Citation: Dong-Bin CHEN, Jing-Ya DING, Guo-Lin ZHANG, Lan FAN, Lin SUN, Feng CHENG, Yong-Long LIU, Yi-Ke CHEN, Qi XU. Manganese Supported Nitrogen-Doped Graphene and Performance of Catalytic Decomposition High-Humidity Ozone[J]. Chinese Journal of Inorganic Chemistry, ;2022, 38(10): 2072-2082. doi: 10.11862/CJIC.2022.203 shu

Manganese Supported Nitrogen-Doped Graphene and Performance of Catalytic Decomposition High-Humidity Ozone

Dong-Bin CHEN ¹ ,
Jing-Ya DING ¹ ,
Guo-Lin ZHANG ² ,
Lan FAN ³ ,
Lin SUN ⁴ ,
Feng CHENG ^4,, ,
Yong-Long LIU ¹ ,
Yi-Ke CHEN ¹ ,
Qi XU ^1,,

1.
School of Chemistry and Chemical Engineering, Yancheng Institute of Technology, Yancheng, Jiangsu 224051, China
2.
School of Mechanical Engineering, Yancheng Institute of Technology, Yancheng, Jiangsu 224051, China
3.
Yancheng Lanfeng Environmental Engineering Technology Co., Ltd., Yancheng 224051, China
4.
Key Laboratory for Advanced Technology in Environmental Protection of Jiangsu Province, Yancheng Institute of Technology, Yancheng, Jiangsu 224051, China

Corresponding author: Feng CHENG, chf@nju.edu.cn Qi XU, ycxqsteve@163.com
Received Date: 27 April 2022
Revised Date: 14 August 2022

Figures(12)

