³⁺, Cr³⁺, and Al³⁺ Based on a Co(Ⅱ) Metal-Organic Framework with Open Functional Sites[J]. Inorg. Chem., 2020,59(5):2803-2810. doi: 10.1021/acs.inorgchem.9b03152
33. [33]
  Wang M, Guo L, Cao D P. Metal-Organic Framework as Luminescence Turn-On Sensor for Selective Detection of Metal Ions: Absorbance Caused Enhancement Mechanism[J]. Sens. Actuators B-Chem., 2018,256:839-845. doi: 10.1016/j.snb.2017.10.016
34. [34]
  Pramanik S, Hu Z C, Zhang X, Zheng C, Kelly S, Li J. A Systematic Study of Fluorescence-Based Detection of Nitroexplosives and Other Aromatics in the Vapor Phase by Microporous Metal-Organic Frameworks[J]. Chem. Eur. J., 2013,19(47):15964-15971. doi: 10.1002/chem.201301194
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A Dual-Function Fluorescence Sensor Based on CdⅡ Coordination Polymer for Selective Recognition of MnO4- and H2PO4-

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A Dual-Function Fluorescence Sensor Based on Cd^Ⅱ Coordination Polymer for Selective Recognition of MnO₄^- and H₂PO₄^-