Citation: You-Zhu YU, Yan-Ru ZHANG, Yu-Hua GUO, Zhong-Yuan ZHOU, Li-Guo YANG, Jia-Lin LI, Li-Yue FANG, Kuan-Kuan QIAO. Syntheses, Structure-Regulation, and Photoelectric Properties of 2-Pyridinecarbaldehyde Oxime Assembled Titanium Oxo Clusters[J]. Chinese Journal of Inorganic Chemistry, ;2022, 38(11): 2299-2307. doi: 10.11862/CJIC.2022.205 shu

Syntheses, Structure-Regulation, and Photoelectric Properties of 2-Pyridinecarbaldehyde Oxime Assembled Titanium Oxo Clusters

1.
School of Chemical and Environmental Engineering, Anyang Institute of Technology, Anyang, Henan 455000, China
2.
School of Chemistry and Material Science, Shanxi Normal University, Taiyuan 030000, China

Corresponding author: You-Zhu YU, 119yyz@163.com
Received Date: 1 May 2022
Revised Date: 1 August 2022

Figures(7)

[Ti₂(μ₂-O)(Pycox)₂(OⁱPr)₄] (1) was solvothermally synthesized by the reaction of 2-pyridinecarbaldehyde oxime (Hpycox) and Ti(OⁱPr)₄ in a simple and general approach. Interestingly, by analyzing the structure of 1, diphenylphosphinic acid and phenylphosphonic acid were selected respectively to regulate the structure of 1, and [Ti₃(μ₂-O)₂(Pycox)₂(Ph₂PO₂)₂(OⁱPr)₄] (2) and [Ti₆(μ₂-O)₂(μ₃-O)₂(Pycox) ₂ (PhPO₃)₄(OⁱPr) ₆]·2CH₃CN (3) were successfully obtained. Moreover, their light absorption behaviors, band gaps, and photocurrent responses were also investigated. The band gaps of complexes 1-3 were 2.89, 3.00, and 2.87 eV, respectively. Among the three complexes, complex 2 exhibited the largest photocurrent density with the value of 0.10 μA·cm^-2.
- titanium oxo clusters,
- 2-pyridinecarbaldehyde oxime,
- structure regulation,
- phosphonic acid
1. [1]
  Chen X, Mao S S. Titanium Dioxide Nanomaterials: Synthesis, Properties, Modifications, and Applications[J]. Chem. Rev., 2007,107(7):2891-2959. doi: 10.1021/cr0500535
2. [2]
  Kongkanand A, Tvrdy K, Takechi K, Kuno M, Kamat P V. Quantum Dot Solar Cells. Tuning Photoresponse through Size and Shape Control of CdSe-TiO₂ Architecture[J]. J. Am. Chem. Soc., 2008,130(12):4007-4015.
3. [3]
  Schneider J, Matsuoka M, Takeuchi M, Zhang J, Horiuchi Y, Anpo M, Bahnemann D W. Understanding TiO₂ Photocatalysis: Mechanisms and Materials[J]. Chem. Rev., 2014,114(19):9919-9986.
4. [4]
  Chen X, Liu L, Peter Y Y, Mao S S. Increasing Solar Absorption for Photocatalysis with Black Hydrogenated Titanium Dioxide Nanocrystals[J]. Science, 2011,331(6018):746-750. doi: 10.1126/science.1200448
5. [5]
  Sun S C, Gao P, Yang Y R, Yang P P, Chen Y J, Wang Y B. N-Doped TiO₂ Nanobelts with Coexposed (001) and (101) Facets and Their Highly Efficient Visible-Light-Driven Photocatalytic Hydrogen Production[J]. ACS Appl. Mater. Interfaces, 2016,8(28):18126-18131. doi: 10.1021/acsami.6b05244
6. [6]
  Wu M C, Hiltunen J, Sápi A S, Avila A, Larsson W, Liao H C, Huuhtanen M, Tóth G Z, Shchukarev A, Laufe N M. Nitrogen-Doped Anatase Nanofibers Decorated with Noble Metal Nanoparticles for Photocatalytic Production of Hydrogen[J]. ACS Nano, 2011,5(6):5025-5030. doi: 10.1021/nn201111j
7. [7]
  Park J H, Kim S, Bard A J. Novel Carbon-Doped TiO₂ Nanotube Arrays with High Aspect Ratios for Efficient Solar Water Splitting[J]. Nano Lett., 2006,6(1):24-28. doi: 10.1021/nl051807y