Nitrogen - doped graphene (NG) was synthesized by thermal annealing of graphene oxide (GO) using melamine as the nitrogen source, and NG-loaded manganese (Mn/NG) was prepared using the immersion precipitation method. At 80% relative humidity (RH) and an initial ozone concentration of 85.7 mg·m^-3, the decomposition rate of ozone remained above 80% after 24 h of reaction. Under the low RH environment, the catalytic activity can be restored to the initial state again. The nitrogen doping not only created structural defects for the catalyst, but also the lone pair electrons of nitrogen atoms increased the electron density of oxygen vacancies, reduced the adsorption energy of water molecules, and improved the moisture resistance of the catalyst.
- nitrogen-doped graphene,
- ozone decomposition,
- manganese
1. [1]
  Batakliev T, Georgiev V, Anachkov M, Rakovsky S, Zaikov G E. Ozone Decomposition[J]. Interdiscip Toxicol., 2014,7(2):47-59. doi: 10.2478/intox-2014-0008
2. [2]
  Namdari M, Lee C S, Haghighat F. Active Ozone Removal Technologies for a Safe Indoor Environment: A Comprehensive Review[J]. Build. Sci., 2021,187107370.
3. [3]
  ZHANG L H, GAO W W, CHEN Z C, ZHOU J, WANG X M, ZHANG H F. CoAl₂O₄/Ceramic Honeycomb Catalyst: Preparation and Performance on Catalytic Ozonation in Wastewater Treatment[J]. Chinese J. Inorg. Chem., 2017,33(6):985-992.
4. [4]
  Shao M, Zhang Y H, Zeng L M, Tang X Y, Zhang J, Zhong L J, Wang B G. Ground-Level Ozone in the Pearl River Delta and the Roles of VOC and NO x in Its Production[J]. J. Environ. Manage., 2009,90(1):512-518. doi: 10.1016/j.jenvman.2007.12.008
5. [5]
  Wolkoff P. Indoor Air Pollutants in Office Environments: Assessment of Comfort, Health, and Performance[J]. Int. J. Hyg. Environ. Health, 2013,216(4):371-394. doi: 10.1016/j.ijheh.2012.08.001
6. [6]
  Tao Y B, Huang W, Huang X L, Zhong L J, Lu S E, Li Y, Dai L Z, Zhang Y H, Zhu T. Estimated Acute Effects of Ambient Ozone and Nitrogen Dioxide on Mortality in the Pearl River Delta of Southern China[J]. Environ. Health Perspect., 2012,120(3):393-398. doi: 10.1289/ehp.1103715
7. [7]
  Gao W, Tie X X, Xu J M, Huang R J, Mao X Q, Zhou G Q, Chang L Y. Long-Term Trend of O₃ in a Mega City (Shanghai), China: Characteristics, Causes, and Interactions with Precursors[J]. Sci. Total Environ., 2017,603:425-433.
8. [8]
  ZHOU L N, CHEN Y Q, REN C J, GONG M C. Pd/MnOx+Pd/γ-Al₂O₃ Monolith Catalysts for Ground-Level Ozone Decomposition[J]. Chinese J. Inorg. Chem., 2013,29(11):2363-2369.
9. [9]
  Kotelnikov S N, Stepanov E V. Role of Aqueous Aerosols in Ozone Decomposition in the Near-Surface Atmosphere[J]. Bull. Lebedev Phys. Inst., 2019,46(9):284-288. doi: 10.3103/S1068335619090045
10. [10]
  Hellen H, Kuronen P, Hakola H. Heated Stainless Steel Tube for Ozone Removal in the Ambient Air Measurements of Mono - and Sesquiterpenes[J]. Atmos. Environ., 2012,57:35-40. doi: 10.1016/j.atmosenv.2012.04.019
11. [11]
  Schumacher , Joachim H. The Mechanism of the Photochemical Decomposition of Ozone[J]. J. Am. Chem. Soc., 1930,52(6):2377-2391. doi: 10.1021/ja01369a026
12. [12]
  SUN Y H, ZHANG M, YANG J J. Preparationand Characterization of Bimetal Core - Shell Structure Supported Au@Ag/TiO₂ Catalyst[J]. Chinese J.Inorg. Chem., 2009,25(11):1965-1970. doi: 10.3321/j.issn:1001-4861.2009.11.014
13. [13]
  Brodu N, Manero M H, Andriantsiferana C, Pic J S, Valdes H. Role of Lewis Acid Sites of ZSM-5 Zeolite on Gaseous Ozone Abatement[J]. Chem. Eng. J., 2013,231:281-286. doi: 10.1016/j.cej.2013.07.002
14. [14]
  Wang H, Rassu P, Wang X, Li H W, Wang X R, Wang X Q, Feng X, Yin A X, Li P F, Jin X, Chen S L, Ma X J, Wang B. An Iron-Containing Metal-Organic Framework as a Highly Efficient Catalyst for Ozone Decomposition[J]. Angew. Chem. Int. Ed., 2018,57(50):16416-16420. doi: 10.1002/anie.201810268
15. [15]
  Jia J B, Zhang P Y, Chen L. The Effect of Morphology of α-Mno₂ on Catalytic Decomposition of Gaseous Ozone[J]. Catal. Sci. Technol., 2016,6(15):5841-5847. doi: 10.1039/C6CY00301J
16. [16]
  Xu Z H, Yang W H, Si W Z, Chen J J, Peng Y, Li J H. A Novel γlike MnO₂ Catalyst for Ozone Decomposition in High Humidity Conditions[J]. J. Hazard. Mater., 2021,420126641. doi: 10.1016/j.jhazmat.2021.126641
17. [17]
  Liu Y, Yang W J, Zhang P Y, Zhang J Y. Nitric Acid-Treated Birnessite- Type MnO₂: An Efficient and Hydrophobic Material for Humid Ozone Decomposition[J]. Appl. Surf. Sci., 2018,422:640-649.
18. [18]
  Zhu G X, Zhu W, Lou Y, Ma J, Yao W Q, Zong R L, Zhu Y F. Encapsulate α-MnO₂ Nanofiber within Graphene Layer to Tune Surface Electronic Structure for Efficient Ozone Decomposition[J]. Nat. Commun., 2021,12(1)4152. doi: 10.1038/s41467-021-24424-x
19. [19]
  Zhang L, Yang J W, Wang A Q, Chai S H, Guan J, Nie L F, Fan G J, Han N, Chen Y F. High Performance Ozone Decomposition Spinel (Mn, Co)₃O₄ Catalyst Accelerating the Rate-Determining Step[J]. Appl. Catal. B-Environ., 2022,30120957.
20. [20]
  Yu Y, Ji J, Li K, Huang H B, Shrestha R P, Oanh N T K, Winijkul E, Deng J G. Activated Carbon Supported MnO Nanoparticles for Efficient Ozone Decomposition at Room Temperature[J]. Catal. Today, 2020,355:573-579. doi: 10.1016/j.cattod.2019.05.063
21. [21]
  Ma J Z, Wang C X, He H. Transition Metal Doped Cryptomelane- Type Manganese Oxide Catalysts for Ozone Decomposition[J]. Appl. Catal. B-Environ., 2017,201:503-510. doi: 10.1016/j.apcatb.2016.08.050
22. [22]
  Dato A, Lee Z, Jeon K J, Erni R, Radmilovic V, Richardson T J, Frenklach M. Clean and Highly Ordered Graphene Synthesized in the Gas Phase[J]. Chem. Commun., 2009,40:6095-6097.
23. [23]
  Sheng Z H, Shao L, Chen J J, Bao W J, Wang F B, Xia X H. Catalyst- Free Synthesis of Nitrogen-Doped Graphene via Thermal Annealing Graphite Oxide with Melamine and Its Excellent Electrocatalysis[J]. ACS Nano, 2011,5(6):4350-4358. doi: 10.1021/nn103584t
24. [24]
  Pieta I S, Rathi A, Pieta P, Nowakowski R, Holdynski M, Pisarek M, Kaminska A, Gawande M B, Zboril R. Electrocatalytic Methanol Oxidation over Cu, Ni and Bimetallic Cu-Ni nanoparticles Supported on Graphitic Carbon Nitride[J]. Appl. Catal. B -Environ., 2019,244:272-283. doi: 10.1016/j.apcatb.2018.10.072
25. [25]
  Li X L, Wang H L, Robinson J T, Sanchez H, Diankov G, Dai H J. Simultaneous Nitrogen Doping and Reduction of Graphene Oxide[J]. J. Am. Chem. Soc., 2009,131(43):15939-15944. doi: 10.1021/ja907098f
26. [26]
  Sun Q L, Tang M, Hendriksen P V, Chen B. Biotemplated Fabrication of a 3D Hierarchical Structure of Magnetic ZnFe₂O₄/MgAl-LDH for Efficient Elimination of Dye from Water[J]. J. Alloy. Compd., 2020,829154552. doi: 10.1016/j.jallcom.2020.154552
27. [27]
  Liu Z, Guo R T, Meng J S, Liu X, Wang X P, Li Q, Mai L Q. Facile Electrospinning Formation of Carbon-Confined Metal Oxide Cubein-Tube Nanostructures for Stable Lithium Storage[J]. Chem. Commun., 2017,53(59):8284-8287. doi: 10.1039/C7CC03727A
28. [28]
  Wang Y, Shao Y Y, Matson D W, Li J H, Lin Y H. Nitrogen-Doped Graphene and Its Application in Electrochemical Biosensing[J]. ACS Nano, 2010,4(4):1790-1798. doi: 10.1021/nn100315s
29. [29]
  Gong K P, Du F, Xia Z H, Durstock M, Dai L M. Nitrogen-Doped Carbon Nanotube Arrays with High Electrocatalytic Activity for Oxygen Reduction[J]. Science, 2009,323(5915):760-764. doi: 10.1126/science.1168049
30. [30]
  Yang H, Gong L Q, Wang H M, Dong C L, Wa ng, J L, Qi K, Liu H F, Guo X P, Xia B Y. Preparation of Nickel-Iron Hydroxides by Microorganism Corrosion for Efficient Oxygen Evolution[J]. Nat. Commun., 2020,115075. doi: 10.1038/s41467-020-18891-x
31. [31]
  Wang H, Peng B, Zhang R D, Chen H X, Wei Y. Synergies of Mn Oxidative Ability and ZSM-5 Acidity for 1, 2-Dichloroethane Catalytic Elimination[J]. Appl. Catal. B-Environ., 2020,276118922. doi: 10.1016/j.apcatb.2020.118922
32. [32]
  Liu S L, Ji J, Yu Y, Huang H B. Facile Synthesis of Amorphous Mesoporous Manganese Oxides for Efficient Catalytic Decomposition of Ozone[J]. Catal. Sci. Technol., 2018,8:4264-4273. doi: 10.1039/C8CY01111G
33. [33]
  Liu J, Ke J, Li D G, Sun H Q, Liang P, Duan X G, Tian W J, Tade M O, Liu S M, Wang S B. Oxygen Vacancies in Shape Controlled Cu₂O/ Reduced Graphene Oxide/In₂O₃ Hybrid for Promoted Photocatalytic Water Oxidation and Degradation of Environmental Pollutants[J]. ACS Appl. Mater. Interfaces, 2017,9(13):11678-11688. doi: 10.1021/acsami.7b01605
34. [34]
  Yang W J, Ren J N, Li J J, Zhang H W, Ma K, Wang Q W, Gao Z Y, Wu C C, Gates I D. A Novel Fe-Co Double-Atom Catalyst with High Low-Temperature Activity and Strong Water-Resistant for O₃ Decomposition: A Theoretical Exploration[J]. J. Hazard. Mater., 2022,421126639. doi: 10.1016/j.jhazmat.2021.126639
35. [35]
  Yang W J, Gao Z Y, Liu X S, Li X, Ding X L, Yan W P. Single-Atom Iron Catalyst with Single- Vacancy Graphene-Based Substrate as a Novel Catalyst for NO oxidation: A Theoretical Study[J]. Catal. Sci. Technol., 2018,8(16):4159-4168. doi: 10.1039/C8CY01225C
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