8. [8]
  Yang C Y, Wang Z, Lin T Q, Yin H, Lü X J, Wan D Y, Xu T, Zheng C, Lin J H, Huang F Q, Xie X M, Jiang M H. Core-Shell Nanostructured "Black" Rutile Titania as Excellent Catalyst for Hydrogen Production Enhanced by Sulfur Doping[J]. J. Am. Chem. Soc., 2013,135(47):17831-17838. doi: 10.1021/ja4076748
9. [9]
  Narayanam N, Chintakrinda K, Fang W H, Kang Y, Zhang L, Zhang J. Azole Functionalized Polyoxo-Titanium Clusters With Sunlight-Driven Dye Degradation Applications: Synthesis, Structure, and Photocatalytic Studies[J]. Inorg. Chem., 2016,55(20):10294-10301. doi: 10.1021/acs.inorgchem.6b01551
10. [10]
  Fan X, Fu H, Zhang L, Zhang J. Pyrazole-thermal Synthesis: New Approach towards N-Rich Titanium-Oxo Clusters with Photochromic Behaviors[J]. Dalton Trans., 2019,48(23):8049-8052. doi: 10.1039/C9DT01628G
11. [11]
  Fan X, Wang J H, Wu K F, Zhang L, Zhang J. Isomerism in Titanium-Oxo Clusters: Molecular Anatase Model with Atomic Structure and Improved Photocatalytic Activity[J]. Angew. Chem. Int. Ed., 2019,131(5):1334-1337. doi: 10.1002/ange.201809961
12. [12]
  Narayanam N, Fang W H, Chintakrinda K, Zhang L, Zhang J. Deep Eutectic-Solvothermal Synthesis of Titanium-Oxo Clusters Protected by π-Conjugated Chromophores[J]. Chem. Commun., 2017,53(57):8078-8080. doi: 10.1039/C7CC04388K
13. [13]
  Gao M Y, Fang W H, Wen T, Zhang L, Zhang J. Connecting Titanium-Oxo Clusters by Nitrogen Heterocyclic Ligands to Produce Multiple Cluster Series with Photocatalytic H₂ Evolution Activities[J]. Cryst. Growth Des., 2017,17(7):3592-3595. doi: 10.1021/acs.cgd.7b00413
14. [14]
  Cui X, Zhang F Q, Li X, Hou J J, Li H, Zhang X M. Polyoxotitanate Molecular Cage Featuring Four Types of Ethylenediamines: Formation Mechanism Insight from Host-Guest Interaction and Crystallo-graphic Study[J]. Inorg. Chem., 2021,60(12):9174-9180. doi: 10.1021/acs.inorgchem.1c01189
15. [15]
  Yu Y Z, Zhang Y R, Geng C H, Sun L, Guo Y, Feng Y R, Wang Y X, Zhang X M. Precise and Wide-Ranged Band-Gap Tuning of Ti₆-Core-Based Titanium Oxo Clusters by the Type and Number of Chromophore Ligands[J]. Inorg. Chem., 2019,58(24):16785-16791. doi: 10.1021/acs.inorgchem.9b02951
16. [16]
  Cui L N, Liu P Y, Yang L, Su X P, Zhu Q Y, Dai J. A Series of Ti₆-Oxo-Clusters Anchored with Arylamine Dyes, Effect of Dye Structures on Photocurrent Responses[J]. Chem. Asian J., 2019,14(18):3098-3204.
17. [17]
  Zhu Q Y, Dai J. Titanium Oxo/Alkoxyl Clusters Anchored with Photoactive Ligands[J]. Coord. Chem. Rev., 2020213664.
18. [18]
  Benedict J B, Coppens P. The Crystalline Nanocluster Phase as a Medium for Structural and Spectroscopic Studies of Light Absorption Of Photosensitizer Dyes On Semiconductor Surfaces[J]. J. Am. Chem. Soc., 2010,132(9):2938-2944. doi: 10.1021/ja909600w
19. [19]
  Guo Y H, Yu Y Z, Niu Y S, Wang Z, Shi W Y, Wu X L. Solvothermal Synthesis, Crystal Structure and Photocurrent Property of a Ti₆-Core-Based Titanium Oxo Cluster[J]. Chin. J. Struct. Chem., 2021,40(3):357-362.
20. [20]
  Yu Y Z, Guo Y, Zhang Y R, Liu M M, Feng Y R, Geng C H, Zhang X M. A Series of Silver Doped Butterfly-like Ti₈Ag₂ Clusters with Two Ag Ions Panelled on a Ti₈ Surface[J]. Dalton Trans., 2019,48(35):13423-13423. doi: 10.1039/C9DT02508A
21. [21]
  Mirzaee M, Norouzi M, Faghani M, Amini M M, Khavasi H R. Synthesis, Characterization and Molecular Structure of Titanium Alkoxide Complexes with Aromatic Oxime Ligands[J]. Transit. Met. Chem., 2014,39(1):55-62. doi: 10.1007/s11243-013-9773-x
22. [22]
  Liu X X, Chen G H, Tao J, Zhang J, Zhang L. Synthesis, Structure, and Light Absorption Behaviors of Prismatic Titanium-Oxo Clusters Containing Lacunary Lindqvist-like Species[J]. Inorg. Chem., 2022,61(3):1385-1390. doi: 10.1021/acs.inorgchem.1c02891
23. [23]
  Said A, Gao C, Liu C, Niu H, Wang D, Liu Y, Du L, Tung C H, Wang Y. A Mesoporous Lead-Doped Titanium Oxide Complex with High Performance and Recyclability in I₂ Uptake and Photocatalysis[J]. Inorg. Chem., 2022,61(1):586-596. doi: 10.1021/acs.inorgchem.1c03263
24. [24]
  Han E M, Yu W D, Yan J, Yi X Y, Liu C. Metal-Directed Self-Assembly of {Ti₈L₂} Cluster-Based Coordination Polymers with Enhanced Photocatalytic Alcohol Oxidation Activity[J]. Inorg. Chem., 2022,61(2):923-930. doi: 10.1021/acs.inorgchem.1c02842
25. [25]
  Chen R, Hong Z F, Zhao Y R, Zheng H, Li G J, Zhang Q C, Kong X J, Long L S, Zheng L S. Ligand-Dependent Luminescence Properties of Lanthanide-Titanium Oxo Clusters[J]. Inorg. Chem., 2019,58(22):15008-15012. doi: 10.1021/acs.inorgchem.9b02112
26. [26]
  Li N, Zhao S Q, Ding X R, Hu X Y, Zhang Q K, Zou G D, Fan Y. 8-Hydroxyquinoline Functionalized Titanium-Oxo Clusters for Visible-Light-Driven Photocatalytic Oxidative Desulfurization[J]. Inorg. Chem. Commun., 2021,130108681. doi: 10.1016/j.inoche.2021.108681
27. [27]
  Zhu B C, Zhang L, Zhang J. p-Arsanilic Acid Stabilizing Titanium-Oxo Clusters with Various Core Structures and Light Absorption Behaviours[J]. Inorg. Chem. Commun., 2017,86:14-17. doi: 10.1016/j.inoche.2017.09.015
28. [28]
  WU N N, ZHAO M M, LIU S J, LIU B. Preparation, Crystal Structure and Characterization of One-Dimensional Europium-Doped Titanium-Oxo Cluster of Ti₄Eu₂O₄(OOCC₆H₅)₁₄[J]. Chinese J. Inorg. Chem., 2020,36(11):2080-2086. doi: 10.11862/CJIC.2020.231
29. [29]
  Zhang N, Guo Y H, Yu Y Z, Wang Z, Niu Y S, Wu X L. Solvothermal Synthesis, Crystal Structure and Luminescence Property of a 1D Silver Coordination Polymer[J]. Chin. J. Struct. Chem., 2020,39(11):2009-2015.
30. [30]
  Wendlandt W W, Hecht H G. Reflectance Spectroscopy: Vol. 21. John Wiley & Sons, 1966.
31. [31]
  Liu J J, Li N, Sun J W, Liu J, Dong L Z, Yao S J, Zhang L, Xin Z F, Shi J W, Wang J X, Li S L, Lan Y Q. Ferrocene-Functionalized Polyoxo-Titanium Cluster for CO₂ Photoreduction[J]. ACS Catal., 2021:4510-4519.
32. [32]
  Li N, Liu J J, Sun J W, Dong B X, Dong L Z, Yao S J, Xin Z, Li S L, Lan Y Q. Calix[8]arene-Constructed Stable Polyoxo-Titanium Clusters for Efficient CO₂ Photoreduction[J]. Green Chem., 2020,22(16):5325-5332. doi: 10.1039/D0GC01497D
33. [33]
  Wang C, Liu C, Li L J, Sun Z M. Synthesis, Crystal Structures, and Photochemical Properties of a Family of Heterometallic Titanium Oxo Clusters[J]. Inorg. Chem., 2019,58(9):6312-6319. doi: 10.1021/acs.inorgchem.9b00508
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